Influence of structure and technology of drawing of multilayer heat-protective coatings produced by thermal spraying dusting on thermal conductivity

Loshinin U.V., Razmakhov M.G., Pahomkin S.I., Lutsenko A.N.
Loshinin U.V., Razmakhov M.G., Pahomkin S.I., Lutsenko A.N. Influence of structure and technology of drawing of multilayer heat-protective coatings produced by thermal spraying dusting on thermal conductivity // Proceedings of VIAM. 2019. No. 6. DOI: 10.18577/2307-6046-2019-0-6-95-103. URL: https://test.viam.ru/en/journal/2019/6/10
Keywords
heat-protective covering, cathode-ray and magnetron drawing, thermocyclic durability, thermal diffusivity, thermal conductivity, heat capacity, method of laser flash, thermal resistance.
Abstract

On the basis of results of measurement of thermal diffusivity the method of laser flash with the temperature range from 20 to 1100°C multilayer heat-protective coatings received by thermal spraying dusting has establishes essential increase (from 40 to 50%) efficiency of heat-protective properties of coverings of having two ceramic layers: one – ZrO2+7%Y2O3, of other – ZrO2+7%Y2O3+oxides REM in comparison with the heat-protective coverings having one ceramic layer of – ZrO2+7%Y2O3. The same effect is observed on the coverings having one ceramic layer of ZrO2+7%Y2O3 of bigger thickness, alloyed by ytterbium and gadolinium oxides. Thermal conductivity of ceramic layer of ZrO2+7%Y2O3 made on technologies of atmospheriс plasma spraying, equal 1,5 W/(m·K) and is determined by technology of the magnetron drawing, equal 2,4 W/(m·K).

Reference list
  1. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] // Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
  2. Kablov E.N., Muboyadzhyan S.A. Teplozashchitnyye pokrytiya s keramicheskim sloyem ponizhennoy teploprovodnosti na osnove oksida tsirkoniya dlya lopatok turbiny vysokogo davleniya perspektivnykh GTD // Sovremennyye dostizheniya v oblasti sozdaniya perspektivnykh nemetallicheskikh kompozitsionnykh materialov i pokrytiy dlya aviatsionnoy i kosmicheskoy tekhniki: sb. dokl. konf. M.: VIAM, 2015. Ch. 1. Doklad №3. URL: http://conf.viam.ru/conf/172/proceedings (data obrashcheniya: 25.03.2019).
  3. Kablov E.N., Ospennikova O.G., Svetlov I.L. Vysokoeffektivnoe ohlazhdenie lopatok goryachego trakta GTD [Highly efficient cooling of GTE hot section blades] // Aviacionnye materialy i tehnologii. 2017. №2 (47). S. 3–14. DOI: 10.18577/2071-9140-2017-0-2-3-14.
  4. Chubarov D.A., Budinovskij S.A. Vybor keramicheskogo materiala dlya teplozashhitnyh pokrytij lopatok aviacionnyh turbin na rabochie temperatury do 1400°C [Choosing ceramic materials for thermal barrier coating of GTE turbine blades on working temperatures up to 1400°С] // Trudy VIAM : elektron. nauch.-tehnich. zhurn. 2015. №4. St. 07. Available at: http://viam-works.ru (accessed: March 26, 2019). DOI: 10.18577/2307-6046-2015-0-4-7-7.
  5. Budinovskij S.A., Smirnov A.A., Matveev P.V., Chubarov D.A. Razrabotka teplozashhitnyh pokrytij dlja rabochih i soplovyh lopatok turbiny iz zharoprochnyh i intermetallidnyh splavov [Development of thermal barrier coatings for rotor and nozzle turbine blades made of nickel-base super- and intermetallic alloys] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2015. №4. St. 05. Available at: http://www.viam-works.ru (accessed: March 26, 2019). DOI: 10.18577/2307-6046-2015-0-4-5-5.
  6. Matveev P.V., Budinovskij S.A., Chubarov D.A. Tehnologiya polucheniya ionno-plazmennyh zharostojkih podsloev s povyshennym soderzhaniem alyuminiya dlya perspektivnyh TZP [Technology for production of ion-plasma heat-resistant bonding sub-layers with increased aluminum content for advanced TBCs] // Aviacionnye materialy i tehnologii. 2014. №S5. S. 56–60. DOI: 10.18577/2071-9140-2014-0-s5-56-60.
  7. Budinovskij S.A., Chubarov D.A., Matveev P.V. . Sovremennye sposoby naneseniya teplozashhitnyh pokrytij na lopatki gazoturbinnyh dvigatelej (obzor) [Modern methods for deposition of thermal barrier coatings on GTE turbine blades] // Aviacionnye materialy i tehnologii. 2014. №S5. S. 38–44.
  8. Tamarin Yu.A., Kachanov E.B. Svoystva teplozashchitnykh pokrytiy, nanosimykh elektronnoluchevoy tekhnologiyey [Properties of heat-shielding coatings applied by electron-beam technology] // Novyye tekhnologicheskiye protsessy i nadezhnost GTD. M.: Izd-vo TSIAM, 2008. Vyp. 7. S. 125–144.
  9. Gayamov A.M., Budinovskij S.A., Muboyadzhyan S.A., Kosmin A.A. Vybor zharostojkogo pokrytija dlya zharoprochnogo nikelevogo renij-rutenijsoderzhashhego splava marki VZhM4 [Selection of heat-resistant coating with metalloceramic barrier layer for protection of Re-Ru nickel-based superalloy] // Trudy VIAM : elektron. nauch.-tehnich. zhurn. 2014. №1. St. 01. Available at: http://viam-works.ru (accessed: March 26, 2019).
  10. Matveyev P.V., Budinovskiy S.A. Issledovaniye svoystv zashchitnykh zharostoykikh pokrytiy dlya intermetallidnykh nikelevykh splavov tipa VKNA dlya rabochikh temperatur do 1300°S // Aviatsionnyye materialy i tekhnologii. 2014. №3. S. 22–26. DOI: 10.18577/2071-9140-2014-0-3-22-26.
  11. Popov P.A., Solomennik V.D., Lomonova E.E. i dr. Teploprovodnost' monokristallicheskikh tverdykh rastvorov ZrO2–Y2O3 v intervale temperatur 50–300 K [Selection of a heat-resistant coating for a heat-resistant nickel rhenium-ruthenium-containing alloy of the VZhM4 grade] // Fizika tverdogo tela. 2012. T. 54. Vyp. 3. S. 615–618.
  12. Yakovchuk K.Yu. Teploprovodnost i termotsiklicheskaya dolgovechnost' kondensatsionnykh termobaryernykh pokrytiy [Thermal conductivity and thermocyclic durability of condensation thermal barrier coatings] // Sovremennaya elektrometallurgiya. 2014. №4. S. 25–31.
  13. Loshchinin Yu.V., Budinovskiy S.A., Razmakhov M.G. Teploprovodnost teplozashchitnykh legirovannykh oksidami RZM pokrytiy ZrO2–Y2O3, poluchennykh magnetronnym naneseniyem [Heat conductivity of heat-protective coatings ZrO2–Y2O3 alloyed by REM oxides obtained by magnetronny application] // Aviacionnye materialy i tehnologii. 2018. №3 (52). S. 42–49. DOI: 10.18577/2071-9140-2018-0-3-42-49.
  14. Movchan B.A., Yakovchuk K.Yu. Advanced graded protective coatings, deposited by EB-PVD // Materials Science Forum. 2007. No. 546–549. P. 1681–1688.
  15. Zhong X., Zhao H., Zhou X. et al. Thermal shock behaviour of toughened gadolinium zirconate / YSZ double-layered thermal barrier coating // Journal of Alloy and Compounds. 2014. No. 593. P. 50–55.
  16. ASTM E 1461. Standard Test Method for Thermal Diffusivity of Solids by the Flash Method. West Conshohocken: ASTM International, 2001. P. 1–8.
  17. Zuev A.V., Loshchinin Yu.V., Barinov D.Ya., Marakhovskij P.S. Raschetno-eksperimentalnye issledovaniya teplofizicheskikh svojstv [Computational and experimental investigations of thermophysical properties] // Aviacionnye materialy i tehnologii. 2017. №S. S. 575–595. DOI: 10.18577/2071-9140-2017-0-S-575-595.
  18. Slifka A.J., Filla B.J. Thermal conductivity measurement of an electron-beam physical-vapor-deposition coating // Journal of Research of the National Institute of Standards and Technology. 2003. Vol. 108. P. 147–150.
  19. Ratzer-Scheibe H.-J., Schulz U., Krell T. The effect of coating thickness on the thermal conductivity of EB-PVD PYSZ thermal barrier coatings // Surface and Coatings Technology. 2006. Vol. 200. P. 5636–5644.
  20. Jang B.K., Yoshiya M., Yamaguchi N., Matsubara H. Evaluation of thermal conductivity of zirconia coating layers deposited by EB-PVD // Journal of Materials Science. 2004. Vol. 39. P. 1823–1825.