Magnets with high temperature stability for navigation

Potapov M.V., Buzenkov A.V., Morgunov R.B., Piskorsky V.P.
Potapov M.V., Buzenkov A.V., Morgunov R.B., Piskorsky V.P. Magnets with high temperature stability for navigation // Proceedings of VIAM. 2025. No. 12. DOI: 10.18577/2307-6046-2025-0-12-63-73. URL: https://test.viam.ru/en/journal/2025/12/6
Keywords
permanent magnets, rare-earth magnets, saturation magnetization, residual induction, coercive force, squareness factor of demagnetization curves, temperature induction coefficient, temperature coefficient coercive force
Abstract

Materials of Fe–Ni–Al–Co and Pr–Nd–Dy–Fe–Co–B systems were studied in the article. Sintering and further heat treatment in the form of high temperature annealing, cooling in a magnetic field, and a stepwise annealing were performed. The effect of heat treatment on the magnetic properties of the samples, as well as the temperature coefficient of induction were investigated. It is shown that these sintered materials are similar in magnitude to AlNiCo magnets. The negative effect of neodymium impurity on the thermal stability of the material has been revealed. In order to improve temperature stability, it is necessary to increase the cobalt content.

Reference list
  1. Matusevich V.A., Getya A.N., Sharaban Yu.V. Application of high-coercivity permanent magnets in aircraft units. Elektrotekhnika i elektromekhanika, 2006, no. 1, pp. 33–35.
  2. Cherednichenko I.V., Bavina M.A., Bondarenko Yu.A., Shurygin V.D., Ovchinnikov A.D., Galimullin S.A. Influence of directed crystallization parameters on structure and properties of Alnico 5-7 alloy permanent magnets. Trudy VIAM, 2023, no. 11 (129), paper no. 08. Available at: http://www.viam-works.ru (accessed: October 29, 2024). DOI: 10.18577/2307-6046-2023-0-11-77-89.
  3. Zhukov A.S., Zhumagalieva A.A., Khromenkov M.V. et al. Structure and properties of magnetic materials manufactured by selective laser melting. Fundamentalnye problemy sovremennogo materialovedeniya, 2020, vol. 17, no. 2, pp. 251–256. DOI: 10.25712/ASTU.111-1416.2020.02.0116.
  4. Liu Z., Miller M.K., Ping L. et al. Architecture and magnetism of alnico. Acta Materialia, 2014, vol. 74, pp. 224–233.
  5. Rehman S.U., Jiang Q., He L. et al. Synthesis, microstructures, magnetic properties and thermal stabilities of isotropic alnico ribbons. Journal of Magnetism and Magnetic Materials, 2018, vol. 466, p. 2777–2782. DOI: 010.1016/j.jmmm.2018.07.020.
  6. Bin S., Bingbing L., Chunhong L. et al. Microstructure and distribution of low content elements in AlNiCo 9. Materials Science Forum, 2017, vol. 898, pp. 1669–1674.
  7. Sajjad U.R., Qingzheng J., Qiulan T. et al. Evolution of microstructure, magnetic properties and thermal stabilities of isotropic alnico ribbons. IEEE Transactions on Magnetics, 2020, vol. 56, no. 2, pp. 127–132.
  8. Vasilevsky N.I. Development of a dynamically adjustable gyroscope taking into account its vibration characteristics. Miass: South Ural State Univ., 2018, 77 p.
  9. Chirkin D.S., Roslovets P.V., Tatarinov F.V. et al. Reducing the drift of a dynamically tuned gyroscope from launch to launch. Inzhenerniy zhurnal: nauka i innovatsii, 2017, no. 1, pp. 1–14. DOI: 10.18698/2308-6033-2017-01-1579.
  10. Kablov E.N., Ospennikova O.G., Piskorskij V.P. et al. Ring magnets with radial texture for dynamically tuned gyroscopes. Aviacionnye materialy i tehnologii, 2014, no. S5, pp. 89–94. DOI: 10.18577/2071-9140-2014-0-s5-89-94.
  11. Jianjun T., Huanhui Q., Shengen Z. et al. Magnetic properties and microstructure of radially oriented Sm(Co, Fe, Cu, Zr)Z ring magnets. Materials Letters, 2007, vol. 61, pp. 5271–5274.
  12. Anhua L., Wei L., Huijie W. et al. The study on thermal expansion of sintered Sm2Co17 magnets. IEEE Transaction on Magnetics, 2009, vol. 45, no. 10, pp. 4402–4404.
  13. Gorlov D.S., Cherednichenko I.V., Valeev R.A., Chesnokov D.V. Improving the corrosion resistance of RЕM–Fe–B magnets. Trudy VIAM, 2021, no. 10 (104), paper no. 10. Available at: http://www.viam-works.ru (accessed: October 29, 2024). DOI: 10.18577/2307-6046-2021-0-10-97-107.
  14. Demin S.A., Zavarzin S.V., Cherednichenko I.V., Kozlov I.A. Protective anticorrosive coating of magnets of the REM–Fe–B system. Trudy VIAM, 2022, no. 6 (112), paper no. 08. Available at: http://www.viam-works.ru (accessed: October 29, 2024). DOI: 10.18577/2307-6046-2022-0-6-96-107.
  15. Pedziwiatr A.T., Wallace W.E. Structure and magnetism of the R2Fe14–xCoxB ferromagnetic Systems (R=Dy and Er). Journal of Magnetism and Magnetic Materials, 1986, vol. 66, pp. 63–68.
  16. Kablov E.N., Ospennikova O.G., Rezchikova I.I., Valeev R.A. et al. Comparison of the temperature stability of SmCo and PrDy–FeCo–B magnets. Aviacionnye materialy i tehnologii, 2015, no. S2 (39), pp. 42–46. DOI: 10.18577/2071-9140-2015-0-S2-42-46.
  17. Meeran R., Kamal R. A Mossbauer spectroscopic study of Nd2(Fe1-xCox)B at x = 0,13 between 100 K and 700 K. Journal of the Less-Common Metals, 1987, vol. 128, pp. 343–350.
  18. Zubair A., Shan T., Mozaffar H. Tailoring magnetic properties in 60Fe–27Co–2Mo–1Ti magnetic alloy by Ni and Hf additive. Journal of Magnetism and Magnetic Materials, 2021, vol. 538, p. 169257. DOI: 10.1016/j.jmmm.2021.168266.
  19. Efremov D.B., Gerasimova A.A. Production of magnets from the material of the Fe–Cr–Co system by selective laser sintering. Izvestiya vysshikh uchebnykh zavedeniy. Chernaya metallurgiya, 2021, vol. 64, no. 10, pp. 721–727. DOI: m10.17073/0368-0797-2021-10-721-727.
  20. Generalova K.N. Regularities of phase transformations and properties of powder magnetic materials based on the Fe–Cr–Co–Si system and non-stoichiometric Cu–Au alloy: thesis, Cand. Sc. (Tech.). Perm: Publ. House of PNIPU, 2019, 138 p.
  21. Marinescu M., McGinnis K., Liu J.F. et al. High (BH)max permanent magnets with near-zero reversible temperature coefficient of BR. Proceedings of 20th International Workshop on rare earth permanent magnets and their applications. Grete, 2008, pp. 1–6.
  22. Ray A.E. Metallurgical behavior of Sm(Co, Fe, Cu, Zr)z alloys. Journal of Applied Physics, 1984, vol. 55, pp. 2094–2096.
  23. Masato S., Setsuo F., Hitoshi Y. et al. Permanent magnet materials based on the rare earth-iron-boron tetragonal compounds. IEEE Transactions on Magnetics, 1984, vol. 20, pp. 1584–1589.
  24. Jiang S.Y., Chen H.Y., Cheng S.F. et al. Magnetic properties of R–Fe–B and R–Fe–Co–Al–B magnets (R=Pr and Nd). Journal of Applied Physics, 1988, vol. 64, pp. 5510–5512.
  25. Piskorsky V.P., Burkhanov G.S., Ospennikova O.G. et al. Calculation of the temperature coefficient of induction of nanostructured magnetic hard materials Pr–Dy–Fe–Co–B by the molecular field method. Metally, 2010, no. 1, pp. 64–67.
  26. Kablov E.N., Antipov V.V. The role of new generation materials in ensuring the technological sovereignty of the Russian Federation. Vestnik Rossiyskoy akademii nauk, 2023, vol. 93, no. 10, pp. 907–916.
  27. Herbst J.F. R2Fe14B materials: intrinsic properties and technological aspects. Reviews of Modern Physics, 1991, vol. 63, no. 4, pp. 819–898.
  28. Faria R.N., Davies B.E., Brown D.N. et al. Microstructural and magnetic studies of cast and annealed Nd and PrFeCoBZr alloys and HDDR materials. Journal of Alloys and Compounds, 2000, vol. 296, pp. 223–228.
  29. Valeev R.A., Korolev D.V., Morgunov R.B., Piskorsky V.P. The effect of high concentrations of cobalt on the properties of magnets Pr–Dy–Fe–Co–B and Nd–Dy–Fe–Co–B. Trudy VIAM, 2022, no. 10 (116), paper no. 06. Available at: http://www.viam-works.ru (accessed: October 29, 2024). DOI: 10.18577/2307-6046-2022-0-10-66-75.
  30. Kablov E.N. Trends and guidelines for innovative development of Russia: collection of information materials. 3rd ed., rev. and add. Moscow: VIAM, 2015, 720 p.