Improvement of analytical characteristics for the determination of impurities in high temperature nickel alloys using ICP-MS

Yakimovitch P.V., Alekseev A.V.
UDC
669.018.44:669.245
DOI
10.18577/2307-6046-2019-0-5-3-11
Article PDF (Russian) (589.2 KB)
How to cite
Yakimovitch P.V., Alekseev A.V. Improvement of analytical characteristics for the determination of impurities in high temperature nickel alloys using ICP-MS // Proceedings of VIAM. 2019. No. 5. DOI: 10.18577/2307-6046-2019-0-5-3-11. URL: https://test.viam.ru/en/journal/2019/5/1
Keywords
mass spectrometry with inductively coupled plasma (ICP-MS), nickel alloys, de-termination of impurities, microwave sample preparation.
Abstract

In this work, the determination of P, As, Se, Cd, Cu, Zn, Te, Sb in samples of complex alloy nickel alloys by inductively coupled plasma mass spectrometry (ICP-MS) was carried out. The technique of dissolving the sample and preparing it for analysis. Applied different techniques for elimination of spectral interferences and improve sensitivity definitions: reaction-collision cell and mathematical correction. Range of determined concentrations were 0,00001–0,087% by weight, relative standard deviation not greater than 0,05.

Reference list
  1. Kablov E.N. Strategicheskie napravleniya razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda [The strategic directions of development of materials and technologies of their processing for the period to 2030] // Aviacionnye materialy i tehnologii. 2012. №S. S. 7–17.
  2. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] // Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
  3. Kablov E.N., Petrushin N.V., Parfenovich P.I. Konstruirovaniye liteynykh zharoprochnykh nikelevykh splavov s polikristallicheskoy strukturoy [Construction of foundry heat-resistant nickel alloys with polycrystalline structure] // Metallovedeniye i termicheskaya obrabotka metallov. 2018. №2 (752). S. 47–55.
  4. Kablov E.N., Ospennikova O.G., Petrushin N.V., Visik E.M. Monokristallicheskij zharoprochnyj nikelevyj splav novogo pokoleniya s nizkoj plotnostyu [Single-crystal nickel-based superalloy of a new generation with low-density] // Aviacionnye materialy i tehnologii. 2015. №2 (35). S. 14–25. DOI: 10.18577/2071-9140-2015-0-2-14-25.
  5. Echin A.B., Bondarenko Yu.A. Osobennosti struktury i svojstva nikelevogo monokristallicheskogo splava, poluchennogo v usloviyah peremennogo temperaturnogo gradienta na fronte rosta [Structural features and properties of single-crystal Ni-based superalloy produced under conditions of variable temperature gradient on the solidification front] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2015. №8. St. 01. Available at: http://www.viam-works.ru (accessed: July 07, 2018). DOI: 10.18577/2307-6046-2015-0-8-1-1.
  6. Kablov E.N., Bondarenko Yu.A., Echin A.B. Razvitiye tekhnologii napravlennoy kristallizatsii liteynykh vysokozharoprochnykh splavov s peremennym upravlyayemym temperaturnym gradiyentom [Development of technology of cast superalloys directional solidification with variable controlled temperature gradient] // Aviacionnyye materialy i tehnologii. 2017. №S. S. 24–38. DOI: 10.18577/2071-9140-2017-0-S-24-38.
  7. Shein E.A. Tendentsii v oblasti legirovaniya i mikrolegirovaniya zharoprochnykh monokristallicheskikh splavov na osnove nikelya (obzor) [Tendencies in the field of alloying and microalloying of heat resisting single-crystal alloys on the basis of nickel (review)] // Trudy VIAM: elektron. nauch.-tekhnich. zhurn. 2016. №3. St. 02. Available at: http://viam-works.ru (accessed: 07 July, 2018). DOI: 10.18557/2307-6046-2016-0-3-2-2.
  8. Hu J., Wang H. Determination of Trace Elements in Super Alloy by ICP-MS // Mikrochim. Acta. 2001. Vol. 137. P. 149–155.
  9. Alekseev A.V., Yakimovich P.V., Min P.G. Opredelenie primesej v splave na osnove niobiya metodom ISP-MS. Chast II [Determination of impurity in alloy based on Nb by ICP-MS. Part II] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2015. №7. St. 03. Available at: http://www.viam-works.ru (accessed: April 01, 2019). DOI: 10.18557/2307-6046-2015-0-7-3-3.
  10. Pupyshev A.A., Epova E.N. Spektralnyye pomekhi poliatomnykh ionov v metode mass-spektrometrii s induktivno svyazannoy plazmoy [Spectral noise of polyatomic ions in the method of mass spectrometry with inductively coupled plasma] // Analitika i kontrol. 2001. T. 5. №4. S. 335–369.
  11. Gao Y., Liu R., Yang L. Application of chemical vapor generation in ICP-MS: A review // Chinese Science Bulletin 2013. Vol. 58. No. 8. P. 1980–1991.
  12. Leykin A.Yu., Yakimovich P.V. Sistemy podavleniya spektra'nykh interferentsiy v mass-spektrometrii s induktivno svyazannoy plazmoy [Systems of suppression of spectral interferences in mass spectrometry with inductively coupled plasma] // Zhurnal analiticheskoy khimii. 2012. T. 67. №8. S. 752–762.
  13. Nie X., Liang Y. Determination of trace elements in high purity nickel by high resolution inductively coupled plasma mass spectrometry // Journal of Central South University 2012. Vol. 19. P. 2416–2420.
  14. Jakubowski N., Prohaska T., Rottmann L., Vanhaecke F. Inductively coupled plasma- and glow discharge plasma-sector field mass spectrometry // Journal of Analytical Atomic Spectrometry 2011. Vol. 26. P. 693–726.
  15. Liu H., Chen S., Chang P. yet al. Determination of bismuth, selenium and tellurium in nickel-based alloys and pure copper by flow-injection hydride generation atomic absorption spectrometry with ascorbic acid prereduction and cupferron chelation extraction // Analytica Chimica Acta. 2002. Vol. 459. P. 161–168.
  16. Yakubenko E.V., Voytkova Z.A., Chernikova I.I., Ermolayeva T.N. Mikrovolnovaya probopodgotovka dlya opredeleniya Si, P, V, Cr, Mn, Ni, Cu, W metodom AES-ISP v konstruktsionnykh stalyakh [Microwave sample preparation for the determination of Si, P, V, Cr, Mn, Ni, Cu, W by AES-ICP method in structural steels] // Zavodskaya laboratoriya. Diagnostika materialov. 2014. T. 80. №1. S. 12–15.