Phase-to-phase borders interaction in the Nb-matrix composite material reinforced by single-crystal fibers α-Al2O3

Schetanov B. V., Efimochkin I.Yu., Paegle S.V.
Schetanov B. V., Efimochkin I.Yu., Paegle S.V. Phase-to-phase borders interaction in the Nb-matrix composite material reinforced by single-crystal fibers α-Al2O3 // Proceedings of VIAM. 2016. No. 4. DOI: 10.18577/2307-6046-2016-0-4-6-6. URL: https://test.viam.ru/en/journal/2016/4/6
Abstract

A set of experimental samples of fibrous composite material (CM) was fabricated by hot pressing of niobium powder and continuous single-crystal fibers α-Al2O3 with TiN or Mo coatings and without them. The investigation of interactions on phase-to-phase borders in the CM has shown, that molybdenum diffusion-barrier coating, in comparison with TiN coating, is more effective as corrosion protection of single-crystal fibers α-Al2O3 at higher (>1300°С) temperatures and more use time. It has been found that the high-temperature bending strength at 1300°C of the initial CM reinforced by fibers without coating 2,2 times higher than for the pure (Nb) matrix; for the CM reinforced by fibers with TiN coating this value is 1,8 times higher. The strength of the material reinforced by TiN-coated fibers increases after heat aging and exceeds the strength of matrix 2,4 times. High-temperature strength of the initial CM with Mo-coated fibers and after heat aging are about similar and exceeds the stren

Reference list
  1. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] // Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33.
  2. Kablov E.N. Tendencii i orientiry innovacionnogo razvitiya Rossii: sb. nauch.-informacionnyh materialov [Tendencies and reference points of innovative development of Russia: Saturday. nauch. - information materials]. M.: VIAM, 2015. 720 s.
  3. Kablov E.N., Svetlov I.L., Efimochkin I.Yu. Vysokotemperaturnye Nb–Si-kompozity [High-temperature Nb-Si-composites] // Vestnik MGTU im. N.E. Baumana. Ser. «Mashinostroenie». 2011. №SP2. S. 164–173.
  4. Kablov E.N., Shhetanov B.V., Ivahnenko Yu.A., Balinova Yu.A. Perspektivnye armiruyushhie vysokotemperaturnye volokna dlya metallicheskih i keramicheskih kompozicionnyh materialov [Perspective reinforcing high-temperature fibers for metal and ceramic composite materials] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2013. №2. St. 05. Available at: http://www.viam-works.ru (accessed: September 07, 2015).
  5. Kablov E.N., Muboyadzhyan S.A. Zharostojkie i teplozashhitnye pokrytiya dlya lopatok turbiny vysokogo davleniya perspektivnyh GTD [Heat resisting and heat-protective coverings for turbine blades of high pressure of perspective GTE] //Aviacionnye materialy i tehnologii. 2012. №S. S. 60–70.
  6. Menon E.S.K., Mendiratta M.G., Dimiduk D.M. Oxidation of complex niobium based alloys / In: International Symposium Niobium; Science & technology. Orlando. December 2–5. 2001. P. 121–146.
  7. Weiping Hu, Hao Chen, Yonlong Zhong, Jia Song, Gottstein G. Investigations оn NiAl composites fabricated by matrix coated single crystalline Al2O3-fibers with and without hBN interlayer // Mater. Sci. China. 2008. №2 (2). P. 182–193.
  8. Shhetanov B.V., Stryukov D.O., Kolyshev S.G., Murasheva V.V. Monokristallicheskie volokna oksida alyuminiya: poluchenie, struktura, svojstva [Single-crystal fibers of aluminum oxide: receiving, structure, properties] // Vse materialy. Enciklopedicheskij spravochnik. 2014. №4. S. 14–18.
  9. Shhetanov B.V., Efimochkin I.Yu., Kuptsov R.S., Svistunov V.I. Issledovanie kompozicionnogo materiala na osnove Nb, armirovannogo monokristallicheskimi voloknami α-Al2O3 s barernym pokrytiem TiN i bez nego [Research of composite material on the basis of Nb reinforced by single-crystal fibers α-Al2O3 with barrier coating of TiN and without it] // Tehnologiya mashinostroeniya (v pechati).
  10. Shhetanov B.V., Grashhenkov D.V., Efimochkin I.Yu., Shheglova T.M. Monokristallicheskie volokna oksida alyuminiya dlya vysokotemperaturnyh (do 1400°C) kompozicionnyh materialov [Single-crystal fibers of aluminum oxide for high-temperature (to 1400°С) composite materials] // Tehnologiya mashinostroeniya. 2014. №10 (148). S. 5–9.
  11. Shchetanov B.V., Efimochkin I.Yu., Paegle S.V., Karachevcev F.N. Issledovanie vysokotemperaturnoj prochnosti «in-situ»-kompozitov na osnove Nb, armirovannyh monokristallicheskimi voloknami α-Al2O3 [Research of high-temperature durability of "in-situ" - composites on the basis of Nb reinforced by single-crystal fibers α-Al2O3] // Aviacionnye materialy i tehnologii. 2016 (v pechati).
  12. Grashhenkov D.V., Shhetanov B.V., Efimochkin I.Yu. Razvitie poroshkovoj metallurgii zharoprochnyh materialov. Ch. 1 [Development of powder metallurgy of heat resisting materials. Part1] // Vse materialy. Enciklopedicheskij spravochnik. 2011. №5. S. 13–26.
  13. Grashhenkov D.V., Shhetanov B.V., Efimochkin I.Yu. Razvitie poroshkovoj metallurgii zharoprochnyh materialov. Ch. 2 [Development of powder metallurgy of heat resisting materials. Part 2] // Vse materialy. Enciklopedicheskij spravochnik. 2011. №6. S. 10–22.
  14. Basargin O.V., Kolyshev S.G., Shchetanov B.V., Shcheglova T.M. Osobennosti vysokotemperaturnyh ispytanij pri izgibe obrazcov kompozicionnogo materiala s matricej na osnove Nb [Some features of high-temperature bend tests of Nb-based CM specimens] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2015. №5. St. 11. Available at: http://www.viam-works.ru (accessed: September 07, 2015). DOI: 10.18577/2307-6046-2015-0-5-11-11.
  15. Samsonov G.V., Vinickij I.M. Tugoplavkie soedineniya: spravochnik. 2-e izd [High-melting connections: directory. 2nd ed.]. M.: Metallurgiya, 1976. 516 s.
  16. Marmer E.N., Gurvich O.S., Maltseva L.F. Vysokotemperaturnye materialy [High-temperature materials]. M.: Metallurgiya, 1967. 215 s.
  17. Bowman R.R., Misra A.K., Arnold S.M. Processing and Mechanical Properties of Al2O3 Fibwe-Reinforced NiAl Composites // Metallurgical and Materials Transactions. 1995. V. 26A. P. 615–628.