Protective technological coating for zirconium alloys

Vlasova O.V., Solntsev St.S., Denisova V.S., Lepschikov V.G.
UDC
629.7.023.222
DOI
10.18577/2307-6046-2022-0-8-132-140
Article PDF (Russian) (639.68 KB)
How to cite
Vlasova O.V., Solntsev St.S., Denisova V.S., Lepschikov V.G. Protective technological coating for zirconium alloys // Proceedings of VIAM. 2022. No. 8. DOI: 10.18577/2307-6046-2022-0-8-132-140. URL: https://test.viam.ru/en/journal/2022/8/11
Keywords
coating, zirconium alloy, heat treatment, oxidation, protective enamel, pressure treatment
Abstract

In this work technological coatings based on glass-forming systems K2O–BaO–SiO2 and Na2O–BaO–SiO2, used to protect zirconium alloys from oxidation during hot deformation was studied. Among 12 synthesized compositions a composition was selected with such a ratio of base glass components and modifying additives that provides a dense glassy visible coating on samples of zirconium alloys, prevents rapid increase in microhardness in near-surface layer of metal and effectively protects material from changes in mass during heating for deformation and prolonged excerpts.

Reference list
  1. Kablov E.N. The role of fundamental research in the creation of new generation materials. Repors of the XXI Mendeleev Congress on General Applied Chemistry: in 6 vols. St. Petersburg, 2019, vol. 4, pp. 21.
  2. Gavrilov G.N., Kablov E.N., Erofeev V.T. et al. Material science. Theory and technology of heat treatment: textbook. Saransk: Ogarev Mordovian State University, 2019, 276 p.
  3. Zaimovsky A.S., Nikulina A.V., Reshetnikov N.G. Zirconium alloys in nuclear power engineering. 2nd ed., rev. and add. Mosocw: Energoatomizdat, 1994, 252 p.
  4. Borisova O.A., Kolomytsev K.A. Obtaining zirconium tubes from an ingot for shells of a fuel element for nuclear reactors. Collection of scientific papers of the XXX International Scientific-Practical Conference "The current state and prospects for the development of science and education" (Anapa, January 7, 2022). Anapa, 2022, pp. 19–24.
  5. Erasov V.S., Oreshko E.I., Lutsenko A.N. Multilevel large-scale complex research of defor-mation of metal materials. Aviation materials and technologies, 2021, no. 4 (65), paper no. 11. Available at: http://www.journal.viam.ru (accessed: March 16, 22). DOI: 10.18577/2713-0193-2021-0-4-98-106.
  6. Mosbacher M., Holzinger M., Galetz M. et al. The influence of oxide color on the surface characteristics of zirconium alloy ZrNb7 (wt. %) after different heat treatments. Oxidation of Metals, 2021, vol. 95, no. 5, pp. 377–388. DOI: 10.1007/s11085-021-10030-1.
  7. Yang S., Guo Z., Zhao L. et al. Surface microstructure and high-temperature high-pressure corrosion behavior of N18 zirconium alloy induced by high current pulsed electron beam irradiation. Applied Surface Science, 2019, vol. 484, pp. 453–460. DOI: 10.1006/J.APSUSC.2019.04.124.
  8. Kablov E.N., Muboyadzhan S.A. Erosion-resistant coatings for compressor blades of gas turbine engines. Elektrometallurgiya, 2016, no. 10, pp. 23–38.
  9. Petelguzov I.A. Influence of protective coatings from aluminum and chromium on the oxidation of zirconium and its alloys. Voprosy atomnoy nauki i tekhniki, 2012, no. 2 (78), pp. 114–119.
  10. Ruchkin S.E., Pirozhkov A.V. Protective multilayer ZrO2/Cr coatings for E110 zirconium alloy. Modern problems of mechanical engineering: collection of works of the XIV International Scientific-Technologies Conference (Tomsk, October 25–30, 2021). Tomsk, 2021, pp. 179–180.
  11. Kovrizhkina N.A., Kuznetsova V.A., Silaeva A.A., Marchenko S.A. Ways to improve the properties of paint coatings by adding different fillers (review). Aviacionnye materialy i tehnologii, 2019, no. 4 (57), pp. 41–48. DOI: 10.18577/2071-9140-2019-0-4-41-48.
  12. Nefedov N.I., Semenova L.V., Kuznecova V.A., Vereninova N.P. Paint coatings for protection of metallic and polymer composite materials against aging, corrosion and biodeterioration. Aviacionnye materialy i tehnologii, 2017, no. S, pp. 393–404. DOI: 10.18577/2071-9140-2017-0-S-393-404.
  13. Gorlov D.S., Shchepilov A.V. Study of the damping capacity of the «alloy–coating» composition after tests on heat resistance and corrosion resistance. Aviacionnye materialy i tehnologii, 2017, no. 4 (49), pp. 62–69. DOI: 10.18577/2071-9140-2017-0-4-62-69.
  14. Bashkova I.O., Kharanzhevsky E.V. Laser synthesis of anticorrosive coatings on zirconium.
  15. 20th All-Russian Scientific Conference Physics Students and Young Scientists «VNKSF-20» (Izhevsk, March 27 – April 3, 2014). Izhevsk, 2014, 401 p.
  16. Mamaeva A.I., Chubenko A.K., Mamaeva V.A. Formation of non-metallic inorganic nanostructured coatings on zirconium by microplasma oxidation. Nauchno-tekhnicheskiy vestnik Povolzhya, 2013, no. 4, pp. 75–78.
  17. Malayoğlu U., Tekin K.C., Malayoğlu U. et al. Mechanical and electrochemical properties of PEO coatings on zirconium alloy. Surface Engineering, 2020, vol. 36, no. 8, pp. 800–808. DOI: 10.1080/02670844.2019.1706233.
  18. Kashkarov E.B., Sidelev D.V., Syrtanov M.S. et al. Oxidation kinetics of Cr-coated zirconium alloy: Effect of coating thickness and microstructure. Corrosion Science, 2020, vol. 175, p. 108883. DOI: 10.1016/j.corsci.2020.108883.
  19. Kuprin A.S., Belous V.A., Voyevodin V.N. et al. Irradiation resistance of vacuum arc chromium coatings for zirconium alloy fuel claddings. Journal of Nuclear Materials, 2018, vol. 510, pp. 163–167. DOI: 10.1016/j.jnucmat.2018.07.063.
  20. Li Z.Y., Cai Z.B., Cui X.J. et al. Influence of nanoparticle additions on structure and fretting corrosion behavior of micro-arc oxidation coatings on zirconium alloy. Surface and Coatings Technology, 2021, vol. 410, p. 126949. DOI: 10.1016/j.surfcoat.2021.126949.