Directions for development of heat-resistant carbon fiber reinforced plastics on ba-sis of polyimide and heterocyclic polymers

Gulyaev I.N., Vlasenko F.S., Zelenina I.V., Raskutin A.E.
UDC
678.747.2
DOI
10.18577/2307-6046-2014-0-1-4-4
Article PDF (Russian) (510.62 KB)
How to cite
Gulyaev I.N., Vlasenko F.S., Zelenina I.V., Raskutin A.E. Directions for development of heat-resistant carbon fiber reinforced plastics on ba-sis of polyimide and heterocyclic polymers // Proceedings of VIAM. 2014. No. 1. DOI: 10.18577/2307-6046-2014-0-1-4-4. URL: https://test.viam.ru/en/journal/2014/1/4
Abstract

The main tendencies of development of receiving high-temperature polymeric com-posite materials, in particular carbon plastics are considered. Perspective types of the polymers, allowing to provide heat resistance to 400°С and technologies of receiving products on their basis are considered. The main directions of development of PCM on the basis of polyimide, bismaleimide resin and the phthalonitrile binding are revealed. The works which are carried out to Federal State Unitary Enterprise «VIAM» for re-ceiving heat resistant carbon plastics are provided.

Reference list
  1. Kablov E.N. Strategicheskie napravleniya razvitiya materialov i tehnologiy ih pererabotki na period do 2030 goda [Strategic directions of the development of materials and technologies of their processing for the period till 2030] //Aviatsionnye materialy i tehnologii. 2012. №S. S. 7–17.
  2. Graschenkov D.V., Chursova L.V. Strategiya razvitiya kompozitsionnyh i funktsional'nyh materialov [Development strategy of composite and functional materials] //Aviatsionnye materialy i tehnologii. 2012. №S. S. 231–242.
  3. Raskutin A.E., Sokolov I.I. Ugleplastiki i stekloplastiki novogo pokoleniya [Carbon-filled plastics and fiber glass of new generation] //Trudy VIAM. 2013. №4. (viam-works.ru).
  4. Prepregi i izdelie, vypolnennoe iz nego [Prepregs and products thereof]: pat. 2427594 Ros. Federatsii opubl. 21.12.2009.
  5. Zainul Huda, Prasetyo Eddi. Materials selection in design of structures and engines of supersonic aircrafts: a review //Materials & Design. 2013. V. 46. P. 552–560.
  6. Vicki P. McConnell. Resins for the Hote zone. Part 2: BMIs, CEs, benzoxazines and phthalonitriles /High-Performance Composites. 2009. (material iz seti Internet).
  7. Kuznetsov A.A., Semenova G.K. Perspektivnye vysokotemperaturnye termoreaktivnye svyazuyuschie dlya polimernyh kompozitsionnyh materialov [Promising high-temperature thermo-reactive binders for polymer composite materials] //Rossiyskiy himicheskiy zhurnal. 2009. T. LIII. №4. S. 86–96.
  8. Raskutin A.E., Panina T.V. Problemy sozdaniya konstruktsionnyh ugleplastikov s povyshennoy termookislitel'noy stoykost'yu [Problems of creating structural carbonplastics with increased thermal-oxidative resistance] /V sb. Aviatsionnye materialy i tehnologii: nauch.-tehnich. sb. 2002. №3. S. 18–23.
  9. Mihaylin Yu.A. Termoustoychivye polimery i polimernye materialy [Heat-resistant pol-ymers and polymeric materials]. SPb.: 2006. 610 s.
  10. Chuang K.C., Bowles K.J. A high Tg PMR polyimide composites (DMBZ-15) //Journal of Advanced Materials. 2001. V. 33. №4. P. 1–17.
  11. Sposob polucheniya svyazuyuschego dlya prepregov [Technique to obtain binders for prepreg]: pat. 2052474 Ros. Federatsiya; opubl. 20.01.1996.
  12. Geterotsiklicheskiy termoreaktivnyj polimer [Heterocyclic thermoreactive polymer]: pat. 2225417 Ros. Federatsiya; opubl. 10.03.2004.
  13. Trostyanskaya E.B., Mihaylin Yu.A., Hohlova L.F., Miychenko I.P., Borovskaya S.M., Pomerantseva K.P. Ugleplastiki na osnove polimerizuyuschihsya imidov API-2 [Carbon-filled plastics based on polymerizing imides API-2] /V sb. Voprosy aviatsionnoy nauki i tehniki. Ser. Aviatsionnye materialy. M.: VIAM. 1985. S. 12–19.
  14. Polimernye materialy i vysokoprochnye termostoykie kompozitsionnye materialy na ego osnove [Polymeric materials and high-strength heat-resistant composite materials obtained on their basis]: pat. 2201423 Ros. Federatsiya; opubl. 26.12.2000.
  15. Low-Toxicity, high-temperature polyimides: pat. 99/36462 WO; opubl. 22.07.1999.
  16. Composition of and method for making high performance resins for infusion and transfer mol-ding processes: pat. 6359107 US; opubl.19.03.2002.
  17. Imide oligomers endcapped with phenylethynil phthalic anhydrides and polymers therefrom: pat. 5760168 US; opubl. 02.06.1998.
  18. Sastri S.B., Armistead J.P., Keller T.M., Sorathia U. Phthalonitrile-glass fabric composites //Polymer Composites. 1997. V. 18. №1. P. 48–54.
  19. Sastri S.B., Armistead J.P., Keller T.M. Phthalonitrile-carbon fiber composites //Polymer Composites. 1996. V. 17. №6. P. 816–822.
  20. Mukhametov R.R., Akhmadieva K.R., Chursova L.V. New thermostable heterocyclic binders and environmentally friendly technologies of production of composite materials //Russian Journal of General Chemistry. 2011. V. 81. №5. P. 1025–1031.
  21. Raskutin A.E., Davydova I.F., Muhametov R.R., Minakov V.T. Novoe termostoykoe svyazuyuschee dlya steklo- i ugleplastikov [New heat-resistant binder for glass fiber and carbon-filled plastics] //Klei. Germetiki. Tehnologii. 2007. №11. S. 20–23.
  22. Muhametov R.R., Ahmadieva K.R., Chursova L.V., Kogan D.I. Novye polimernye svyazuyuschie dlya perspektivnyh metodov izgotovleniya konstruktsionnyh voloknistyh PKM [New polymeric binders for promising production methods of structural fibrous polymer composite materials] //Aviatsionnye materialy i tehnologii. 2011. №2. S. 38–42.
  23. Phthalonitrile thermoset polymers and composites cured with halogen-containing aromatic amine cutting agents: pat. 5925475 US; opubl. 20.07.1999.
  24. Fiber reinforced phtalonitrile composites cured with low reactivity aromatic amine curing agent: pat. 6001926 US; opubl. 14.12.1999.
  25. Phthalonitrile prepolymerization composition: pat. 6297298 US; opubl. 02.10.2001.
  26. Phthalonitrile composites: pat. 7642336 US; opubl. 05.01.2010.
  27. Bi-phthalonitrile resin glass fiber composite material toughened by poly(arylene ether nitrile) and preparation method thereof: pat. 101831173 SN; opubl. 15.09.2010.
  28. Heng Zhoul, Amir Badashah, Zhenhua Luol et al. Preparation and property comparison of orto, meta and para autocatalytic phthalonitrile compounds with amino group //Polymers for Advanced Technologies. 2011. V. 22. №10. P. 1459–1465.
  29. Heng Guo, Zhiran Chen, Xulin Yang et al. Self-promoted curingphtalonitrile whith high glass transition temperature for advanced composites //Journal of Polymer Research. 2012. V. 19. №7. P. 1–8.
  30. System and methods for modified resin and composite material: pat. 2008176987 US; opubl. 24.07.2008.
  31. Polimer nanocomposites and methods of preparation: pat. 7049353 US; opubl. 23.05.2006.
  32. Thermosetting resin glass fiber laminating composite material and preparation method thereof: pat. 101700705 SN; opubl. 05.05.2010.
  33. Magnetic ferrocene-double-terminal phthalonitrile resin, condensate and preparation thereof: pat. 101463049 SN; opubl. 24.06.2009.
  34. High temperature epoxy-phthalonitrile blends: pat. 5939508 US; opubl. 17.08.1999.
  35. Dushin M.I., Hrul'kov A.V., Muhametov R.R., Chursova L.V. Osobennosti izgotovleniya izdeliy iz PKM metodom propitki pod davleniem [Peculiarities of production of polymer composite products using pressure impregnation method] //Aviatsionnye materialy i tehnologii. 2012. №1. S. 18–26.