Comparison of the properties of glass-reinforced plastics based on polyimide binders of solution and melt type

Kurnosov A.O., Petrova A.P., Slavin A.V., Vavilova M.I., Kurshev E.V.
UDC
678.067.5
DOI
10.18577/2307-6046-2022-0-10-42-54
Article PDF (Russian) (1.43 MB)
How to cite
Kurnosov A.O., Petrova A.P., Slavin A.V., Vavilova M.I., Kurshev E.V. Comparison of the properties of glass-reinforced plastics based on polyimide binders of solution and melt type // Proceedings of VIAM. 2022. No. 10. DOI: 10.18577/2307-6046-2022-0-10-42-54. URL: https://test.viam.ru/en/journal/2022/10/4
Keywords
polymer composite material, prepreg, fiberglass, polyimide, binder, polymerization, heat resistance
Abstract

This article describes the features of the use of polyimide binders of solution and melt type in the manufacture of prepregs. The main physical and chemical characteristics of the solution binder of the polycondensation type brand SP-97S and the melt binder VS-51 of the polymerization type and prepregs based on them are given. The mechanical characteristics of glass-reinforced plastics were studied on the basis of binder data at room and elevated temperatures. The microstructural analysis of the surface of delamination of the samples after the compression test at temperature 20 °C was carried out by the method of scanning electron microscopy.

Reference list
  1. Kablov E.N. The strategic directions of development of materials and technologies of their processing for the period to 2030. Aviacionnye materialy i tehnologii, 2012, no. S, pp. 7–17.
  2. Kramarev D.V. Composite materials based on thermoplastic polyimide and polyaramid fabric: thesis, Cand. Sc. (Tech.). Moscow: Mendeleev Russian Chemical Technical University, 2018, 137 p.
  3. Raskutin A.E. Development strategy of polymer composite materials. Aviacionnye materialy i tehnologii, 2017, no. S, pp. 344–348. DOI: 10.18577/2071-9140-2017-0-S-344-348.
  4. Zharinov M.A., Petrova A.P., Babchuk I.V., Akhmadieva K.R. Heat-resistant polyimide structural adhesives. Klei. Germetiki. Tekhnologii, 2021, no. 4, pp. 2–8.
  5. Bondaletova L.I., Bondaletov V.G. Polymer composite materials (part 1): textbook. Tomsk: Tomsk Polytechnic University, 2013, pp. 5–7.
  6. Zharinov M.A., Shimkin A.A., Akhmadiyeva K.R., Zelenina I.V. Features and properties of solvent-free PMR-type polyimide resin. Trudy VIAM, 2018, no. 12 (72), paper no. 05. Available at: http://www.viam-works.ru (accessed: December 4, 2021). DOI: 10.18577/2307-6046-2018-0-12-46-53.
  7. Fiberglass and other structural plastics: collection of articles. Ed. Ya.D. Avrasin. Moscow: Oborongiz, 1960, 169 p.
  8. Korshak V.V. Heat resistant polymers. Moscow: Nauka, 1969, 381 p.
  9. Raskutin A.E., Sokolov I.I., Shuldeshova P.M., Kutsevich K.E., Gulyaev I.N. Structural carbon plastics, fiberglass and organoplastics for high- and medium-loaded structures. Report of XX Int. sci.-tech. conf. "Designs and technologies for the production of products from non-metallic materials". Obninsk: ONPP Tekhnologiya, 2013, pp. 67–69.
  10. Kolpachkov E.D., Vavilova M.I., Kurnosov A.O., Gunyaeva A.G. Glass-reinforced plastics based on thermosetting polyimide binders. Materials of All-Rus. sci.-tech. conf. "Polymer composite materials of a new generation for civil industries". Moscow: VIAM, 2020, pp. 31–41. Available at: https://conf.viam.ru/sites/default/files/uploads/proceedings/1294.pdf (accessed: December 4, 2021).
  11. Valueva M.I., Zelenina I.V., Zharinov M.A., Akhmadieva K.R. World market of high temperature polyimide carbon plastic (review). Trudy VIAM, 2019, no. 12 (84), paper no. 08. Available at: http://www.viam-works.ru (accessed: April 4, 2022). DOI: 10.18577/2307-6046-2019-0-12-67-79.
  12. Kurnosov A.O., Raskutin A.E., Mukhametov R.R., Melnikov D.A. Polymer composite materials based on thermosetting polyimide binders. Voprosy materialovedeniya, 2016, no. 4, pp. 50–62.
  13. Handbook of composite materials: in 2 books. Ed. J. Lubin. Moscow: Mashinostroenie, 1988, book. 1, 448 p.
  14. Veshkin E.A. Technologies of autoclave-free molding of low-porous polymer composite materials and large-sized structures from them: thesis, Cand. Sc. (Tech.). Moscow: VIAM, 2016, 23 p.
  15. Kablov E.N. Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030». Aviacionnye materialy i tehnologii, 2015, no. 1 (34), pp. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
  16. Tsyplakov O.G. Scientific bases of technology of composite-fibrous materials. Perm, 1974, pp. 36–38.
  17. Kablov E.N. Materials of a new generation and digital technologies for their processing. Vestnik Rossiyskoy akademii nauk, 2020, vol. 90, no. 4, pp. 331–334.
  18. Kablov E.N., Startsev V.O. Measurement and forecasting of materials samples’ temperature during weathering in different climatic zones. Aviacionnye materialy i tehnologii, 2020, no. 4 (61), pp. 47–58. DOI: 10.18577/2071-9140-2020-0-4-47-58.
  19. Kablov E.N., Startsev V.O. Systematical analysis of the climatics influence on mechanical properties of the polymer composite materials based on domestic and foreign sources (review). Aviacionnye materialy i tehnologii, 2018, no. 2 (51), pp. 47–58. DOI: 10.18577/2071-9140-2018-0-2-47-58.
  20. Kobets L.P., Deev I.S. Structure formation in thermosetting binders in matrices of composite materials based on them. Mendeleev Russian Chemical Journal of the Chemical Society, 2010, no. 1, pp. 67–78.
  21. Deev I.S., Startsev V.O., Nikishin E.F. Fractographic analysis of KMU-4L carbon fiber after 12 years of exposure to the outer surface of the International Space Station and subsequent bending tests. Voprosy materialovedeniya, 2015, no. 3 (83), pp. 140–149.