Influence of recipe of chromate-free quick-drying primer on structure and properties of protective coating
Kuznetsova V.A., Emelyanov V.V., Marchenko S.A., Kurshev E.V. Influence of recipe of chromate-free quick-drying primer on structure and properties of protective coating // Proceedings of VIAM. 2022. No. 11. DOI: 10.18577/2307-6046-2022-0-11-93-102. URL: https://test.viam.ru/en/journal/2022/11/9
Keywords
epoxy-thiokol compositions, hardeners, curing accelerator, chromate-free primer, pigments, fillers, oxygen permeability, water absorption, micro-structural analysis
Abstract
In this work the main attention has been given to choice of recipe of inhibitive pigments and fillers, and also definition of their optimum ratio in the polymeric film-forming. For researches the epoxy compositions modified by liquid polysulphide rubber, containing inhibitive pigments and fillers of different structure have been used. For curing of primer compositions organic silicon ammine has been used. For acceleration of process of curing of primer compositions, it was used tertiary amine UP-606/2. As a part of pigmental composition the inhibitive pigments as well as structure-forming fillers, have been investigated.
Reference list
- Zhitomirsky G.I. Aircraft design. Moscow: Mashinostroenie, 1991, 400 p.
- Kablov E.N. Aviation materials science: results and prospects. Vestnik Rossiyskoy akademii nauk, 2002, vol. 72, no. 1, pp. 3–12.
- Kablov E.N. The role of chemistry in the creation of new generation materials for complex technical systems. Reports of XX Mendeleev Congress on General and Applied Chemistry. Ekaterinburg: Ural Branch of the Russian Academy of Sciences, 2016, pp. 25–26.
- Zheleznyak V.G., Serdcelyubova A.S., Merkulova Yu.I., Skivko P.V. Paint coating system based on polyurethane enamel for protecting heated frontal surfaces of aviation products. Aviation materials and technologies, 2022, no. 1 (66), paper no. 10. Available at: http://www.journal.viam.ru (ассеssed: October 24, 2022). DOI: 10.18577/2713-0193-2022-0-1-120-128.
- Semenova L.V., Nefedov N.I., Belova M.V., Laptev A.B. Systems of paint coatings for helicopter equipment. Aviacionnye materialy i tehnologii, 2017, no. 4 (49), pp. 56–61. DOI: 10.18577/2071-9140-2017-0-4-56-61.
- Pyrikov A.V., Loiko D.P., Kochergin Yu.S. Modification of epoxy resins with liquid polysulfide and carboxylate butadiene rubbers. Klei. Germetiki. Tekhnologii, 2010, no. 1, pp. 28–33.
- Kuznetsova V.А., Zheleznyak V.G., Kurshev E.V., Yemelyanov V.V. Research of fuel- and water resistance of coatings based on the filled epoxy-thiokol polymeric compositions. Aviation materials and technologies, 2021, no. 2 (63), paper no. 10. Available at: http://www.journal.viam.ru (accessed: October 24, 2022). DOI: 10.18577/2713-0193-2021-0-2-93-102.
- Ashuyko V.A., Ivanova N.P., Salychits O.I. Properties of anticorrosive phosphate-containing pigments for paint and varnish coatings of metals. Energy and material-saving environmentally friendly technologies: abstracts of the X Intern. conf. Grodno, 2013, pp. 117–118.
- Skorokhodova O.N., Kazakova E.E. New pigments and fillers for the production of coatings. Lakokrasochnaya promyshlennost, 2017, no. 6, pp. 20–23.
- Emirova I.V., Alekseev A.A. New anticorrosion pigments. Izvestiya vuzov. Khimiya i khimicheskaya tekhnologiya, 2009, vol. 52, pp. 113–114.
- Orekhova S.E., Ashuiko V.A., Kurilo I.I., Salychits O.I. Synthesis and properties of pigments for paints and varnishes with anticorrosive properties. Energy and material-saving environmentally friendly technologies: abstracts of the IX Intern. conf. Grodno, 2011, pp. 42–43.
- Zhavoronok E.S., Senchikhin I.N. Evaluation of the crosslink density of a densely reticulated polymer taking into account the rigidity of the chain fragment between the network nodes. Vysokomolekulyarnye soyedineniya. Series B, 2019, vol. 61, no. 4, pp. 282–288.
- Pyrikov A.V., Loiko D.P., Kochergin Yu.S. Modification of epoxy resins with liquid polysulfide and carboxylate butadiene rubbers. Klei. Germetiki. Tekhnologii, 2010, no. 1, pp. 28–33.
- Eselev A.D., Bobylev V.A. Epoxy resins and hardeners for the production of paints and varnishes. Lakokrasochnye materialy i ikh primenenie, 2005, no. 10, pp. 16–25.
- Kochnova Z.A., Zhavoronok E.S., Chalykh A.E. Epoxy resins and hardeners: industrial products. Moscow: Paint Media, 2006, 200 p.
- Chebotareva E.G., Ogrel L.Yu. Modern trends in the modification of epoxy oligomers. Fundamentalnye issledovaniya, 2008, no. 4, pp. 102–104.
- Chalykh A.E., Kochnova Z.A., Zhavoronok E.S. Baru R.L. Chemical transformations and rheokinetics in the system carboxyl-containing rubber–epoxy oligomer. Izvestiya vuzov. Izvestiya vuzov. Khimiya i khimicheskaya tekhnologiya, 2007, vol. 50, no. 1, pp. 43–47.
- Kablov E.N. Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030». Aviacionnye materialy i tehnologii, 2015, no. 1 (34), pp. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
- Kuznetsova V.A., Semenova L.V., Shapovalov G.G. Development trends in the field of anticorrosive polymeric systems for corrosion protection of fixing connections of contact couples of combined structures (review). Aviacionnye materialy i tehnologii, 2017, no. 1 (46), pp. 25–31. DOI: 10.18577/2071-9140-2017-0-1-25-31.
- Kovrizhkina N.A., Kuznetsova V.A., Silaeva A.A., Marchenko S.A. Ways to improve the properties of paint coatings by adding different fillers (review). Aviacionnye materialy i tehnologii, 2019, no. 4 (57), pp. 41–48. DOI: 10.18577/2071-9140-2019-0-4-41-48.
- Chalykh A.E., Zhavoronok E.S., Kochnova Z.A. Interaction of carboxyl-containing nitrile rubber and epoxy oligomer. Vysokomolekulyarnye soyedineniya. Series B, 2010, vol. 52, no. 5, pp. 880–887.
