Analysis of high purity nickel by glow discharge high resolution mass spectrometry

Alekseev A.V., Yakimovitch P.V.
UDC
543.51: 669.1
DOI
10.18577/2307-6046-2023-0-9-122-131
Article PDF (Russian) (727.42 KB)
How to cite
Alekseev A.V., Yakimovitch P.V. Analysis of high purity nickel by glow discharge high resolution mass spectrometry // Proceedings of VIAM. 2023. No. 9. DOI: 10.18577/2307-6046-2023-0-9-122-131. URL: https://test.viam.ru/en/journal/2023/9/11
Keywords
high resolution glow discharge mass spectrometry, nickel, nickel alloys, determination of harmful impurities
Abstract

The impurities of 68 elements in high (5N) purity nickel were determined by the method of high-resolution glow discharge mass spectrometry. Sample preparation for analysis is described. To achieve maximum analytical signals from all the required elements, the appropriate equipment settings were selected. Spectral interferences are eliminated by applying high resolution. Relative sensitivity coefficients were calculated for all analyzed elements using a standard nickel sample.

Reference list
  1. Bondarenko Yu.A. Trends in the development of high-temperature metal materials and technologies in the production of modern aircraft gas turbine engines. Aviacionnye materialy i tehnologii, 2019, no. 2 (55), pp. 3–11. DOI: 10.18577/2071-9140-2019-0-2-3-11.
  2. Min P.G., Vadeev V.E., Kramer V.V. The development of the new VZhM200 superalloy and the technology of its production for casting of the advanced engines’ blades by the directional crystallization. Aviation materials and technologies, 2021, no. 3 (64), paper no. 02. Available at: http://www.journal.viam.ru (accessed: June 01, 2023). DOI: 10.18577/2071-9140-2021-0-3-11-18.
  3. Svetlov I.L., Petrushin N.V., Epishin A.I., Karashaew M.M., Elyutin E.S. Single crystals of nickel-based superalloys alloyed with rhenium and ruthenium (review). Part 2. Aviation materials and technologies, 2023, no. 2 (71), paper no. 01. Available at: http://www.journal.viam.ru (accessed: June 01, 2023). DOI: 10.18577/2071-9140-2023-0-2-3-22.
  4. Gorbovets M.A., Hodinev I.A., Ryzhkov P.V. Low-cycle fatigue at high temperatures of heat-resistant nickel-based alloy manufactured by selective laser melting. Aviacionnye materialy i tehnologii, 2019, no. 4 (57), pp. 65–73. DOI: 10.18577/2071-9140-2019-0-4-65-73.
  5. Yoon Y.Y., Lee K.Y., Lee G.H. Neutron activation analysis of high purity nickel by solvent extraction using 2-benzylpyridin/benzene. Journal of Radioanalytical and Nuclear Chemistry. 1996, vol. 210, no. 1, pp. 55–63.
  6. State Standart 849–2018. Nickel is primary. Specifications. Moscow: Standinform, 2018, pp. 3–4.
  7. Kablov E.N., Cabina E.B., Morozov G.A., Muravskaya N.P. Assessment of compliance of new materials using high -level CO and MI. Kompetentnost, 2017, no. 2, pp. 40–46.
  8. State Standart 6689.1–92. Nickel, nickel and copper-nickel alloys. Methods for determining copper. Moscow: Publ. House of Standards, 1992, pp. 8–9.
  9. State Standart 6689.5–92. Nickel, nickel and copper-nickel alloys. Methods for determining iron. Moscow: Publ. House of Standards, 1992, pp. 1–4.
  10. State Standart 6689.12–92. Nickel, nickel and copper-nickel alloys. Methods for determining magnesium. Moscow: Publ. House of Standards, 1992, pp. 5–6.
  11. State Standart 6012–98. Nickel. Methods of chemical-atom-emission analysis. Minsk: Publishing House of Standards, 1999, рр. 1–4.
  12. ASTM E2594–09. Standard Test Method for Analysis of Nickel Alloys by Inductively Coupled Plasma Atomic Emission Spectrometry. USA, 2014, рр. 1–9.
  13. Hu J., Wang H. Determination of Trace Elements in Super Alloy by ICP-MS. Mikrochimica Acta, 2001, vol. 137, рр. 149–155.
  14. Pyupishev A.A., Epova E.N. The spectral interference of polyiatomic ions in the method of mass spectrometry with inductively connected plasma. Analitika i kontrol, 2001, vol. 5, no. 4, pp. 335–369.
  15. Jakubowski N., Prohaska T., Rottmann L., Vanhaecke F. Inductively coupled plasma- and glow discharge plasma-sector field mass spectrometry. Part I. Tutorial: Fundamentals and instrumentation. Journal of Analytical Atomic Spectrometry. 2011, vol. 26, pp. 693–726.
  16. Ganeyev A.A., Gubal A.R., Uskov K.N., Potapov S.V. Analytical mass spectrometry with a smoldering category. Izvestiya Akademii nauk. Seriya khimicheskaya, 2012, no. 4, pp. 1–15.