Technological features of carbon fibers production on the basis of oil mesophase pitches
Vikulin V.V., Shavnev A.A., Sidorov D.V., Kurbatkina E.I., Pastukh E.S. Technological features of carbon fibers production on the basis of oil mesophase pitches // Proceedings of VIAM. 2025. No. 11. DOI: 10.18577/2307-6046-2025-0-11-50-60. URL: https://test.viam.ru/en/journal/2025/11/5
Keywords
carbon fibers, pitch, mesophase, domains, polyacrylonitrile (PAN), crystal lattice, forming, dies, oxidative thermal stabilization, carbonization, graphitization, strength, elastic modulus
Abstract
A comparative analysis of physical and technical characteristics of carbon fibers produced from petroleum mesophase pitches and polyacrylonitrile is carried out. The fields of application of pitch carbon fibers are presented. An explanation of some features of the technologies influencing the achievement of unique properties of carbon pitch fibers is presented. An explanation of the reasons for the lower strength of carbon fibers based on mesophase pitches compared to the strength of carbon fibers based on polyacrylonitrile is given. New fields of application of carbon fibers based on carbon pitches are recommended.
Reference list
- Goncharov K., Panin Yu., Balykin M., Khmelnitsky A. High Thermal Conductive Carbon Fiber Radiators with Controlled Loop Heat Pipes. 46th International Conference on Enviromental Systems (Vienna, Austria, 10–14 July, 2016). Vienna, 2016, pp. 1–6.
- Sharipov A., Budnik B., Zhirnov V. Modern trends in the development of the market of carbon fibers based on petroleum feedstock. Neftepererabotka i neftekhimiya, 2012, no. 6, pp. 30–34.
- The Global Outlook for Carbon Fiber Composites: Expansion as a Result of Efficiency and Productivity. San Diego, CA, 2009, Part 3, 116 p.
- Method for producing mesophase pitch (variants): pat. 2708848 Rus. Federation; appl. 14.06.16; publ. 11.12.19.
- Gulyaev I.N., Pavlovskiy K.A. High modulus carbon plastics for civil aviation equipment (review). Trudy VIAM, 2023, no. 3 (121), paper no. 09. Available at: http://www.viam-works.ru (accessed: March 21, 2025). DOI: 10.18577/2307-6046-2023-0-3-95-106.
- Kolobkov A.S. Polymer composite materials for various aircraft structures (review). Trudy VIAM, 2020, no. 6–7 (89), paper no. 05. Available at: http://www.viam-works.ru (accessed: March 21, 2025). DOI: 10.18577/2307-6046-2020-0-67-38-44.
- High modulus, high strength carbon fibers produced from mesophase pitch: pat. 4005183 US; appl. 05.03.73; publ. 25.01.77.
- Konkin A.A. Carbon and other heat-resistant fibrous materials. Moscow: Khimiya, 1974, 375 p.
- Varshavsky V.Ya. Carbon fibers. Moscow: Varshavsky V.Ya., 2007, 497 p.
- Bermudez V., Lurubira S., Ogale A.A. Pith Precursor-Based Carbon Fibers. Comprehensive Composite Materials II, 2018, vol. 1, pp. 41–65.
- Emmerich F.G. Young’s modulus, thermal conductivity, electrical resistivity and coefficient of thermal expansion of mesophase pitch-based carbon fibers. Carbon, 2014, no. 79, pp. 274–293. DOI: 10.1016/j.carbon.2014.07.068.
- Process for producing carbon fibers from mesophase pitch: pat. 3974264 US; appl. 31.10.74; publ. 10.08.76.
- Process for producing mesophase pitch: pat. 4026788 US; appl. 11.12.73; publ. 31.05.77.
- Abramov O.N., Sidorov D.V., Apukhtina T.L., Khramkova V.A. Production of pitch carbon fiber based on petroleum feedstock. Izvestiya vuzov. Khimiya i khimicheskaya tekhnologiya, 2015, vol. 58 (5), pp. 86–89.
- Lu Xi Lan. Production of carbon fiber based on mesophase pitch: thesis abstract, Cand. Sc. (Tech.) thesis. Moscow, 1996, 17 p.
- High-temperature stabilization of pitch fibers at low oxidizer concentrations: pat. 2198969 Rus. Federation; appl. 01.04.98; publ. 20.02.03.
- Diefendorf R.J. Pith precursor carbon fibers. Comprehensive Composite Materials. Oxford, 2000, pp. 35–83. DOI: 10.1016/B0-08-042993-9/00041-3.
- Matsumoto T. Mesophase pith and its carbon fibers. Pure & Applied Chemistry, 1985, vol. 57, no. 11, pp. 1553–1562. DOI: 10.1351/pac198557111553.
- Bermudes V., Ogale A.A. Adverse effect of mesophase pith draw-down ratio on carbon fibers strength. Carbon, 2020, vol. 168, pp. 328–336. DOI: 10.1016/j.carbon.2020.06.062.
- Hawthorne H.M., Baker C., Bentall R.H., Linger K.P. High Strength, high modulus graphite fibers from pith. Nature, 1970, no. 227, pp. 946–947. DOI: 10.1038/227946a0.
- Process for producing mesophase pitch: pat. 4017327 US; appl. 31.10.74; publ. 12.04.77.
- Forming optically anisotropic pitches: pat. 4208267 US; appl. 05.05.78; publ. 17.06.80.
- Starting pitches for carbon fibers: pat. 4391788 US; appl. 09.04.82; publ. 05.07.83.
- Pitch-based carbon or graphite fiber and process for preparation thereof: pat. 4628001 US; appl. 03.04.85; publ. 09.12.86.
- Process for producing carbon fibers from mesophase pith: pat. 3976729 US; appl. 11.12.73; publ. 24.08.76.
