The choice the of the thermosetting binder composition modified by active nanoparticles of LSNO ceramics, for impregnation of thermoplastic templates obtained by FDM-printing

Pykhtin A.A., Sorokin A.E., Kraev I.D., Voronov V.A.
Pykhtin A.A., Sorokin A.E., Kraev I.D., Voronov V.A. The choice the of the thermosetting binder composition modified by active nanoparticles of LSNO ceramics, for impregnation of thermoplastic templates obtained by FDM-printing // Proceedings of VIAM. 2020. No. 9. DOI: 10.18577/2307-6046-2020-0-9-15-26. URL: https://test.viam.ru/en/journal/2020/9/2
Keywords
nickelate ceramics, polymer matrix, nanocomposites, surfactants, dispersions, electrophysical properties.
Abstract

Within the framework of this work, the synthesis technology was developed and the characterization of complex nickelate ceramics of the composition La15/8Sr1/8NiO4 (LSNO) was carried out by the method of х-ray phase analysis. Research has been carried out to identify the regularities of the influence of the chemical nature of the polymer matrix on the complex of technological, physical-mechanical and electrophysical properties of nanocomposites modified with LSNO. The effect of surfactants (surfactants) of different brands on the stability and rheological characteristics of nanodispersions based on the previously selected oligomer was investigated and the optimal content of ceramic nanoparticles and surfactants for each of the systems was determined. The rheological and physical-mechanical properties of the obtained dispersions and polymer nanocomposites based on them have been determined. Research has been carried out and the concentration dependences of the electrophysical properties of samples of cured nanocomposites have been determined.

Reference list
  1. Kablov E.N. Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030». Aviacionnye materialy i tehnologii, 2015, no. 1 (34), pp. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
  2. Kablov E.N., Semenova L.V., Petrova G.N. at al. Polymer composite materials on a thermoplastic matrix. Izvestiya vysshikh uchebnykh zavedeniy, Ser.: Chemistry and Chemical Technology, 2016, vol. 59, no. 10, pp. 61–71.
  3. Kablov E.N., Startsev V.O., Inozemtsev A.A. The moisture absorption of structurally similar samples from polymer composite materials in open climatic conditions with application of thermal spikes. Aviacionnye materialy i tehnologii, 2017, no. 2 (47), pp. 56–68. DOI: 10.18577/2071-9140-2017-0-2-56-68.
  4. Kraev I.D., Popkov O.V., Shuldeshov E.M. i dr. Prospects for the use of organosilicon elastomers in the development of modern polymer materials and coatings for various purposes. Trudy VIAM, 2017, no. 12 (60), paper no. 5. Available at: http://www.viam-works.ru (accessed: Februry 28, 2020). DOI: 10.18577/2307-6046-2017-0-12-5-5.
  5. Thomassin J.-M., Jerome C., Pardoen T. et al. Polymer / carbon based composites as electromagnetic interference (EMI) shielding materials. Materials Science and Engineering: Reports, 2013, vol. 74, pp. 211–232.
  6. Sandler J.K.W., Kirk J.E., Kinloch I.A. et al. Ultra-low electrical percolation threshold in carbon-nanotube epoxy composites. Polymer, 2003, vol. 44 (19). P. 5893–5899.
  7. Silva V.A., Folgueras L., Candido G.M. et al. Nanostructured Composites Based on Carbon Nanotubes and Epoxy Resin for Use as Radar Absorbing Materials. Materials Research, 2013, vol. 16 (6), pp. 1299–1308.
  8. Kondrashov S.V., Solovyanchik L.V., Melnikov A.A., Dyachkova T.P., Buznik V.M. Hybrid composite fiberglass for shielding of electromagnetic radiation of ultrahigh frequencies. Trudy VIAM, 2018, no. 7 (67), paper no. 09. Available at: http://www.viam-works.ru (accessed: June 03, 2020). DOI: 10.18577/2307-6046-2018-0-7-78-87.
  9. Teber A., Cil K., Yilmaz T. et al. Manganese and Zinc Spinel Ferrites Blended with Multi-Walled Carbon Nanotubes as Microwave Absorbing Materials. Aerospacep, 2017, no. 4, pp. 2–19.
  10. Wang Z., Wu L., Zhou J. et al. Magnetite Nanocrystals on Multiwalled Carbon Nanotubes as a Synergistic Microwave Absorber. Journal Physical Chemistry, 2013, no. 117, pp. 5446–5452.
  11. Subramanian M.A., Li D., Duan N., Reisner B.A. et al. High Dielectric Constant in ACu3Ti4O12 and ACu3Ti3FeO12 Phases. Journal Solid State Chemistry, 2000, no. 151, pp. 323–325.
  12. Kadkhodayan H., Seyed Dorraji M.S., Rasoulifard M.H. et al. Enhanced microwave absorption property of Fe3O4 /CaCu3-xMgxTi4-ySnyO12 (0≤x, y≤1)/graphene oxide nanocomposites in epoxy vinyl ester resin. Journal of Materials Science: Materials in Electronics, 2017, vol. 28 (17), pp. 1–10. DOI: 10.1007/s10854-017-7076-2.
  13. Merkulova Yu.I., Muhametov R.R. Development of a low-viscosity epoxy binder for processing by vacuum infusion. Aviacionnye materialy i tehnologii, 2014, no. 1, paper no. 39–41. DOI: 10.18577/2071-9140-2014-0-1-39-41.
  14. Krohns S., Lunkenheimer P., Loidl A. Colossal dielectric constants in La15/8Sr1/8NiO4. IOP Conf. Series: Materials Science and Engineering, 2010, no. 8, pp. 1–4.
  15. Krohns S., Lunkenheimer P., Kant Ch. et al. Colossal dielectric constant up to gigahertz at room temperature. Applied Physics Letters, 2009, no. 94, pp. 94–96.
  16. Voronov V.A., Shvetsov A.O., Gubin S.P. Influence of the method of obtaining cathode material with composition LiNi0.33Mn0.33Co0.33O2 on the electrochemical characteristics of a lithium-ion battery. Journal of Inorganic Chemistry, 2016, vol. 61, no. 9, pp. 1211–1217.