Phase and structural transformations in directionally solidified with plant front intermetallic eutectic Ni-based alloys
Ingots of samples of eutectic intermetallic nickel-base alloys γʹ+β, β+δ(Re), γʹ+NbC and γ/γʹ+NbC with natural composite structure respectively of the systems Ni–Al–W, Ni–Al–Re, Ni–Al–Nb–C and Ni–Al–Cr–Co–W–Mo–Nb–C are produced by the method of directional solidification with a plan front. Investigation are produced characteristics of the eutectic composites microstructure and phase composition, segregation of alloying elements along the composite zone of ingot, solidus temperature, liquidus temperature, volume fraction fibers δ(Re) and NbC in eutectic composites. For samples eutectic composite system Ni–Al–Cr–Cr–W–Mo–Nb–C with heterophase matrix base γʹ phase reinforced fibers of NbC-carbide tensile tests were performed in the temperature interval 20–1200 °С and long-term strength in the temperature interval 900–1200 °С at bases up to 1000 h.
- Cast blades of gas turbine engines: alloys, technologies, coatings. Ed. E.N. Kablov. 2nd ed. Moscow: Nauka, 2006, 632 p.
- Kablov E.N. Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030». Aviacionnye materialy i tehnologii, 2015, no. 1 (34), pp. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
- Walston S., Cetel A., MacKay R. et al. Joint development of a fourth generation single crystal superalloy. Superalloys-2004. Pennsylvania: Minerals, Metals & Materials Society, 2004, pp. 15–24.
- Harada H. Development of Superalloys for 1700 °C ultra-efficient gas turbines. Proceedings 9th Liège Conference «Materials for Advanced Power Engineering 2010». Liège: University of Liège, 2010, pp. 604–614.
- Sato A., Harada H., Yen An-C. et al. A 5th generation SC superalloy with balanced high temperature properties and processability. Superalloys-2008. Pennsylvania: Minerals, Metals & Materials Society, 2008, pp. 131–138.
- Petrushin N.V., Ospennikova O.G., Svetlov I.L. Single-crystal Ni-based superalloys for turbine blades of advanced gas turbine engines. Aviacionnye materialy i tehnologii, 2017, no. S, pp. 72−103. DOI: 10.18577/2071-9140-2017-0-S-72-103.
- Buntushkin V.P., Kablov E.N., Bazyleva O.A. Mechanical and operational properties of a heat-resistant foundry alloy based on Ni3Al intermetallic. Metally, 1995, no. 3, pp. 70–73.
- Buntushkin V.P., Povarova K.B., Bannykh O.A. et al. Effect of crystallographic orientation on the mechanical properties of single crystals of doped Ni3Al intermetallic. Metally, 1998, no. 2, pp. 49–53.
- Kablov E.N., Ospennikova O.G., Bazyleva O.A. Foundry structural alloys based on nickel aluminide. Dvigatel, 2010, no. 4, pp. 24–25.
- Bazyleva O.A., Arginbaeva E.G., Turenko E.Yu. Heat resisting cast intermetallic alloys. Aviacionnye materialy i tehnologii, 2012, no. S, pp. 57–60.
- Bazyleva O.A., Arginbaeva E.G., Turenko E.Yu. The high-temperature intermetallic alloys for parts of gas-turbine engines. Aviacionnye materialy i tehnologii, 2013, no. 3, pp. 26–31.
- Kablov E.N., Ospennikova O.G., Petrushin N.V. New single crystal heat-resistant intermetallic γʹ-based alloy for GTE blades. Aviacionnye materialy i tehnologii, 2015, no. 1 (34), pp. 34–40. DOI: 10.18577/2071-9140-2015-0-1-34-40.
- Ni3Al-based intermetallic alloys having improved strength above 850 °C: pat. US6106640 A; filed 08.06.98, publ. 22.08.00.
- Ni3Al-based alloys for die and tool application: pat. US6238620B1; filed 15.09.99; publ. 29.05.01.
- Trinickel aluminide-base heat-resistant alloy: pat. US2001/0013383A1; filed 06.02.01; publ. 16.08.01.
- Nickel aluminide alloy for high temperature structural use: pat US5006308; filed 09.06.89; publ. 09.04.91.
- Povarova K.B., Kazanskaya N.K., Drozdov A.A., Antonova A.V. Studying the possibility of creating thermally stable structural materials based on transition metal aluminides of the Ni–Al–X, Ru–Al–X, Ti–Al–X systems, where X is an alloying element or phase. Metally, 2005, no. 2, pp. 78–87.
- Povarova K.B., Drozdov A.A., Kazanskaya N.K., Morozov A.E., Antonova A.V. Physicochemical approaches to the development of NiAl-based alloys for high-temperature service. Metally, 2011, no. 2, pp. 48–62.
- Petrushin N.V., Bronfin M.B., Chabina E.B., Dyachkova L.A. Phase transformations and the structure of directionally crystallized Ni–Al–Re intermetallic alloys. Metally, 1994, no. 4, pp. 85–93.
- Joslin S.M., Chen X.F., Oliver B.F., Noebe R.D. Fracture behavior of directional solidified NiAl–Mo and NiAl–V eutectics. Materials Science Engineering A, 1995, vol, 196, is. 1–2, pp. 9–18.
- Nickel-based alloy and a product made from it: pat. 2187572 Rus. Federation; filed 16.11.00; publ. 20.08.02.
- Kupchenko G.V., Poko O.A., Mayonov A.V., Kupchenko V.G. Directionally crystallized corrosion-resistant eutectic alloys of the Ni – Cr – Al system. Modern methods and technologies for the creation and processing of materials: collection of articles. materials III International scientific and technical conf. (Minsk, October 15–17, 2008): in 4 books. Minsk: FTI NAS of Belarus, 2008, book. 1: Multifunctional materials in modern technology, micro- and nanoelectronics, pp. 18–22.
- Gorynin I.V., Burkhanov G.S., Farmakovsky B.V. Promising development of structural materials based on refractory compounds. Voprosy materialovedeniya, 2012, no. 2 (70), pp. 5–15.
- Que Z.P., Gu J.H., Choi H.K., Jung Y.G., Lee J.H. Lamellar to rod eutectic transition in the hypereutectic nickel-aluminum alloy. Materials Today: Proceedings, 2014, vol. 1, is. 1, pp. 17–24.
- Bremer F.J., Beyss M., Karthaus E. at al. Experimental analysis of the Ni–Al phase diagram. Journal of Crystal Grows, 1988, vol. 87, pp. 185–192.
- Hunziker O., Kurz W. Directional solidification and phase equilibria in the Ni–Al system. Metallurgical and Materials Transactions A, 1999, vol. 30, is. 12, pp. 3167–3175.
- Udovsky A.L., Alekseeva Z.M., Lukovkin A.I. On the phase equilibrium diagram of the nickel – aluminum – tungsten system in the range 1200–2000 ° С in the range of Ni–Ni0.5Al0.5–W compositions. Doklady AN SSSR, 1986, vol. 286, no. 4, pp. 935–939.
- Udovsky A.L., Oldakovsky I.V., Moldavsky V.G. Theoretical and experimental studies of phase equilibria of the Ni – NiAl – W system in the range 900–1500 ° С. Metally, 1991, no. 4, pp. 112–123.
- Giamei A.F., Anton D.L. Rhenium addition to a Ni-base superalloy: Effects on microstructure. Metallurgical Transaction A, 1985, vol. 16A, is. 11, pp. 1997–2005.
- Webber J.G., Van Aken D.C. Studies of a quasy-binary β-NiAl and α-Re eutectic. Scripta Metallurgica, 1989, vol. 23, is. 2, pp. 193–196.
- Barabash O.M., Koval Yu.N. The crystal structure of metals and alloys. Kiev: Naukova Dumka, 1986, 598 p.
- Leiderman G.M., Nikolaeva V.A. Interaction of NbC and ZrC with Ni. Izvestiya AN SSSR, ser.: Neorganicheskiye materialy, 1973, vol. 9, no. 10, pp. 1721–1723.
- Somov A.I., Tikhonovsky M.A., Oleksienko M.M., Golovin V.N. The influence of the composition and crystallization conditions on the microstructure and strength of the eutectic composition Ni–NbC. Fizika metallov i metallovedeniye, 1979, vol. 48, no. 2, pp. 318–322.
- Gridnev V.N., Barabash O.M., Easy T.N. Phase equilibria and structure of directionally crystallized alloys of the Ni–Nb–C system. Izvestiya AN SSSR, ser.: Metally, 1985, no. 6, pp. 211–217.
- Shurin A.K. Investigation of phase equilibria and the structure of alloys with interstitial phases for the tasks of developing materials with composite hardening. Fazovye ravnovesiya v metallicheskikh splavakh. Moscow: Nauka, 1981, pp. 209–217.
- Svetlov I.L., Petrushin N.V. Heat-resistant eutectic alloys. Mashinostroyenie: Encyclopedia: in 4 vols. Moscow: Mashinostroyenie, 2001. Vol. II-3: Non-ferrous metals and alloys. Composite materials, pp. 810–813.
- Yang S.W. Ni-base MC-carbide reinforced eutectic alloys for jet engine application. Proceedings of NCKU/AAS International Symposium on Engineering Sciences and Mechanics. National Cheng Kung University, 1981, pp. 1525–1537.
- Veys J.M., Mevrel R. Influence of protective coatings on the mechanical properties of CMSX-2 and Cotac 784. Materials Science and Engineering, 1987, vol. 88, pp. 253–260.
- Dannemann K., Stoloff N.S., Duquette D.J. High temperature fatigue of three nickel-base eutectic composite. Materials Science and Engineering, 1987, vol. 95, pp. 63–71.
- Shalin R.E., Svetlov I.L., Kachanov E.B., Toloraya V.N., Gavrilin O.S. Single crystals of heat-resistant nickel alloys. Moscow: Engineering, 1997. 336 p.
- Thomson E.R., Lemke F.D. Eutectic heat-resistant alloys obtained by directional crystallization. Composite materials: in 8 vols. Moscow: Mashinostroenie, 1978. Vol. 4: Composite materials with a metal matrix, pp. 110–164.
- Petrushin N.V., Elyutin E.S., Raevskikh A.N., Treninkov I.A. High-gradient directional solidification of intermetallic Ni–Al–Ta alloy based on Ni3Al, strengthened by TaC-phase. Trudy VIAM, 2017, no. 3, paper no. 01, Available at: http://www.viam-works.ru (accessed: December 2, 2019). DOI: 10.18577/2307-6046-2017-0-3-1-1.
- Kurtz V., Deputy P.R. Directional crystallization of eutectic materials. Moscow: Metallurgiya, 1980, 274 pp.
- Chabina E.B., Alekseev A.A., Filonova E.V., Lukina E.A. Application of methods of analytical microscopy and X-ray of the structural analysis for research of structural and phase condition of materials. Trudy VIAM, 2013, no. 5, paper no. 06. Available at: http://www.viam-works.ru (accessed: December 12, 2019).
- Gigliotte M.F.X., Henry M.F. Segregation in a plane front solidified γ/γʹ-TaC alloy. Proceedings of Conference on in Situ Composites II. Lexington: Xerox Individualized Publishing, 1976. P. 253–265.
- Petrushin N.V., Eljutin E.S., Dzhioeva E.S., Nazarkin R.M. Structural-phase characteristics of heat-resistant γ/γʹ-NbC eutectic composites containing rhenium and ruthenium. Perspektivnye materialy, 2015, no3, pp. 22–33.
- Portnoy K.I., Babich B.N., Svetlov I.L. Nickel-based composite materials. Moscow: Metallurgiya, 1979, 263 p.
- Stolof N.S. The mechanical properties of directional eutectics. Achievements in the field of composite materials. Moscow: Metallurgiya, 1982, pp. 189–220.
