Experience on development of measurement procedure for determination of hydrogen content in titanium alloys
An overview of publications about advanced research in the field of development and application of titanium alloys is hereby provided. The importance of determination of low hydrogen concentration in titanium alloys is highlighted. The challenge for VIAM now is to develop new measurement procedures and manufacture reference materials (CRMs) with certified hydrogen content. Existing measurement procedures for determination of hydrogen content in Ti alloys are hereby overviewed. The experience of such method developing by using the RHEN-600 gas analyzer unit is considered in details – from the choice of the reference materials and unit pre-treatment method to metrological characteristics estimation. The developed measurement procedure for determination of hydrogen content in Ti alloys by fusion of reference material in inert gas (argon) is approved and included in the State Register.
- Galaktionova N.A. Vodorod v metallah [Hydrogen in metals]. M.: Metallurgizdat. 1958. 157 s.
- Antashov V.G., Nochovnaja N.A., Shirjaev A.A., Izotova A.Ju. Perspektivy razrabotki novyh titanovyh splavov [Prospects for the development of new titanium alloys] //Vestnik MGTU im. N.Je. Baumana. Ser. «Mashinostroenie». 2011. №SP2. C. 60–67.
- Nochovnaja N.A., Ivanov V.I., Alekseev E.B., Kochetkov A.S. Puti optimizacii jekspluatacionnyh svojstv splavov na osnove intermetallidov titana [Ways to optimize the performance properties of intermetallic alloys based on titanium] //Aviacionnye materialy i tehnologii. 2012. №S. S. 196–206.
- Kashapov O.S., Novak A.V., Nochovnaja N.A., Pavlova T.V. Sostojanie, problemy i perspektivy sozdanija zharoprochnyh titanovyh splavov dlja detalej GTD [Status, problems and prospects of creating heat-resistant titanium alloys for GTE parts] //Trudy VIAM. 2013. №3. St. 02 (viam-works.ru).
- Horev A.I., Nochovnaja N.A., Jakovlev A.L. Mikrolegirovanie redkozemel'nymi metallami titanovyh splavov [Microalloying rare earth metals titanium alloys] //Aviacionnye materialy i tehnologii. 2012. №S. S. 206–212.
- Kablov E.N. Strategicheskie napravlenija razvitija materialov i tehnologij ih pererabotki na period do 2030 goda [Strategic directions of development of materials and technologies to process them for the period up to 2030] //Aviacionnye materialy i tehnologii. 2012. №S. S. 7–17.
- Kablov E.N., Bondarenko Ju.A., Echin A.B., Surova V.A. Razvitie processa napravlennoj kristallizacii lopatok GTD iz zharoprochnyh splavov s monokristallicheskoj i kompozicionnoj strukturoj [The development process of directional solidification of the gas turbine engine blades superalloys with a single-crystal structure and composition] //Aviacionnye materialy i tehnologii. 2012. №1. S. 3–8.
- Skvorcova S.V., Panin P.V., Nochovnaja N.A. i dr. Vlijanie vodoroda na fazovye i strukturnye prevrashhenija v titanovom splave VT6 [The effect of hydrogen on the phase and structural transformations in titanium alloy BT6] //Tehnologija legkih splavov. 2011. №4. C. 35–40.
- Panin P.V., Shirjaev A.A., Dzunovich D.A. Postroenie temperaturno-koncentracionnoj diagrammy fazovogo sostava titanovogo splava VT6, dopolnitel'no legirovannogo vodorodom [Construction of the temperature-concentration phase diagram of the titanium alloy BT6 additionally doped with hydrogen] //Tehnologija mashinostroenija. 2014. №3. S. 5–9.
- Il'in A.A., Skvorcova S.V., Panin P.V., Shalin A.V. Vlijanie termovodorodnoj obrabotki i plasticheskoj deformacii na strukturoobrazovanie v titanovyh splavah raznyh klassov [Influence thermohydrogen processing and plastic deformation on the structure formation in titanium alloys of different classes] //Aviacionnaja promyshlennost'. 2009. №4. S. 31–36.
- Nochovnaja N.A., Alekseev E.B., Jasinskij K.K., Kochetkov A.S. Specifika plavki i sposoby poluchenija slitkov intermetallida titanovyh splavov s povyshennym soderzhaniem niobija [Specificity melting ingots and methods of preparing the intermetallic titanium alloys with a high content of niobium] //Vestnik MGTU im. N.Je. Baumana. Ser. «Mashinostroenie». 2011. №SP2. C. 53–59.
- Poljanskij A.M., Poljanskij V.A., Popov-Djumin D.B. Primenenie metoda vysokotemperaturnoj vakuum-jekstrakcii vodoroda iz metallicheskih obrazcov dlja opredelenija plotnosti defektov struktury i jenergii svjazi vodoroda v metallah [Application of the method of high-temperature vacuum extraction of hydrogen from metal samples to determine the density of structural defects and the binding energy of hydrogen in metals] //ISJAEE. 2005. P. 42–46.
- Letov A.F., Karachevcev F.N. Opyt razrabotki standartnyh obrazcov aviacionnyh splavov [Experience in the development of standard samples aviation alloys] //Mir izmerenij. 2012. №8. S. 31–35.
- Kablov E.N., Morozov G.A., Krutikov V.N., Muravskaja N.P. Attestacija standartnyh obrazcov sostava slozhnolegirovannyh splavov s primeneniem jetalona [Certification of standard samples of complex alloys using standard] //Aviacionnye materialy i tehnologii. 2012. №2. C. 9–11.
- Letov A.F., Karachevcev F.N., Gundobin N.V., Titov V.I. Razrabotka standartnyh obrazcov sostava splavov aviacionnogo naznachenija [Development of standard samples of alloys aviation applications] //Aviacionnye materialy i tehnologii. 2012. №S. C. 393–398.
- Grigorovich K.V. Novye vozmozhnosti sovremennyh metodov opredelenija gazoobrazujushhih primesej v metallah [New features of modern methods for the determination of gas-forming impurities in metals] //Zavodskaja laboratorija. Diagnostika materialov. 2007. №1. S. 23–34.
- GOST 9853.21–96. Titan gubchatyj. Metody opredelenija vodoroda [Titanium sponge. Methods for determination of hydrogen].
- Karpov Ju.A. Spektral'nyj analiz v analiticheskom kontrole metallurgicheskogo pro-izvodstva [Spectral analysis in analytical control of metallurgical production] //Standartnye obrazcy. 2012. №1. C. 3–6.
- GOST 24956–81. Splavy titanovye. Opredelenie vodoroda v tverdom metalle metodom vakuum-nagreva [Titanium alloys. Determination of hydrogen in solid metals by vacuum heating].
- GOST 17745. Stali i splavy. Metody analiza gazov [Steels and alloys. Methods for analysis of gases].
- OST I 90034. Splavy titanovye. Metod spektral'nogo opredelenija soderzhanija vodoroda [Titanium alloys. Method for the determination of hydrogen content].
- GOST 5725. Tochnost' (pravil'nost' i precizionnost') metodov i rezul'tatov izmerenij [Accuracy (trueness and precision) of measurement methods and results].
