Mixing ethylene-propylene-diene and methylphenylsiloxane rubbers in the formulation of cold and ozone resistant rubber

Semenova S.N., Suleymanov R.R., Chaykun A.М.
Semenova S.N., Suleymanov R.R., Chaykun A.М. Mixing ethylene-propylene-diene and methylphenylsiloxane rubbers in the formulation of cold and ozone resistant rubber // Proceedings of VIAM. 2019. No. 9. DOI: 10.18577/2307-6046-2019-0-9-64-72. URL: https://test.viam.ru/en/journal/2019/9/7
Keywords
rubber, ethylene-propylene-diene rubber, silicone rubber, cold-resistance, ozone-resistance, compatibility, compatibilizer, vulcanization.
Abstract

The possibility of using ethylene-propylene-diene (SKEPT-40) and methylphenylsiloxane (SKTFV-803) rubbers in the formulation of cold-resistant and ozone-resistant rubber was investigated. The optimal ratio of rubber in the rubber mixture, mixing method and vulcanizing system are proposed. The elastic-strength and thermo cold-resistant characteristics of vulcanizates were determined. It is shown that the investigated rubber based on EPDM and SKTFV has improved physicomechanical and cold-resistant indicators compared to the sealing rubber IRP-1375 based on a mixture of ethylene-propylene and butadiene-styrene rubbers.

Reference list
  1. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] // Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
  2. Kablov E.N. Materialy novogo pokoleniya – osnova innovatsiy, tekhnologicheskogo liderstva i natsionalnoy bezopasnosti Rossii [Materials of a new generation – the basis of innovation, technological leadership and national security of Russia] // Intellekt i tekhnologiya. 2016. №2 (14). S. 16–21.
  3. Kablov E.N., Startsev V.O. Sistemnyj analiz vliyaniya klimata na mekhanicheskie svojstva polimernykh kompozitsionnykh materialov po dannym otechestvennykh i zarubezhnykh istochnikov (obzor) [Systematical analysis of the climatics influence on mechanical properties of the polymer composite materials based on domestic and foreign sources (review)] // Aviacionnye materialy i tehnologii. 2018. №2 (51). S. 47–58. DOI: 10.18577/2071-9140-2018-0-2-47-58.
  4. Kablov E.N. Materialy i khimicheskiye tekhnologii dlya aviatsionnoy tekhniki [Materials and chemical technologies for aviation technology] // Vestnik Rossiyskoy akademii nauk. 2012. T. 82. №6. S. 520–530.
  5. Kablov E.N. Rol khimii v sozdanii materialov novogo pokoleniya dlya slozhnykh tekhnicheskikh sistem [The role of chemistry in the creation of new generation materials for complex technical systems] // Tez. dokl. XX Mendeleyevskogo syezda po obshchey i prikladnoy khimii. Ekaterinburg: UrO RAN, 2016. S. 25–26.
  6. Laptev A.B., Barbotko S.L., Nikolaev E.V. Osnovnye napravleniya issledovanij sokhranyaemosti svojstv materialov pod vozdejstviem klimaticheskikh i ekspluatatsionnykh faktorov [The main research areas of the persistence properties of materials under the influence of climatic and operational factors] // Aviacionnye materialy i tehnologii. 2017. №S. S. 547–561. DOI: 10.18577/2071-9140-2017-0-S-547-561.
  7. Gryaznov V.I., Petrova G.N., Yurkov G.Yu., Buznik V.M. Smesevye termojelastoplasty so specialnymi svojstvami [Thermoplastic mixtures with special properties] // Aviacionnye materialy i tehnologii. 2014. №1. S. 25–29. DOI: 10.18577/2071-9140-2014-0-1-25-29.
  8. Eliseev O.A., Krasnov L.L., Zajceva E.I., Savenkova A.V. Razrabotka i modificirovanie elastomernyh materialov dlya primeneniya vo vseklimaticheskih usloviyah [Development and modifying of elastomeric materials for application in all weather conditions] // Aviacionnye materialy i tehnologii. 2012. №S. S. 309–314.
  9. Efimov V.A., Shvedkova A.K., Korenkova T.G., Kirillov V.N. Issledovanie polimernyh konstrukcionnyh materialov pri vozdejstvii klimaticheskih faktorov i nagruzok v laboratornyh i naturnyh usloviyah [Research of polymeric constructional materials at influence of climatic factors and loadings in laboratory and natural conditions] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2013. №1. St. 05. Available at: http://viam-works.ru (accessed: April 04, 2019).
  10. Rubber compositions containing ethylene-propylene-diene terpolymers or ethylene-propylene copolymers and silicones: pat. US4341675A; filed 08.04.80; publ. 30.03.01.
  11. Epdm and/or ethylene propylene and silicon rubber compositions: pat. CA1301982C; filed 30.03.87; publ. 26.05.09.
  12. Silicon rubber/conductive ethylene propylene terpolymer rubber and its preparing method: pat. CN1186381C; filed 20.06.03; publ. 26.01.05.
  13. Silicone rubber and terpolymer EP rubber blend and preparation method thereof: pat. CN103602067A; filed 20.10.13; publ. 26.10.14.
  14. Silicone rubber/EPDM/LDPE ternary blending foaming material and preparation method thereof: pat. CN106867118A; filed 01.03.17; publ. 20.06.17.
  15. Composite material from silicon rubber and ethylene-propylene-copolymer or terpolymer rubber: pat. EP0484245A1; filed 31.10.90; publ. 18.03.19.
  16. Silicone rubber modified polymer compositions, to their preparation, and this material comprehensive wiper method: pat. DE102008001007A1; filed 04.04.08; publ. 18.03.19.