Features of quench-induced precipitation in sheets of V-1341 aluminum alloy of Al–Mg–Si system
Benarieb I., Sbitneva S.V., Zaysev D.V., Shorstov S.Yu. Features of quench-induced precipitation in sheets of V-1341 aluminum alloy of Al–Mg–Si system // Proceedings of VIAM. 2025. No. 8. DOI: 10.18577/2307-6046-2025-0-8-53-66. URL: https://test.viam.ru/en/journal/2025/8/5
Keywords
Al–Mg–Si alloys, quench sensitivity, thermodynamic modeling, quench-induced precipitation, dispersoids, solid solution decomposition, transmission electron microscopy, differential scanning calorimetry
Abstract
This study focuses on the quench sensitivity of sheets made of V-1341 aluminum alloy of the Al–Mg–Si system. Using transmission electron microscopy, energy-dispersive X-ray spectroscopy), differential scanning calorimetry, and thermodynamic modeling, some features of precipitate formation during slow quenching (below the critical cooling rate) were examined. It has been determined that quench-induced precipitates form on the surface of α-phase dispersoids (Al15(Mn, Fe)3Si2) as coarse rod-like precipitates of β-type phases, with some inclusions potentially containing copper.
Reference list
- Kolobnev N.I., Ber L.B., Tsukrov S.L. Heat treatment of deformable aluminum alloys. Ed. E.N. Kablov. Moscow: APRAL, 2020, 551 p.
- Ostermann F. Technology of aluminum application. Moscow: APRAL, 2019, 872 p.
- Lumley R. Fundamentals of aluminium metallurgy: recent advances. Cambridge: Woodhead Publishing, 2018, 578 р.
- Benarieb I., Ber L.B., Antipov K.V., Sbitneva S.V. Trends in development of wrought alloys of Al–Mg–Si–(Cu) system. Part 1 (review). Aviacionnye materialy i tehnologii, 2019, no. 3 (56), pp. 14–22. DOI: 10.18577/2071-9140-2019-0-3-14-22.
- Ovchinnikov V.V. Prospects for the Development of High-Tech Deformable Aluminum Alloys for Welded Structures. Part 2. Mashinostroenie i inzhenernoe obrazovaniy, 2017, no. 3, рр. 22–39.
- Kolobnev N.I., Ber L.B., Khokhlatova L.B., Ryabov D.K. Structure, Properties, and Application of Al–Mg–Si–(Cu) System Alloys. Metallovedenie i termicheskaya obrabotka metallov, 2011, no. 9, pp. 40–45.
- Nefedova Yu.N., Shlyapnikova T.A., Ivanov A.L., Sedelnikov V.V. Methods for reducing residual stresses during hardening of high-strength aluminum alloys. Trudy VIAM, 2023, no. 7 (125), paper no. 03. Available at: http://www.viam-works.ru (accessed: May 06, 2025). DOI: 10.18577/2307-6046-2023-0-7-23-33.
- Benarieb I., Puchkov Yu.A., Sbitneva S.V., Shorstov S.Yu., Shumeyko R.M. Quench sensitivity of wrought heat-treatable aluminum alloys of the Al–Mg–Si system (review). Trudy VIAM, 2025, no. 2 (144), paper no. 03. Available at: http://www.viam-works.ru (accessed: May 06, 2025). DOI: 10.18577/2307-6046-2025-0-2-25-46.
- Marioara C.D., Nordmark H., Andersen S.J., Holmestad R. Post-βʹʹ phases and their influence on microstructure and hardness in 6xxx Al–Mg–Si alloys. Journal of Materials Science, 2006, vol. 41, pp. 471–478.
- Marioara C.D., Andersen S., Hell C. et al. Atomic structure of clusters and GP-zones in an Al–Mg–Si alloy. Acta Materialia, 2024, vol. 269, p. 119811.
- Andersen S.J., Zandbergen H.W., Jansen J. et al. The crystal structure of the β″ phase in Al–Mg–Si alloys. Acta Materialia, 1998, vol. 46, pp. 3283–3298.
- Christiansen E., Marioara C., Holmedal B. et al. Nano-scale characterisation of sheared β′′ precipitates in a deformed A–Mg–Si alloy. Scientific Reports, 2019, vol. 9, no. 1, art. 17446.
- Sunde J.K., Marioara C.D., van Helvoort A.T.J., Holmestad R. The evolution of precipitate crystal structures in an Al–Mg–Si(–Cu) alloy studied by a combined HAADF-STEM and SPED approach. Materials Characterization, 2018, vol. 142, pp. 458–469.
- Saito T., Mortsell E.A., Wenner S. et al. Atomic structures of precipitates in Al–Mg–Si alloys with small additions of other elements. Advanced Engineering Materials, 2018, vol. 20, no. 7, p. 1800125.
- Li K., Song M., Du Y., Fang X. Effect of minor Cu addition on the precipitation sequence of an as-cast Al–Mg–Si 6005 alloy. Archives of Metallurgy and Materials, 2012, vol. 57, no. 2, pp. 458–466.
- Ohmori Y., Long C., Matsuura Y. et al. Morphology and crystallography of β-Mg2Si precipitation in Al–Mg–Si alloys. Materials Transactions, 2001, vol. 42, no. 12, pp. 2576–2583.
- Ohmori Y., Doan L.C., Nakai K. Ageing processes in Al–Mg–Si alloys during continuous heating. Materials Transactions, 2002, vol. 43, no. 2, pp. 246–255.
- Garric V., Colas K., Donnadieu P. et al. Correlation between quenching rate, mechanical properties and microstructure in thick sections of AlMgSi (Cu) alloys. Materials Science and Engineering: A, 2019, vol. 753, pp. 253–261.
- Ma Y., Liu C., Miao K. et al. Effects of cooling rate and cryogenic temperature on the mechanical properties and deformation characteristics of an Al–Mg–Si–Fe–Cr alloy. Journal of Alloys and Compounds, 2023, vol. 947, p. 169559.
- Liu S., Wang X., Pan Q. et al. Investigation of microstructure evolution and quench sensitivity of Al–Mg–Si–Mn–Cr alloy during isothermal treatment. Journal of Alloys and Compounds, 2020, vol. 826, p. 154144.
- Strobel K., Easton M., Sweet L. et al. Relating quench sensitivity to microstructure in 6000 series aluminium alloys. Materials Transactions, 2011, vol. 52, no. 5, pp. 914–919.
- Strobel K. Quench Sensitivity in 6xxx Series Aluminium Alloys: A Thesis Submitted for the Degree of Doctor of Philosophy. Clayton: Monash University, 2013, 223 р.
- Gao C., Liu X., Zhao D. et al. Recent Progress in Testing and Characterization of Hardenability of Aluminum Alloys: A Review. Materials, 2023, vol. 16, p. 4736.
- Yang M., Ruan Z., Lin H. et al. Quantified effect of quench rate on the microstructures and mechanical properties of an Al–Mg–Si alloy. Journal of Materials Research and Technology, 2023, vol. 24, pp. 6753–6761.
- Xia C., Deng S., Ni C. et al. Study on laminar structure and process on high strength brazed aluminum alloy for heat exchangers. Vacuum, 2023, vol. 215, pp. 112303.
- Fan Z., Lei X., Wang L. et al. Influence of quenching rate and aging on bendability of AA6016 sheet. Materials Science and Engineering: A, 2018, vol. 730, pp. 317–327.
- Yang Z., Mallow S., Banhart J., Kessler O. Probing precipitation in aluminium alloys during linear cooling via in-situ differential scanning calorimetry and electrical resistivity measurement. Thermochimica Acta, 2024, vol. 739, p. 179815.
- Milkereit B., Starink M.J. Quench sensitivity of Al–Mg–Si alloys: a model for linear cooling and strengthening. Materials & Design, 2015, vol. 76, pp. 117–129.
- Benarieb I., Puchkov Yu.A., Sbitneva S.V., Zaitsev D.V. Study of the decomposition of a supersaturated solid solution during quench cooling of sheets of aluminum alloy of the Al–Mg–Si system. Fizika metallov i metallovedenie, 2023, vol. 124, no. 9, pp. 838–845. DOI: 10.31857/S0015323023600843.
- Puchkov Yu.A., Polyansky V.M., Sedova L.A. Study of the influence of isothermal quenching modes on the structure and properties of aluminum alloy B-1341T. Metallovedenie i termicheskaya obrabotka metallov, 2019, no. 2, pp. 13–19.
- Sbitneva S.V., Zaytsev D.V., Benarieb I. Features of the structure of age-hardenable aluminum alloy AlSi10MgCu produced by selective laser melting. Trudy VIAM, 2024, no. 9 (139), paper no. 03. Available at: http://www.viam-works.ru (accessed: May 12, 2025). DOI: 10.18577/2307-6046-2024-0-9-15-24.
- Sbitneva S.V., Lukina E.А., Zaytsev D.V. Investigation of the features of the decomposition of a solid solution during aging of alloys of the Al–Mg–Si–Cu system. Trudy VIAM, 2021, no. 12 (106), paper no. 02. Available at: http://www.viam-works.ru (accessed: March 18, 2025). DOI: 10.18577/2307-6046-2021-0-12-14-20.
- Kablov E.N. The strategic directions of development of materials and technologies of their processing for the period to 2030. Aviacionnye materialy i tehnologii, 2012, no. S, pp. 7–17.
- Kablov E.N. Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030». Aviacionnye materialy i tehnologii, 2015, no. 1 (34), pp. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
