Possibility of obtaining ceramics based on reaction-bound silicon nitride with adjustable hardness and high heat strength characteristics

Vikulin V.V., Mukhin A.N., Kurbatkina E.I., Zaklyakova O.V.
UDC
666.3
DOI
10.18577/2307-6046-2026-0-1-124-135
Article PDF (Russian) (690.86 KB)
How to cite
Vikulin V.V., Mukhin A.N., Kurbatkina E.I., Zaklyakova O.V. Possibility of obtaining ceramics based on reaction-bound silicon nitride with adjustable hardness and high heat strength characteristics // Proceedings of VIAM. 2026. No. 1. DOI: 10.18577/2307-6046-2026-0-1-124-135. URL: https://test.viam.ru/en/journal/2026/1/9
Keywords
silicon, boron, silicon nitride, boron nitride, carbonyl nickel, ethyl silicate, borsilicate glasses, tribological tests, infrared transmission and reflection
Abstract

The article presents the features of obtaining silicon nitride-boron nitride ceramics Si3N4‒BN as a result of the joint interaction of silicon and boron with nitrogen in the presence of nickel additives with the subsequent protection of ceramics from high-temperature oxidation by the formation of borosilicate glasses and a solid substitution solution Si‒B‒O‒N in the surface layer. Some high-temperature characteristics of ceramics, the results of tribological studies and the results of tests of samples and products are given.

Reference list
  1. Langer M., Sibels J., Heindrich H. Turbinen rotoren aus nichtoxidischen keramischen Werksstoffen. Keramische komponenten fur Fahrzeug-Gasturbinen III. Berlin: Springer-Velger, 1984, pp. 419–447.
  2. Method for producing an antenna radome shell from reaction-bonded silicon nitride: pat. 2453520 Rus. Federation; appl. 20.12.10; publ. 20.06.12.
  3. Kondratieva L.A., Bichurov G.V. Chemical stages of formation of nitride composites Si3N4‒TiN, Si3N4‒BN, Si3N4‒AlN in the SHS-AZ mode. Vestnik SamGTU, 2016, no. 3 (52), pp. 130–135.
  4. Kondratieva L.A. On chemical stability and structure formation of SiN‒BN composites in the azide SHS mode. Sovremennye materialy, tekhnika i tekhnologii, 2017, no. 4 (12), pp. 22–26.
  5. Rudykina V.N., Paranosenkov V.P., Vikulin V.V. Features of producing reaction-bonded silicon nitride. Methods for producing reaction-bonded silicon nitride. Riga: Zinatne, 1980, pp. 165–166.
  6. Vikulin V.V., Kurskaya I.N., Kindinova O.N. Study of the influence of nickel on the synthesis and some properties of reaction-bonded silicon nitride. Designs and technology for producing products from non-metallic materials: in 3 parts. Moscow: VIMI, 1984, part 1: Heat-resistant ceramic materials, p. 89.
  7. Method for producing products based on silicon nitride: pat. 2239613 Rus. Federation; appl. 28.07.04; publ. 20.05.06.
  8. Vikulin V.V. Effect of additives on the synthesis mechanism and properties of reaction-bonded silicon nitride. Perspektivnye materialy, 2007, no. 5, pp. 12–15.
  9. Vikulin V.V., Chikina A.A., Borzilova V.D., Romashin A.G. Features of the synthesis of reaction-bonded silicon nitride in the presence of boron additives. Designs and technology for producing products from non-metallic materials: in 3 parts. Moscow: VIMI, 1984, part 1: Heat-resistant ceramic materials, pp. 21–23.
  10. Vikulin V.V. Structural ceramic materials with targeted properties made of silicon nitride and carbide and products made of them for aerospace engineering: thesis, Dr of Sc. (Tech.). Obninsk, 1990, 422 p.
  11. Vikulin V.V. Production of Si3N4-Based Products and Their Application in the Aerospace Industry. Perspektivnye materialy, 2006, no. 5, pp. 14–19.
  12. Vikulin V.V., Shkarupa I.L. Testing Silicon Nitride and Carbide-Based Materials under Extreme Conditions. Abstract of the 2nd Scientific and Technical Conf. «High-Temperature Ceramic Composite Materials and Protective Coatings». Moscow: VIAM, 2016, p. 26.
  13. Usherenko S.M., Ovchinnikov V.I., Shmuradko V.T., Kirshina N.V. Ceramic Material Based on Reaction-Bonded Silicon Nitride for Refractory Crucibles. Litye i metallurgiya, 2000, no. 2, pp. 26–30.
  14. Samsonov G.V. Non-metallic Nitrides. Moscow: Metallurgy, 1969, 264 p.
  15. Arnesen D. Steels Quarterly Profits So-So Nonferous Strong. Iron Age, 1980, vol. 223, no. 19, pp. 43–45.
  16. Eliot R. Structure of Binary Alloys; trans. from Engl. Moscow: Metallurgy, 1970, 928 p.
  17. Vikulin V.V., Rusanova L.N., Kuznetsova V.F., Smakhtin L.A. Study of the Effect of Heat Treatment Temperature on the Oxygen Content in Active Boron Nitride Powders by Neutron Activation Analysis. Poroshkovaya metallurgiya, 1978, no. 9, pp. 64‒70.
  18. Wild S., Elliot H., Thompson D. Combined infrared and X-ray studies of β-silicon nitride and β-sialons. Journal Material Science, 1978, vol. 13, pp. 1769–1775.