Features of formation of electrolyte-plasma coatings from nickel-containing electrolytes on titanium alloys
Duyunova V.A., Oglodkov M.S., Gerasimov M.V., Kozlov I.A., Knyazev A.V. Features of formation of electrolyte-plasma coatings from nickel-containing electrolytes on titanium alloys // Proceedings of VIAM. 2021. No. 7. DOI: 10.18577/2307-6046-2021-0-7-86-94. URL: https://test.viam.ru/en/journal/2021/7/9
Keywords
titanium alloy, microarc oxidation, electrolyte-plasma coating, electrical conductivity, corrosion resistance.
Abstract
Influence of nickel sulfate additives in silicate-alkaline electrolyte for microarc oxidation of titanium alloys on properties of formed electrolyte-plasma coatings was investigated. The influence of the component composition of the electrolyte on the chemical composition of the coatings, their protective ability, porosity and electrical characteristics was established. It is shown that the most corrosion-resistant coatings are formed from electrolytes with a low content of nickel sulfate, and an increase in the content of nickel in the coating does not lead to a significant change in its electrical conductivity.
Reference list
- Sibileva S.V., Karimova S.A. Surface treatment of titanium alloys to provide adhesion properties. Aviacionnye materialy i tehnologii, 2013, no. S2, pp. 25–35.
- Tomashov N.D. Titanium and corrosion-resistant alloys based on it. Moscow: Metallurgiya, 1985, 80 p.
- Kablov E.N. Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030». Aviacionnye materialy i tehnologii, 2015, no. 1 (34), pp. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
- Kablov E.N. Corrosion or life. Nauka i zhizn, 2012, no. 11, pp. 16–21.
- Kablov E.N., Kashapov O.S., Pavlova T.V., Nochovnaya N.A. Development of a pilot industrial technology for the manufacture of semi-finished products from pseudo-alpha titanium alloy VT4. Titan, 2016, no. 2 (52), pp. 33–42.
- Molitor P., Young T. Adhesives bonding of a titanium alloy to a glass fiber reinforced composite material. International Journal of Adhesion and Adhesives, 2002, vol. 22, pp. 101-107.
- Ditchek B.M., Breen K.R., Sun T.S., Venables J.D. Morphology and composition of titanium adherends prepared for adhesive bounding. Proceedings of 25th National SAMPE Symposium, 1980, pp. 13–24.
- Method of coating titanium articles and product thereof: pat. US 2864732; filed 05.10.53; publ. 16.12.58.
- Mahoon A. Titanium adherens. Durability of structural adhesives. London: Applied Science Publishers, 1983, p. 255.
- Gorlov D.S., Aleksandrov D.A., Zaklyakova O.V., Azarovskiy E.N. Investigation of the possibility of protection of intermetallic titanium alloy against fretting wear by ion-plasma coating. Trudy VIAM, 2018, no. 4 (64), paper no. 06. Available at: http://www.viam-works.ru (accessed: June 8, 2021). DOI: 10.18577/2307-6046-2018-0-4-51-58.
- Belkin P.N., Kusmanov S.A. Nitriding of commercial titanium during anodic electrolytic-plasma treatment. Fast-hardened materials and coatings: materials of the 13th Intern. scientific and technical conf. (Moscow, November 25–26, 2014). Moscow: MATI, 2014, pp. 273–276.
- Kozlov I.A., Vinogradov S.S., Tarasova K.G., Kulyushina N.V., Manchenko V.A. Plasma electrolytic oxidation of magnesium alloys (review). Aviacionnye materialy i tehnologii, 2019, no. 1 (54), pp. 23–36. DOI: 10.18577/2071-9140-2019-0-1-23-36.
- Gnedenkov S.V., Sidorova M.V., Sinebrjuhov S.L., Antipov V.V., Buznik V.M., Volkova E.F., Sergienko V.I. Structure and properties of the coverings received by method of plasma electrolytic oxidation on aviation magnesium alloys. Aviacionnye materialy i tehnologii, 2013, no. S2, pp. 36–45.
- Sibileva S.V., Kozlova L.S. Review of technologies of applying coatings to titanium alloys by plasma electrolytic oxidation. Aviacionnye materialy i tehnologii, 2016, no. S2, pp. 3–10. DOI: 10.18577/2071-9140-2016-0-S2-3-10.
- Shashkina G.A., Ivanov M.B., Legostaeva E.V., Sharkeev Yu.P. et al. Bioceramic coatings with a high calcium content for medicine. Fizicheskaya mezomekhanika, 2004, vol. 7, no. S1-2, pp. 123–126.
- Pecherskaya E.A., Golubkov P.E., Karpanin O.V. Research of the influence of technological parameters of the process of microarc oxidation on the properties of oxide coatings. Izvestiya vysshikh uchebnykh zavedeniy. Elektronika, 2019.Vol. 24, no. 4, pp. 363–369. DOI: 10.24151/1561-5405-2019-24-4-363-369.
- Legostaeva E.V., Komarova E.G., Sharkeev Yu.P., Uvarkin P.V. Investigation of the effect of microarc oxidation stress on the physicochemical properties of calcium phosphate coatings on titanium. Perspektivnyye materialy, 2011, no. S13, pp. 456–465.
- Kozlov I.A., Vinogradov S.S., Tarasova K.G., Kulyushina N.V., Manchenko V.A. Plasma electrolytic oxidation of magnesium alloys (review). Aviacionnye materialy i tehnologii, 2019, no. 1 (54), pp. 23–36. DOI: 10.18577/2071-9140-2019-0-1-23-36.
- Sibileva S.V., Knyazev A.V., Leshko S.S., Chesnokov D.V. Plasma electrolytic oxidation of titanium alloys for the purpose of protection against contact corrosion of conjugated elements made of aluminum alloys. Corrosion: materials, protection. Korroziya: materialy, zashchita, 2019, no. 6, pp. 1–6. DOI: 10.31044/1813-7016-2019-0-6-1-6.
- Shtefan V.V., Smirnova A.Yu. Obtaining Ce-, Zr-, Cu-containing oxide coatings on titanium by the method of microarc oxidation. Elektrokhimiya, 2015, vol. 51, no. 12, pp. 1309–1316. DOI: 10.7868 / S0424857015120105.
- Nechaev G.G. Microarc oxidation of titanium alloys in alkaline electrolytes. Kondensirovannye sredy i mezhfaznyye granitsy, 2012, vol. 14, no. 4, pp. 453–455.
- Mitroshin A.N., Ivanov P.V., Rosen A.E. et al. Comparative evaluation of osseointegration of screw conical and cylindrical titanium implants processed by the method of microarc oxidation. Fundamentalnye issledovaniya, 2011, no. 9-3, pp. 447–451.
- Legostaeva E.V., Tolkacheva T.V., Komarova E.G. et al. Microstructure and physical and mechanical properties of calcium phosphate coatings obtained by microarc oxidation and detonation gas spraying. Obrabotka metallov (tekhnologiya, oborudovaniye, instrumenty), 2013, no. 1 (58), pp. 63‒68.
- Andreev A.S., Snezhko A.A. The influence of electrolyte composition on the structure and properties of oxide coatings formed on titanium alloys by microarc oxidation. Reshetnevskie readings: materials of the XIII Intern. scientific conf. (Krasnoyarsk, November 10–12, 2009): at 2 parts. Krasnoyarsk, 2009, part 1, pp. 307–308.
- Legostaeva EV, Sharkeev Yu.P., Epple M., Primak O. Structure and properties of microarc calcium phosphate coatings on the surface of titanium and zirconium alloys. Izvestiya vysshikh uchebnykh zavedeniy. Fizika, 2013, vol. 56, no. 10, pp. 23‒28.
- Pecherskaya E.A., Golubkov P.E., Karpanin O.V. Research of the influence of technological parameters of the process of microarc oxidation on the properties of oxide coatings. Izvestiya vysshikh uchebnykh zavedeniy. Elektronika, 2019, vol. 24, no. 4, pp. 363–369.
- Gerasimov M.V., Bogdashkina N.L., Zalavutdinov R.Kh. et al. Influence of Ni, Co and Fe additives in silicate-alkaline electrolyte for microarc oxidation on the characteristics of coatings formed on titanium. Korroziya: materialy, zashchita, 2018, no. 11, pp. 35–40.
- Alyakretskiy R.V., Ravodina D.V., Trushkina T.V. Research of corrosion resistance of protective coatings on titanium alloys obtained by microarc oxidation. Reshetnevskie readings: materials of the XVIII Intern. scientific conf. (Krasnoyarsk, November 11–14, 2014): at 2 parts. Krasnoyarsk, 2014. Part 1, pp. 7–8.
- Kuznetsov Yu.A., Kulakov K.V. Investigation of the microhardness of coatings formed by microarc oxidation. Naukoví notatki, 2011, no. 33, pp. 104–106.
