Prospective producing methods for functional structural materials based on CNT-filled nanocomposites (review)

Kondrashov S.V., Shashkeev K.A., Popkov O.V., Solovyanchik L.V.
Kondrashov S.V., Shashkeev K.A., Popkov O.V., Solovyanchik L.V. Prospective producing methods for functional structural materials based on CNT-filled nanocomposites (review) // Proceedings of VIAM. 2016. No. 3. DOI: 10.18577/2307-6046-2016-0-3-7-7. URL: https://test.viam.ru/en/journal/2016/3/7
Abstract

Various methods for producing structural materials with functional properties by introducing carbon nanotubes (CNTs) into a polymer composite material (PCM) matrix are presented. It is shown that the conductivity of the CNT-filled composites depends not only on CNTs type, concentration and polymer matrix composition, but also on the nanocomposite production method. Thus hybrid PCMs combining high electric conductivity and good physical and mechanical properties can be produced by using extruders ensuring high shear stress. Using CNTs as the reinforcing filler allows producing PCM with the record tensile strength of 3,8 GPa, tensile modulus of 293 GPa and conductivity of 1230 S/cm. Decorating CNTs with metal nanoparticles allows increasing conductivity of the hybrid PCMs by several orders.

Reference list
  1. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] // Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33.
  2. Kablov E.N., Kondrashov S.V., Yurkov G.Yu. Prospects of using carbonaceous nanoparticles in binders for polymer composites // Russian nanotechnologies. 2013. V. 8. №3–4. Р. 163–185.
  3. Kablov E.N. Konstrukcionnye i funkcionalnye materialy – osnova jekonomicheskogo i nauchno-tehnicheskogo razvitiya Rossii [Constructional and functional materials – basis of economic and scientific and technical development of Russia] // Voprosy materialovedeniya. 2006. №1. S. 64–67.
  4. Kislyakov P.P., Hohlov Yu.A., Krynin A.G., Kondrashov S.V. Poluchenie i primenenie polimernoj plenki s prozrachnym elektroprovodyashhim pokrytiem na osnove oksida indiya, legirovannogo olovom [Receiving and application of polymer film with transparent electroconducting coating on the basis of the indium oxide alloyed by tin] // Trudy VIAM : elektron. nauch.-tenhich. zhurn. 2013. №11. St. 06. Available at: http://viam-works.ru (accessed at: June 17, 2015).
  5. Yurkov G.Yu., Kondrashov S.V., Kraev I.D. Nanokompozity na osnove polijetilena vysokogo davleniya i nanochastic kobal'ta: sintez, struktura i svojstva [Nanocomposites based on high-density polyethylene and cobalt nanoparticles: synthesis, structure and properties] // Aviacionnye materialy i tehnologii. 2014. №S2. S. 29–33.
  6. Akatenkov R.V., Anoshkin I.V., Belyaev A.A., Bitt V.V., Bogatov V.A., Dyachkova T.P., Kutsevich K.E., Kondrashov S.V., Romanov A.M., Shirokov V.V., Horobrov N.V. Vliyanie strukturnoj organizacii uglerodnyh nanotrubok na radiojekraniruyushhie i elektroprovodyashhie svojstva nanokompozitov [Influence of the structural organization of carbon nanotubes on radio shielding and electrocarrying-out properties of nanocomposites] // Aviacionnye materialy i tehnologii. 2011. №1. S. 35–42.
  7. Akatenkov R.V., Kondrashov S.V., Fokin A.S., Marahovskij P.S. Osobennosti formirovaniya polimernyh setok pri otverzhdenii jepoksidnyh oligomerov s funkcializovannymi nanotrubkami [Features of forming of polymeric grids when curing epoxy oligomers with functionalizing nanotubes] // Aviacionnye materialy i tehnologii. 2011. №2. S. 31–37.
  8. Fan-Long J., Soo-Jin P. A review of the preparation and properties of carbon nanotubes-reinforced polymer composites // Carbon Letters. 2011. V. 12. №2. Р. 57–69.
  9. Gunyaev G.M., Kablov E.N., Aleksashin V.M. Modificirovanie konstrukcionnyh ugleplastikov uglerodnymi nanochasticami [Modifying constructional ugleplastikov carbon nanoparticles] // Rossijskij himicheskij zhurnal. 2010. T. LIV. №1. S. 5–11.
  10. Meincke O., Kaempfer D., Weickmann H., Friedrich C., Vathauer M., Warth H. Mechanical properties and electrical conductivity of carbon-nanotube filled polyamide-6 and its blends with acrylonitrile/butadiene/styrene // Polymer. 2004. V. 45. P. 739–748.
  11. Fornes T.D., Baur J.W., Sabba Y., Thomas E.L. Morphology and properties of melt-spun polycarbonate fibers containing single-and multi-wall carbon nanotubes // Polymer. 2006. V. 47. P. 1704–1714.
  12. Kim K.H., Jo W.H. A strategy for enhancement of mechanical and electrical properties of polycarbonate/multi-walled carbon nanotube composites // Carbon. 2009. V. 47. P. 1126–1134.
  13. Jia Z., Wang Z., Xu C., Liang J., Wei B., Wu D., Zhu S. Study on poly(methyl methacrylate)/carbon nanotube composites // Mater Sci Eng, A. 1999. V. 271. P. 395–400.
  14. Siochi E.J., Working D.C., Park C., Lillehei P.T., Rouse J.H., Topping C.C., Bhattacharyya A.R., Kumar S. Melt processing of SWCNT-polyimide nanocomposite fibers // Compos Part B: Eng. 2004. V. 35. P. 439–446.
  15. Bauhofer W., Kovacs J.Z. A review and analysis of electrical percolation in carbon nanotube polymer composites // Composites Science and Technology. 2009. V. 69. P. 1486–1498.
  16. Polymer–carbon nanotube composites. Preparation, properties and applications. Ed. McNally T., Pötschke P. Woodhead Publishing Limited. 2011. 820 р.
  17. Carbon Nanotubes – Polymer Nanocomposites / ed. Yellampalli Siva. Published by InTech, 2011.
  18. 396 р.
  19. Irzhak V.I. Jepoksidnye kompozicionnye materialy s uglerodnymi nanotrubkami [Epoxy composite materials with carbon nanotubes] // Uspehi himii. 2011. №8. S. 821–839.
  20. Rakov E.G. Uglerodnye nanotrubki v novyh materialah [Carbon nanotubes in new materials] //Uspehi himii. 2013. T. 82. №1. S. 227–247.
  21. Mamunya Ye., Boudenne A., Lebovka N., Ibos L., Candau Y., Lisunova M. Electrical and thermophysical behaviour of PVC-MWCNT nanocomposites // Compos. Sci. Techn. 2008. V. 68.
  22. Р. 1981–1988.
  23. Malliaris A., Turner D.T. Influence of particle size on the electrical resistivity of compacted mixtures of polymeric and metallic powders // J. Appl Phys. 1971. V. 42. №2. Р. 614–618.
  24. Grunlan J.C., Mehrabi A.R., Bannon M.V., Bahr J.L. Water-based single-walled nanotube–filled polymer composite with an exceptionally low percolation threshold // Adv. Mater. 2004. V. 16. №2. Р. 150–153.
  25. Grossiord N., Loos J., van Laake L., Maugey M., Zakri C., Koning C.E., Hart A.J. High-Conductivity Polymer Nanocomposites Obtained by Tailoring the Characteristics of Carbon Nanotube Fillers // Adv. Funct. Mater. 2008. V. 18. P. 3226–3234.
  26. Goldel A., Potschke P. Carbon nanotubes in multiphase polymer blends Polymer–carbon nanotube composites: Preparation, properties and applications. Woodhead Publishing Limited, 2011. Р. 587–620.
  27. Pötschke P., Pegel S., Claes M., Bonduel D. A novel strategy to incorporate carbon nanotubes into thermoplastic matrices // Macromolecular Rapid Communications. 2008. V. 29. Р. 244–251.
  28. Wu S. Formation of dispersed phase in incompatible polymer blends: interfacial and rheological effects // Polym. Eng. Sci. 1987. V. 27. Р. 335–343.
  29. Shimizu H., Komori K., Inoue T. The phase behavior of polymer blends under high shear flow/high pressure fields // Trans. of Mater. Res. Soc. Jpn. 2004. V. 29. Р. 263–265.
  30. Lebovitz A.H., Khait K., Torkelson J.M. Stabilization of Dispersed Phase to Static Coarsening: Polymer Blend Compatibilization via Solid-State Shear Pulverization // Macromolecules. 2002.
  31. V. 35. Р. 8672–8675.
  32. Mezhikovskij S.M., Irzhak V.I. Himicheskaya fizika otverzhdeniya oligomerov [Chemical physics of curing of oligomers]. M.: Nauka, 2008. 269 s.
  33. McIntosh D., Khabashesku V.N., Barrera E.V. Benzoyl Peroxide Initiated In Situ Functionalization, Processing, and Mechanical Properties of Single-Walled Carbon Nanotube-Polypropylene Composite Fibers // J. Phys. Chem. C. 2007. V. 111. Р. 1592–1600.
  34. Li Y., Shimizu H. Conductive PVDF/PA6/CNT nanocomposites fabricated by dual formation of cocontinuous and nanodispersion structures // Macromolecules. 2008. V. 41. Р. 5339–5344.
  35. Kasaliwal G., Goldel A., Potschke P. Influence of processing conditions in smallscale melt mixing and compression molding on the resistivity and morphology of polycarbonate-MWNT composites // Journal of Applied Polymer Science. 2009. V. 112. Р. 3494–3509.
  36. Krause B., Pötschke P., Häußler L. Influence of small scale mixing conditions on electrical resistivity of carbon nanotube-polyamide composites // Compos Sci Technol. 2009. V. 69 (10). Р. 1505–1515.
  37. Logakis E., Pandis C., Peoglos V., Pissis P., Pionteck J., Potschke P., Micuikand M., Omastova M. Electrical/dielectric properties and conduction mechanism in melt processed polyamide/multi-walled carbon nanotubes composites //Polymer. 2009. V. 50 (21). Р. 5103–5111.
  38. Reia da Costa E.F., Skordos A.A., Partridge I.K., Rezai A. RTM processing and electrical performance of carbon nanotube modified epoxy/fiber composites // Composites Part A: Applied Science and Manufacturing. 2012. V. 43. №4. Р. 593–602.
  39. Garcia E.J., Wardle B.L., Hart A.J., Yamamoto N. Fabrication and multifunctional properties of a hybrid laminate with aligned carbon nanotubes grown In Situ // Composites Science and Technology. 2008. V. 68. Р. 2034–2041.
  40. Singh B.P., Bharadwaj P., Choudhary V., Mathur R.B. Enhanced microwave shielding and mechanical properties of multiwall carbon nanotubes anchored carbon fiber felt reinforced epoxy multiscale composites // Appl Nanosci. 2014. V. 4. №4. Р. 421–428.
  41. Lubineau G., Rahaman A. A review of strategies for improving the degradation properties of laminated continuous-fiber/epoxy composites with carbon-based nanoreinforcements // Carbon. 2012. V. 50. Р. 2377–2395.
  42. Garcia E.J., Saito D.S., Megalini L., Hart A.J., Guzman de Villoria R., Wardle B.L. Fabrication and Multifunctional Properties of High Volume Fraction Aligned Carbon Nanotube Thermoset Composites // Journal of Nano Systems & Technology. 2009. V. 1. №1. Р. 1–11.
  43. Cheng Q., Wang J., Jiang K., Li Q., Fan Sh. Fabrication and properties of aligned multiwalled carbon nanotube-reinforced epoxy composites // J. Mater. Res. 2008. V. 23. №11. Р. 2975–2983.
  44. Wang X., Yong Z.Z., Li Q.W., Bradford P.D., Liu W., Tucker D.S., Cai W., Wang H., Yuan F.G., Zhu Y.T. Ultrastrong, Stiff and Multifunctional Carbon Nanotube Composites // Mater. Res. Lett. 2013. V. 1. №1. Р. 19–25.
  45. Mubeen S., Zhang T., Yoo B., Deshusses M.A., Myung N.V. Palladium Nanoparticles Decorated Single-Walled Carbon Nanotube Hydrogen Sensor // J. Phys. Chem. C. 2007. V. 111. Р. 6321–6327.
  46. Bekyarova E., Itkis M.E., Cabrera N., Zhao B., Yu A., Gao J., Haddon R.C. Electronic Properties of Single-Walled Carbon Nanotube Networks // J. Am. chem. soc. 2005. V. 127. Р. 5990–5995.
  47. Chakravarthi D.K., Khabashesku V.N., Vaidyanathan R., Blaine J., Yarlagadda Sh., Roseman D., Zeng Q., Barrera E.V. Carbon Fiber–Bismaleimide Composites Filled with Nickel-Coated Single-Walled Carbon Nanotubes for Lightning-Strike Protection // Adv. Funct. Mater. 2011. V. 21.
  48. Р. 2527–2533.