Structural features and electrochemical characteristics of orthorhombic vanadium pentoxide synthesized from technical reagents

Leonov A.A., Duyunova V.A., Trofimov N.V., Kuznetsov V.V., Cherkasov D.I., Makarenkov D.A., Rodionov N.M., Komendo I.Yu., Mihlin A.L.
UDC
621.355
DOI
10.18577/2307-6046-2026-0-5-186-197
Article PDF (Russian) (1.97 MB)
How to cite
Leonov A.A., Duyunova V.A., Trofimov N.V., Kuznetsov V.V., Cherkasov D.I., Makarenkov D.A., Rodionov N.M., Komendo I.Yu., Mihlin A.L. Structural features and electrochemical characteristics of orthorhombic vanadium pentoxide synthesized from technical reagents // Proceedings of VIAM. 2026. No. 5. DOI: 10.18577/2307-6046-2026-0-5-186-197. URL: https://test.viam.ru/en/journal/2026/5/15
Keywords
vanadium pentoxide, X-ray diffraction analysis, transmission electron microscopy, scanning electron microscopy, cyclic voltammetry, redox transition
Abstract

The study investigates the features of the synthesized orthorhombic vanadium oxide obtained through a multistage procedure from technical raw materials. It was established that the resulting vanadium oxide is characterized by strong particle aggregation with diverse morphologies, which is related to synthesis parameters. Particularly the high pH value during the precursor precipitation stage. Electrochemical studies revealed two pairs of redox transition: V (V) → V (IV) and V (IV) → V (III), and also allowed the determination of the working pH stability range (pH = 5–9).

Reference list
  1. Abrantes I., Ferreira A.F., Magalhaes L.B. et al. The impact of revolutionary aircraft designs on global aviation emissions. Renewable Energy, 2024, vol. 223, pp. 119937. DOI: 10.1016/j.renene.2024.119937.
  2. Decree of the President of the Russian Federation of November 4, 2020 No. 666 «On the Reduction of Greenhouse Gas Emissions». Available at: www.kremlin.ru/acts/bank/45990 (accessed: September 24, 2025).
  3. Order of the Government of the Russian Federation dated October 29, 2021 No. 3052-r. Available at: http://www.publication.pravo.gov.ru (accessed: September 24, 2025).
  4. Leonov A.A., Trofimov N.V. Magnesium ion batteries: prospects and challenges in the field of energy. Trudy VIAM, 2024, no. 3 (133), pp. 41–51. Available at: http://www.viam-works.ru (accessed: September 24, 2025). DOI: 10.18577/2307-6046-2024-0-3-41-51.
  5. Zhang J., Roumeliotis I., Zhang X., Zolotas A. Techno-economic-environmental evaluation of aircraft propulsion electrification: Surrogate-based multi-mission optimal design approach. Renewable and Sustainable Energy Reviews, 2023, vol. 175, pp. 442–464.
  6. Emmanouil K. Reliability in the era of electrification in aviation: A systems approach. Microelectronics Reliability, 2020, vol. 114, pp. 77–82.
  7. Kablov E.N. Aviation Materials Science in the 21st Century. Prospects and Challenges. Aviation Materials. Selected Works of VIAM 1932–2002. Moscow: MISiS – VIAM, 2002, pp. 23–47.
  8. Kablov E.N. Modern Materials – the Basis for Innovative Modernization of Russia. Metally Evrazii, 2012, no. 3, pp. 10–15.
  9. Deivanayagam R., Ingram B.J., Shahbazian-Yassar R. Progress in development of electrolytes for magnesium batteries. Energy Storage Materials, 2019, no. 21, pp. 136–153.
  10. Kablov E.N. Chemistry in Aviation Materials Science. Rossiyskiy khimicheskiy zhurnal, 2010, vol. LIV, no. 1, pp. 3–4.
  11. Bagotsky V.S. Fundamentals of Electrochemistry. Moscow: Khimiya, 1988, 400 p.
  12. Xu R., Gao X., Chen Ya. et al. Research advances of the electrolytes for rechargeable magnesium ion batteries. Materials Today Physics, 2023, no. 36, pp. 116–133.
  13. Rashad M., Asif M., Ahmed I. et al. Quest for carbon and vanadium oxide based rechargeable magnesium-ion batteries. Journal of magnesium and alloys, 2020, vol. 8, pp. 364–373.
  14. Zhang X., Li D., Ruan Q. et al. Vanadium-based cathode materials for rechargeable magnesium batteries. Materials Today Energy, 2023, no. 32, pp. 169–199.
  15. Tzu-Ho W. Controlling crystal structures of vanadium oxides via pH regulation and decoupling crystallographic perspective on zinc storage behaviors. Acta Materialia, 2022, vol. 245, p. 118663. DOI: 10.1016/j.actamat.2022.118663.
  16. Nikiforov A.A., Demin S.A., Khmeleva K.M. Electrochemical treatment of parts obtained by selective laser fusion. Trudy VIAM, 2021, no. 7 (101), pp. 3–12. Available at: http://www.viam-works.ru (accessed: September 24, 2025). DOI: 10.18577/2307-6046-2021-0-7-3-12.
  17. Sidorina A.I. Modification of the surface of carbon reinforcing fillers for polymer composite materials by electrochemical treatment (review). Trudy VIAM, 2022, no. 4 (110), pp. 61–74. Available at: http://www.viam-works.ru (accessed: September 24, 2025). DOI: 10.18577/2307-6046-2022-0-4-61-74.
  18. Kablov E.N., Startsev O.V. The basic and applied research in the field of corrosion and ageing of materials in natural environments (review). Aviacionnye materialy i tehnologii, 2015, no. 4 (37), pp. 38–52. DOI: 10.18577/2071-9140-2015-0-4-38-52.
  19. Leonov А.А., Zavarzin S.V., Trofimov N.V. On some features of the influence of the composition of the magnesium anode on its electrochemical behavior in relation to magnesium-ion batteries. Trudy VIAM, 2024, no. 6 (136), pp. 18–28. Available at: http://www.viam-works.ru (accessed: September 24, 2025). DOI: 10.18577/2307-6046-2024-0-6-18-28.