The lanthanum influence on quality and operational properties of single crystal nickel base ZhS36-VI superalloy

Kablov D.E., Sidorov V.V., Min P.G., Puchkov Yu.A.
UDC
669.018.44:669.245
DOI
10.18577/2307-6046-2015-0-12-2-2
Article PDF (Russian) (950.22 KB)
How to cite
Kablov D.E., Sidorov V.V., Min P.G., Puchkov Yu.A. The lanthanum influence on quality and operational properties of single crystal nickel base ZhS36-VI superalloy // Proceedings of VIAM. 2015. No. 12. DOI: 10.18577/2307-6046-2015-0-12-2-2. URL: https://test.viam.ru/en/journal/2015/12/2
Keywords
single crystal, nickel-base superalloy, vacuum induction melt, impurities, sulfur, phosphorus, active metals, lanthanum, yield.
Abstract

The harmful influence of sulfur and phosphorus on heat resistant properties of ZhS36-VI alloy during stress rupture test on long base testing (500 and more hours) as well as on middle quantity of cycles to rupture upon MCF wasdetermined . The possibility to reduce the content of harmful influence of sulfur and phosphorus impurities or their neutralization through microalloing by lanthanum that positively influence on alloy properties recovery was investigated. The mechanism of lanthanum addition for neutralization of these impurities harmful influence was suggested whereby sulfur removes from the melt as refractory lanthanum sulfides by their adhesion on crucible walls during melting and on foam filter during casting. In contrast to sulfur the refractory phosphides with lanthanum don’t remove from the melt. The properties comparison of single crystal alloy cast on units of low- and high gradient direct solidification UVNK-9A and UVNS-5 is presented.

Reference list
  1. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] //Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33.
  2. Kablov E.N., Bondarenko Yu.A., Echin A.B. i dr. Razvitie processa napravlennoj kristallizacii lopatok GTD iz zharoprochnyh i intermetallidnyh splavov s monokristallicheskoj strukturoj [Development of process of the directed crystallization of blades of GTE from heat resisting and intermetallic alloys with single-crystal structure] //Vestnik MGTU im. N.E. Baumana. Ser. «Mashinostroenie». 2011. №SP. S. 20–25.
  3. Kablov E.N., Bondarenko Yu.A., Kablov D.E. Osobennosti struktury i zharoprochnyh svojstv monokristallov 001> vysokorenievogo nikelevogo zharoprochnogo splava, poluchennogo v usloviyah vysokogradientnoj napravlennoj kristallizacii [Features of structure and heat resisting properties of single crystals of 001> high-rhenium nickel hot strength alloys received in the conditions of high-gradient directed crystallization] //Aviacionnye materialy i tehnologii. 2011. №4. S. 25–31.
  4. Kablov E.N., Ospennikova O.G., Lomberg B.S., Sidorov V.V. Prioritetnye napravleniya razvitiya tehnologij proizvodstva zharoprochnyh materialov dlya aviacionnogo dvigatelestroeniya [The priority directions of development of production technologies of heat resisting materials for aviation engine building] //Problemy chernoj metallurgii i materialovedeniya. 2013. №3. S. 47–54.
  5. Kablov E.N., Petrushin N.V., Bronfin M.B., Alekseev A.A. Osobennosti monokristallicheskih zharoprochnyh nikelevyh splavov, legirovannyh reniem [Features of the single-crystal heat resisting nickel alloys alloyed by rhenium] //Metally. 2006. №5. S. 47–57.
  6. Kablov E.N., Petrushin N.V., Vasilenok L.B., Morozova G.I. Renij v zharoprochnyh nikelevyh splavah dlya lopatok gazovyh turbin (prodolzhenie) [Rhenium in heat resisting nickel alloys for blades of gas turbines (continuation)] //Materialovedenie. 2000. №3. S. 38–43.
  7. Kablov E.N., Ospennikova O.G., Sidorov V.V., Rigin V.E. Proizvodstvo lityh prutkovyh (shihtovyh) zagotovok iz sovremennyh litejnyh vysokozharoprochnyh nikelevyh splavov [Production of cast bar (blend) preparations from modern cast high-heat resisting nickel alloys] /V sb. trudov nauch.-tehnich. konf., posvyashhennoj 310-letiyu uralskoj metallurgii i sozdaniyu tehniko-vnedrencheskogo centra metallurgii i tyazhelogo mashinostroeniya. Ekaterinburg: Nauka Servis. 2011. T. 1. S. 31–38.
  8. Kablov E.N., Sidorov V.V., Kablov D.E., Rigin V.E., Goryunov A.V. Sovremennye tehnologii polucheniya prutkovyh zagotovok iz litejnyh zharoprochnyh splavov novogo pokolenija [Modern technologies of receiving the bar stock preparations from foundry heat resisting alloys of new generation] //Aviacionnye materialy i tehnologii. 2012. №S. S. 97–105.
  9. Sidorov V.V., Rigin V.E., Kablov D.E. Organizaciya proizvodstva lityh prutkovyh zagotovok iz sovremennyh litejnyh vysokozharoprochnyh nikelevyh splavov [The organization of production of cast bar preparations from modern cast high-heat resisting nickel alloys] //Litejnoe proizvodstvo. 2011. №10. S. 2–5.
  10. Sidorov V.V., Rigin V.E., Goryunov A.V., Kablov D.E. Vysokoeffektivnye tehnologii i sovremennoe oborudovanie dlya proizvodstva shihtovyh zagotovok iz litejnyh zharoprochnyh splavov [Highly effective technologies and the modern equipment for production of blend preparations from foundry hot strength alloys] //Metallurg. 2012. №5. S. 26–30.
  11. Min P.G., Goryunov A.V., Vadeev V.E. Sovremennye zharoprochnye nikelevye splavy i effektivnye resursosberegayushhie tehnologii ih izgotovlenya [Modern heat resisting nickel alloys and effective resource-saving technologies of their manufacturing] //Tehnologiya metallov. 2014. №8. S. 12–23.
  12. Kablov D.E., Sidorov V.V., Min P.G. Vliyanie primesi azota na strukturu monokristallov zharoprochnogo nikelevogo splava ZhS30-VI i razrabotka effektivnyh sposobov ego rafinirovaniya [Influence of impurity of nitrogen on structure of single crystals of heat resisting ZhS30-VI nickel alloy and development of effective ways of its refinement] //Aviacionnye materialy i tehnologii. 2012. №2. S. 32–36.
  13. Kablov D.E., Chabina E.B., Sidorov V.V., Min P.G. Issledovanie vliyaniya azota na strukturu i svoistva monokristallov iz litejnogo zharoprochnogo splava ZhS30-VI [Research of influence of nitrogen on structure and properties of single crystals from foundry ZhS30-VI hot strength alloy] //MiTOM. 2013. №8. S. 3–7.
  14. Kablov D.E., Sidorov V.V., Min P.G. Zakonomernosti povedeniya azota pri poluchenii monokristallov zharoprochnogo nikelevogo splava ZhS30-VI i ego vliyanie na ekspluatacionnye svoistva [Patterns of behavior of nitrogen when receiving single crystals of heat resisting ZhS30-VI nickel alloy and its influence on operational properties] //MiTOM. 2014. №1. S. 8–12.
  15. Sidorov V.V., Rigin V.E., Goryunov A.V., Min P.G., Kablov D.E. Poluchenie Re–Ru-soderzhashhego splava s ispolzovaniem nekonditsionnyh othodov [Receiving Re–Ru-containing alloy with use of unconditioned waste] //Metallurgiya mashinostroeniya. 2012. №3. S. 15–17.
  16. Sidorov V.V., Rigin V.E., Goryunov A.V., Min P.G. Opyt pererabotki v usloviyah FGUP «VIAM» litejnyh othodov zharoprochnyh splavov, obrazuyushhihsya na motorostroitelnyh i remontnyh zavodah [Experience of processing in the conditions of FSUE «VIAM» of foundry waste of the hot strength alloys which are forming at engine-building and repair plants] //Metallurg. №1. 2014. S. 86–90.
  17. Sidorov V.V., Rigin V.E., Goryunov A.V., Min P.G. Resursosberegayushchaya tehnologiya pererabotki nekondicionnyh othodov litejnyh zharoprochnyh splavov [Resource-saving refining technology of unconditioned waste of foundry hot strength alloys] //Metallurg. №5. 2014. S. 35–39.
  18. Sidorov V.V., Rigin V.E., Gorunov A.V., Min P.G. Innovatsionnaya tehnologiya proizvodstva zharoprochnogo splava ZhS32-VI s uchetom pererabotki vseh vidov othodov v usloviyah sertificirovannogo serijnogo proizvodstva FGUP «VIAM» [The innovation technology of high temperature GS32-VI alloy production considering the recycling of all scrap appearance a certificated quantity production of FGUP «VIAM»] //Trudy VIAM. 2014. №6. St. 01 (viam-works.ru).
  19. Improved low sulfur nickel-base single crystal superalloy with ppm additions of lanthanum and yttrium: pat. 2415888 EU; publ. 14.10.2010.
  20. Zhuanggi HU, Hongwei SONG, Shouren GUO, Wenru SUN and Dezhong LU. Effects of Phosphorus on Microstructure and Creep Property of IN718 Superalloy //J. Mater. Sci. Technol. 2005. V. 21. Suppl. P. 73–76.
  21. Sidorov V.V., Min P.G., Burcev V.T., Kablov D.E., Vadeev V.E. Kompyuternoe modelirovanie i eksperimentalnoe issledovanie reakcij rafinirovaniya v vakuume slozhnolegirovannyh renijsoderzhashchih nikelevyh rasplavov ot primesej sery i kremniya [Computer modeling and pilot study of reactions of refinement in vacuum of complex-alloyed rhenium of containing nickel alloys from sulfur and silicon impurity] //Vestnik RFFI. 2015. №1 (85). S. 32–36.
  22. Sidorov V.V., Rigin V.E., Min P.G., Folomejkin Yu.I. Vliyanie fosfora i kremniya na strukturu i svojstva vysokozharoprochnyh litejnyh splavov i razrabotka effektivnyh metodov ustraneniya ih otricatelnogo vliyaniya [Influence of phosphorus and silicon on structure and properties of high-heat resisting cast alloys and development of effective methods of elimination of their negative influence] //MiTOM. 2015. №6 (720). S. 55–59.
  23. Sidorov V.V., Rigin V.E., Min P.G., Folomejkin Yu.I., Timofeeva O.B., Filonova E.V., Ishodzhanova I.V. Vliyanie primesej na strukturu i svoistva vysokozharoprochnyh litejnyh splavov i razrabotka effektivnyh metodov ustraneniya ih otricatelnogo vliyaniya [Influence of impurity on structure and property of high-heat resisting cast alloys and development of effective methods of elimination of their negative influence] //Novosti materialovedeniya. Nauka i tehnika. 2014. №2. St. 03 (materialsnews.ru).
  24. Sidorov V.V., Rigin V.E., Filonova E.V., Timofeeva O.B. Strukturnye issledovaniya i svojstva monokristallov splavov VZhM4-VI i VZhM5-VI, soderzhashhih povyshennoe kolichestvo fosfora [The structure investigations and properties of VGM4-VI and VGM5-VI single crystal alloys with increased phosphorus quantity] //Trudy VIAM. 2014. №3. St. 02 (viam-works.ru).
  25. Sidorov V.V., Min P.G. Rafinirovanie slozhnolegirovannogo nikelevogo rasplava ot primesi sery pri plavke v vakuumnoj indukcionnoj pechi (chast 1) [Refinement complex-alloyed nickel alloys from sulfur impurity when melting in the vacuum induction furnace (part 1)] //Elektrometallurgiya. 2014. №3. S. 18–23.
  26. Min P.G., Sidorov V.V. Opyt pererabotki litejnyh othodov splava ZhS32-VI na nauchno-proizvodstvennom komplekse VIAM po izgotovleniyu lityh prutkovyh (shihtovyh) zagotovok [The experience of GS32-VI alloy scrap recycling at the VIAM scientific and production complex for cast bars production] //Aviacionnye materialy i tehnologii. 2013. №4. S. 20–25.
  27. Min P.G., Sidorov V.V. Rafinirovanie othodov zharoprochnogo nikelevogo splava ZhS32-VI ot primesi kremniya v usloviyah vakuumnoj indukcionnoj plavki [Refining of scraps of Ni-base superalloy ZhS32-VI to eliminate silicon impurity under conditions of vacuum induction melting] //Trudy VIAM. 2014. №9. St. 01 (viam-works.ru).
  28. Min P.G., Vadeev V.E., Kramer V.V. Rafinirovanie nekondicionnyh othodov deformiruemyh nikelevyh splavov v vakuumnoj indukcionnoj pechi [Refinement of unconditioned waste of deformable nickel alloys in the vacuum induction furnace] //Tehnologiya metallov. 2015. №4. S. 8–13.
  29. Sidorov V.V., Min P.G., Folomejkin Yu.I., Vadeev V.E. Vliyanie skorosti filtracii slozhnolegirovannogo nikelevogo rasplava cherez penokeramicheskij filtr na soderzhanie primesi sery v metalle [Influence of speed of filtering complex-alloyed nickel alloy through foam the ceramic filter on the content of impurity of sulfur in metal] //Elektrometallurgiya. 2015. №5. S. 12–15.
  30. Sidorov V.V., Min P.G. Rafinirovanie slozhnolegirovannogo nikelevogo rasplava ot primesi sery pri plavke v vakuumnoj indukcionnoj pechi (chast 2) [Refinement of complex-alloyed nickel alloy from sulfur impurity when melting in the vacuum induction furnace (part 2)] //Elektrometallurgiya. 2014. №5. S. 26–30.
  31. Kablov E.N., Sidorov V.V. Mikrolegirovanie RZM – sovremennaya tehnologiya povysheniya svojstv litejnyh zharoprochnyh nikelevyh splavov [REM microalloying – modern technology of increase of properties of cast heat resisting nickel alloys] //Perspektivnye materialy. 2001. №1. S. 23–24.
  32. Filippov K.S., Burtsev V.G., Sidorov V.V., Rigin V.E. Issledovanie poverhnostnogo natjazheniya i plotnosti rasplavov nikelya, soderzhashhego primesi sery, fosfora i azota [Research of surface tension and density of alloys of the nickel containing impurity of sulfur, phosphorus and nitrogen] //Fizika i himiya obrabotki materialov. 2013. №1. S. 52–56.
  33. Litye lopatki gazoturbinnyh dvigatelej [Cast blades of gas turbine engines] /Pod red. E.N. Kablova. M.: Nauka. 2006. 632 s.
  34. Sidorov V.V., Rigin V.E., Timofeeva O.B., Min P.G. Vliyanie kremniya i fosfora na zharoprochnye svojstva i strukturno-fazovye prevrashheniya v monokristallah iz vysokozharoprochnogo splava VZhM4-VI [An effect of silicon and phosphorus on high temperature properties and structure-phase transformations of single crystals of VGM4-VI superalloy] //Aviacionnye materialy i tehnologii. 2013. №3. S. 32–38.
  35. Mehanik E.A., Min P.G., Gundobin N.V., Rastegaeva G.Yu. Opredelenie massovoj doli sery v zharoprochnyh nikelevyh splavah i stalyah v diapazone koncentracij ot 0,0001 do 0,0009% (po masse) [Determination of sulfur mass fraction in heat-resistant nickel alloy and steels within the concentration range from 0,0001 to 0,0009% wt.] //Trudy VIAM. 2014. №9. St. 12 (viam-works.ru).
  36. Yakimovich P.V., Alekseev A.V., Min P.G. Opredelenie nizkih soderzhanij fosfora v zharoprochnyh nikelevyh splavah metodom ISP-MS [Determination of low phosphorus content in heat-resistant nickel alloys by ICP-MS method] //Trudy VIAM. 2014. №10. St. 02 (viam-works.ru).
  37. Megchiche E.H., Amarouche M., Mijoule C. First-principle calculations of the diffusion of atomic oxygen in nickel: thermal expansion contribution //Journal of Physics: Condenced Mater. 2007. V. 19. №29. P. 296201.
  38. Zachery С.L. A computational investigation of the effect of alloying elements on the thermodynamic and diffusion properties of FCC Ni alloys with application to the creep rate of delute Ni-X alloys: dissertation for the degree of DF. Pennsylvania University. 2012.