Shape memory epoxy polymers

Lyubimova A.S., Tkachuk A.I., Kuznetcova P.A.
UDC
678.6
DOI
10.18577/2307-6046-2024-0-4-50-63
Article PDF (Russian) (829.32 KB)
How to cite
Lyubimova A.S., Tkachuk A.I., Kuznetcova P.A. Shape memory epoxy polymers // Proceedings of VIAM. 2024. No. 4. DOI: 10.18577/2307-6046-2024-0-4-50-63. URL: https://test.viam.ru/en/journal/2024/4/4
Keywords
shape memory polymers, epoxy resins, epoxy shape memory polymers
Abstract

A review of research and development related to a class of smart shape memory materials based on epoxy oligomers that can change and recovery a shape in response to various external factors is presented. High-performance shape memory epoxy polymers with high strength, toughness and heat resistance open new possibilities for various applications, offering great prospects for development in many fields of science and technology in the future. The development of the world economy is impossible without the use of new technologies in the aerospace industry, the aviation industry, and the biomedical industry

Reference list
  1. Zhou Y., Huang W.M. Shape memory effect in polymeric materials: mechanisms and optimization. Procedia IUTAM, 2015, vol. 12, pp. 83–92.
  2. Kablov E.N. The role of chemistry in the creation of new generation materials for complex technical systems. Proc. XX Mendeleev Congress on General and Applied Chemistry. Ekaterinburg: Ural Branch of the Russian Academy of Sciences, 2016, pp. 25–26.
  3. Souri M., Lu Y.C., Erol A. et al. Characterization of unconstraint and constraint shape recoveries of an epoxy based shape memory polymer. Polymer Testing, 2015, vol. 41, pp. 231–238.
  4. Leng J., Lan X., Liu Y., Du S. Shape-memory polymers and their composites: stimulus methods and applications. Progress in Materials Science, 2011, vol. 56, no. 7, pp. 1077–1135.
  5. Lendlein A., Kelch S. Shape‐memory polymers. Angewandte Chemie International Edition, 2002, vol. 41, no. 12, pp. 2034–2057.
  6. Xia Y., He Y., Zhang F., Leng J. A review of shape memory polymers and composites: mechanisms, materials, and applications. Advanced materials, 2021, vol. 33, no. 6, p. 2000713.
  7. Kablov E.N. Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030». Aviacionnye materialy i tehnologii, 2015, no. 1 (34), pp. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
  8. Kablov E.N. New Generation Materials and Technologies for Their Digital Processing. Herald of the Russian Academy of Sciences, 2020, no. 90, pp. 225–228.
  9. Fan M., Yu H., Li X. et al. Thermomechanical and shape-memory properties of epoxy-based shape-memory polymer using diglycidyl ether of ethoxylated bisphenol-A. Smart materials and structures, 2013, vol. 22, no. 5, p. 055034.
  10. Jo M.J., Choi H., Jang H. et al. Preparation of epoxy-based shape memory polymers for deployable space structures using diglycidyl ether of ethoxylated bisphenol-A. Journal of Polymer Research, 2019, vol. 26, pp. 1–6.
  11. Tkachuk A.I., Lyubimova A.S., Kuznetcova P.A. Opportunities of the development of plant-based epoxy resins (review). Trudy VIAM, 2022, no. 8 (114), paper no. 04. Available at: http://www.viam-works.ru (accessed: November 08, 2023). DOI: 10.18577/2307-6046-2022-0-8-49-64.
  12. Liu T., Hao C., Wang L. et al. Eugenol-derived biobased epoxy: shape memory, repairing, and recyclability. Macromolecules, 2017, vol. 50, no. 21, pp. 8588–8597.
  13. Santiago D., Guzman D., Ferrando F. et al. Bio-based epoxy shape-memory thermosets from triglycidyl phloroglucinol. Polymers, 2020, vol. 12, no. 3, pp. 542.
  14. Zheng N., Fang G., Cao Z. et al. High strain epoxy shape memory polymer. Polymer Chemistry, 2015, vol. 6, no. 16, pp. 3046–3053.
  15. Shape memory polymer and adhesive combination and methods of making and using the same: pat. US 8685528 B2; appl. 15.04.09; publ. 12.11.09.
  16. Shape memory epoxy polymers: pat. US 8618238 B2; appl. 04.10.07; publ. 23.10.08.
  17. Polymer systems with multiple shape memory effect: pat. US 8641850 B2; appl. 02.03.09; publ. 04.02.10.
  18. Shape memory material on the basis of a structural adhesive: pat. EP 2553034 B2; appl. 25.03.11; publ. 06.02.13.
  19. Shape memory polymer which functions as a reversible dry adhesive and methods of making and using the same: pat. US 20140069578 A1; appl. 13.09.12; publ. 13.03.14.
  20. Multi-shape product: pat. US 9878487 B2; appl. 03.03.11; publ. 08.09.11.
  21. Fan M., Liu J., Li X. et al. Thermal, mechanical and shape memory properties of an intrinsically toughened epoxy/anhydride system. Journal of Polymer Research, 2014, vol. 21, pp. 1–8.
  22. Brändle A., Khan A. Thiol-epoxy ‘click’ polymerization: efficient construction of reactive and functional polymers. Polymer Chemistry, 2012, vol. 3, no. 12, pp. 3224–3227.
  23. Yakacki C.M., Willis S., Luders C., Gall K. Deformation limits in shape memory polymers. Advanced Engineering Materials, 2008, vol. 10, no. 1–2, pp. 112–119.
  24. Flores M., Tomuta A., Fernandez-Francos X. A new two-stage curing system: Thiol-ene/epoxy homopolymerization using an allyl terminated hyperbranched polyester as reactive modifier. Polymer, 2013, vol. 54, no. 21, pp. 5473–5481.
  25. Belmonte A., Guzman D., Fernandez-Francos X., De la Flor S. Effect of the network structure and programming temperature on the shape-memory response of thiol-epoxy “click” systems. Polymers, 2015, vol. 7, no. 10, pp. 2146–2164.
  26. Kumar K.S.S., Khatwa A.K., Nair C.P.R. High transition temperature shape memory polymers (SMPs) by telechelic oligomer approach. Reactive and Functional Polymers, 2014, vol. 78, pp. 7–13.
  27. Luetzen H., Gesing T.M., Kim B.K., Hartwig A. Novel cationically polymerized epoxy/poly
  28. (ɛ-caprolactone) polymers showing a shape memory effect. Polymer, 2012, vol. 53, no. 26, pp. 6089–6095.
  29. Kablov E.N., Valueva M.I., Zelenina I.V., Khmelnitskiy V.V., Aleksashin V.M. Carbon plastics based on benzoxazine oligomers – perspective materials. Trudy VIAM, 2020, no. 1, paper no. 07. Available at: http://www.viam-works.ru (accessed: November 08, 2023). DOI: 10.18577/2307-6046-2020-0-1-68-77.
  30. Deev I.S., Zhelezina G.F., Lonsky S.L., Kurshev E.V. Features of forming of the microstructure of the polymeric matrix in organoplasty on the basis of the multicomponent epoxy binding. Trudy VIAM, 2019, no. 5 (77), paper no. 03. URL: http://www.viam-works.ru (accessed: February 08, 2024). DOI: 10.18577/2307-6046-2014-0-7-6-6.
  31. Rimdusit S., Lohwerathama M., Hemvichian K. et al. Shape memory polymers from benzoxazine-modified epoxy. Smart materials and structures, 2013, vol. 22, no. 7, p. 075033.
  32. Xie F., Huang L., Leng J., Liu Y. Thermoset shape memory polymers and their composites. Journal of Intelligent Material Systems and Structures, 2016, vol. 27, no. 18, pp. 2433–2455.
  33. Basit A., L’Hostis G., Pac M.J., Durand B. Thermally activated composite with two-way and multi-shape memory effects. Materials, 2013, vol. 6, no. 9, pp. 4031–4045.
  34. Fejős M., Karger-Kocsis J., Grishchuk S. Effects of fibre content and textile structure on dynamic-mechanical and shape-memory properties of ELO/flax biocomposites. Journal of Reinforced Plastics and Composites, 2013, vol. 32, no. 24, pp. 1879–1886.
  35. Lu H., Liang F., Gou J., Leng J. et al. Synergistic effect of Ag nanoparticle-decorated graphene oxide and carbon fiber on electrical actuation of polymeric shape memory nanocomposites. Smart Materials and Structures, 2014, vol. 23, no. 8, p. 085034.
  36. Luo H., Zhou X., Xu Y. et al. Multi-stimuli triggered self-healing of the conductive shape memory polymer composites. Pigment & Resin Technology, 2018, vol. 47, no. 1, pp. 1– 6.
  37. Kablov E.N., Startsev V.O. Systematical analysis of the climatics influence on mechanical properties of the polymer composite materials based on domestic and foreign sources (review). Aviacionnye materialy i tehnologii, 2018, no. 2 (51), pp. 47–58. DOI: 10.18577/2071-9140-2018-0-2-47-58.
  38. Petrova A.P., Donskoy A.A. Adhesive materials. Sealants. St. Petersburg: Professional, 2008, 589 p.
  39. Isaev A.Yu., Rubtsova E.V., Kotova E.V., Sutyagin M.N. Research of properties of glues and glue binding, made with use of modern domestic component base. Trudy VIAM, 2021, no. 3 (97), paper no. 05. Available at: http://www.viam-works.ru (accessed: January 25, 2023). DOI: 10.18577/2307-6046-2021-0-3-58-67.