Analysis of the applicability of rare earth magnets RE–TM–B and RE–TM for magnetocaloric cooling (review)

Korolev D.V., Valeev R.A., Piskorsky V.P., Morgunov R.B.
UDC
621.317.411
DOI
10.18577/2307-6046-2023-0-4-60-68
Article PDF (Russian) (609.52 KB)
How to cite
Korolev D.V., Valeev R.A., Piskorsky V.P., Morgunov R.B. Analysis of the applicability of rare earth magnets RE–TM–B and RE–TM for magnetocaloric cooling (review) // Proceedings of VIAM. 2023. No. 4. DOI: 10.18577/2307-6046-2023-0-4-60-68. URL: https://test.viam.ru/en/journal/2023/4/6
Keywords
ferromagnet, adiabatic and isothermal demagnetization, spins, exchange interaction, heat transfer, entropy
Abstract

Various aspects of the use of RE–TM–B alloys for the development of magnetocaloric cooling systems are considered. Thermodynamic analysis of temperature variations, magnetic part of entropy, internal energy and mechanical work performed in the Carnot cycle is given. The analysis of such factors as the limiting frequency of cycles, thermal conductivity and heat capacity of the working fluid, the density of particles with spin is given. The possibilities of creating hybrid magnetocaloric machines in which the transition between the para- and ferromagnetic states of rare-earth alloys are stimulated by external influences: temperature, mechanical stresses, laser and current remagnetization are discussed.

Reference list
  1. Warburg E. Magnetische Untersuchungen. Magnetische Untersuchungen. Annalen Der Physik, 1881, vol. 249, no. 5, pp. 141–164.
  2. Andreenko A.S., Belov K.P., Nikitin S.A., Tishin A.M. Magnetocaloric effects in rare earth magnets. Uspekhi fizicheskikh nauk, 1989, vol. 158, is. 4, pp. 553–579.
  3. Brown G.V. Magnetic heat pumping near room temperature. Journal of Applied Physics, 1976, vol. 47, no. 8, pp. 3673–3680.
  4. Fast R.W. Advances in Cryogenic Engineering. Proceedings of the 1989 Cryogenic Engineering Conference, 1990, vol. 35, part A, pp. 517–599.
  5. Zimm C., Jastrab A., Sternberg A. et al. Description and Performance of a Near-Room Temperature Magnetic Refrigerator. Advances in Cryogenic Engineering, 1998, vol. 43, рр. 1759–1766.
  6. Gschneidner K.A. (Jr.), Pecharsky V.K. Thirty years of near room temperature magnetic cooling: Where we are today and future prospects. International Journal of Refrigeration, 2008, vol. 31, pp. 945–961.
  7. Tishin A.M., Spichkin Y.I. The Magnetocaloric Effect and its Applications. IOP Publishing Ltd., 2003, 463 p.
  8. Dankov S.Y., Tishin A.M., Pecharsky V.K., Gschneidner K.A. Magnetic phase transitions and the magnetothermal properties of gadolinium. Physical Review B, 1998, vol. 57, no. 6, pp. 3478–3490.
  9. Gschneidner K.A., Pecharsky V.K., Gailloux M.J., Takeya H. Utilization of the Magnetic Entropy in Active Magnetic Regenerator Materials. Advances in Cryogenic Engineering, 1996, vol. 42, pp. 465–474.
  10. Chernyshov A.S., Tsokol A.O., Tishin A.M. et al. Magnetic and magnetocaloric properties and the magnetic phase diagram of single-crystal dysprosium. Physical Review B, 2005, vol. 71, no. 18, pp. 184410-1-17.
  11. Annaorazov M., Asatryan K., Myalikgulyev G. et al. Alloys of the FeRh system as a new class of working material for magnetic refrigerators. Cryogenics, 1992, vol. 32, no. 10, pp. 867–872.
  12. Guo Z.B., Du Y.W., Zhu J.S. et al. Large Magnetic Entropy Change in Perovskite-Type Manganese Oxides. Physical Review Letters, 1997, vol. 78, no. 6, pp. 1142–1145.
  13. Pecharsky V.K., Gschneidner K.A. (Jr.) Giant Magnetocaloric Effect in Gd5(Si2Ge2). Physical Review Letters, 1997, vol. 78, no. 23, pp. 4494–4497.
  14. Pecharsky V.K., Gschneidner K.A. Tunable magnetic regenerator alloys with a giant magnetocaloric effect for magnetic refrigeration from 20 to 290 K. Applied Physics Letters, 1997, vol. 70, no. 24, pp. 3299–3301.
  15. Morellon L., Magen C., Algarabel P.A. et al. Magnetocaloric effect in Tb5(SixGe1–x)4. Applied Physics Letters, 2001, vol. 79, no. 9, pp. 1318–1320.
  16. Wada H., Tanabe Y. Giant magnetocaloric effect of MnAs1–xSbx. Applied Physics Letters, 2001, vol. 79, no. 20, pp. 3302–3304.
  17. Fujita A., Fujieda S., Hasegawa Y., Fukamichi K. Itinerant-electron metamagnetic transition and large magnetocaloric effects in La(FexSi1–x)13 compounds and their hydrides. Physics Review B, 2003, vol. 67, no. 10, pp. 104416-1-12.
  18. Tegus O., Brück E., Buschow K.H.J., de Boer F.R. Transition-metal-based magnetic refrigerants for room-temperature applications. Nature, 2002, vol. 415, no. 10, pp. 150–152.
  19. Albertini F., Canepa F., Cirafici S. et al. Composition dependence of magnetic and magnetothermal properties of Ni–Mn–Ga shape memory alloys. Journal of Magnetism and Magnetic Materials, 2004, pp. 2111–2112.
  20. Gschneidner K.A. (Jr.), Pecharsky V.K., Tsokol A.O. Recent developments in magnetocaloric materials. Reports on Progress in Physics, 2005, vol. 68, no. 6, pp. 1479–1539.
  21. Korolev D.V., Piskorskii V.P., Valeev R.A., Bakradze M.M., Dvoretskaya E.V., Koplak O.V., Morgunov R.B. Rare-earth RE–TM–B micromagnets engineering (review). Aviation materials and technology, 2021, no. 1 (62), paper no. 05. Available at: http://www.journal.viam.ru (accessed: November 05, 2022). DOI: 10.18577/2713-0193-2021-0-1-44-60.
  22. Koplak O.V., Kunitsyna E.I., Valeev R.A., Korolev D.V., Piskorskii V.P., Morgunov R.B. Ferromagnetic microwires α-Fe/(PrDy)(FeCo)B for micromanipulators and polymer composites. Trudy VIAM, 2019, no. 11 (83), paper no. 07. Available at: http://www.viam-works.ru (accessed: November 05, 2022). DOI: 10.18577/2307-6046-2019-0-11-60-67.
  23. Morgunov R.B., Koplak O.V., Talantsev A.D., Korolev D.V., Piskorskij V.P., Valeev R.A. The phenomenology of the magnetic hysteresis loops in multilayer microwires α-Fe/DyPrFeCoB. Trudy VIAM, 2019, no. 7 (79), paper no. 08. Available at: http://www.viam-works.ru (accessed: November 05, 2022). DOI: 10.18577/2307-6046-2019-0-7-67-75.
  24. Kablov E.N., Startsev V.O. Measurement and forecasting of materials samples’ temperature during weathering in different climatic zones. Aviacionnye materialy i tehnologii, 2020, no. 4 (61), pp. 47–58. DOI: 10.18577/2071-9140-2020-0-4-47-58.
  25. Piskorsky V.P., Valeev R.A., Korolev D.V., Morgunov R.B., Rezchikova I.I. Terbium and gadolinium dopin g influence on thermal stability and magnetic properties of sintered magnets Pr–Tb–Gd–Fe–Co–B. Trudy VIAM, 2019, no. 7 (79), paper no. 07. Available at: http://www.viam-works.ru (accessed: November 06, 2022). DOI: 10.18577/2307-6046-2019-0-7-59-66.