Solid resol-novolak resins and composition on their based

A.I. Samatadze, Parakhin I.V., A.S. Tumanov
UDC
678.632
DOI
10.18577/2307-6046-2014-0-9-10-10
Article PDF (Russian) (371.43 KB)
How to cite
A.I. Samatadze, Parakhin I.V., A.S. Tumanov Solid resol-novolak resins and composition on their based // Proceedings of VIAM. 2014. No. 9. DOI: 10.18577/2307-6046-2014-0-9-10-10. URL: https://test.viam.ru/en/journal/2014/9/10
Abstract

The present article is devoted to receiving the combined polymers based on the mixed resol-novolak resins. As a result of the carried-out researches technological properties (viscosity, cured and other) of the combined polymers on the basis of the mixed resol-novolak compositions and also their heat resistance were determined. It is shown that introduction of novolak oligomer in composition on the based of solid resol resins leads to reducing the viscosity of the composition that simplifies carrying out technological process of their receiving. This fact greatly simplifies the technological process. At the same time, studying of kinetics of thermal decomposition of studied compositions has allowed to identify that additives of novolak oligomer have certain thermostabilizing effect on decrease in speed of destruction of the mixed resol-novolak compositions. Durability of the carbon residue of the received compositions also significantly increases in comparison with initial systems.

Reference list
  1. Kablov E.N., Starcev O.V., Deev I.S., Nikishin E.F. Svojstva polimernyh kompozicionnyh materialov posle vozdejstvija otkrytogo kosmosa na okolozemnyh orbitah [Properties of polymer composites after exposure to outer space orbiting the Earth] //Vse materialy. Jenciklopedicheskij spravochnik. 2012. №11. S. 2–16.
  2. Kablov E.N. Himija v aviacionnom materialovedenii [Chemicals in aviation materials] //Rossijskij himicheskij zhurnal. 2010. T. LIV. №1. S. 3–4.
  3. Tkachuk A.I., Grebeneva T.A., Chursova L.V., Panina N.N. Termoplastichnye svjazujushhie. Nastojashhee i budushhee [Thermoplastic binders. Present and Future] //Trudy VIAM. 2013. №11. St. 07 (viam-works.ru).
  4. Vlasenko F.S., Raskutin A.E. Primenenie polimernyh kompozicionnyh materialov v stroitel'nyh konstrukcijah [The use of polymer composite materials in building construction] //Trudy VIAM. 2013. №8. St. 03 (viam-works.ru).
  5. Seo J.H., Cha S.W., Kim H.B. Diffused Reflection of Microcellular Foamed Polycarbonate //Polym. Plastics Technol. Eng. 2009. V. 48. P. 351–358.
  6. Neoh S.B., Azura A.R., Hashim A.S. Comparison of the Different Vulcanization Techniques of Styrene Modified Natural Rubber (SNR) as an Impact Modifier of Natural Rubber-Based High Impact Polystyrene (NRHIPS) //Polym. Plastics Technol. Eng. 2011. V. 49. P. 121–126.
  7. Zastrogina O.B., Shvec N.I., Postnov V.I., Serkova E.A. Fenolformal'degidnoe svjazujushhee dlja novogo pokolenija materialov inter'era [Phenol-formaldehyde binder for a new generation of interior materials] //Aviacionnye materialy i tehnologii. 2012. №S. S. 265–272.
  8. Yoganathan R.B., Mammucari R., Foster N.R. Dense Gas Processing of Polymers //Polymer Reviews. 2011. V. 50. №2. Р. 144–177.
  9. Bing Li, Qingfeng Wu, Nanqiao Zhou, Baoshan Shi Batch Foam. Processing of Polypropylene/Polydimethylsiloxane Blends //International Journal of Polymeric Materials. 2010. V. 60. №1. Р. 51‒61.
  10. Jorge R.M., Lopes L., Benzi M.R., Ferreira M.T., Gomes A.S., Nunes R.C.R. Thiol Addition to Epoxidized Natural Rubber: Effect on the Tensile and Thermal Properties //International Journal of Polymeric Materials. 2010. V. 59. №5. Р. 330–341.
  11. Gofman V. Vulkanizacija i vulkanizujushhie agenty [Vulcanization and curing agents] /Per. s nem. M.: Inostrannaja literatura. 1968. 345 s.
  12. Dogadkin B.A. Vulkanizacionnye struktury i ih izmenenija pri vulkanizacii, termomehanicheskom vozdejstvii i utomlenii vulkanizatov [Vulcanization structures and their changes during curing, thermo-mechanical stress and fatigue vulcanizates] //Himicheskaja nauka i promyshlennost'. 1959. T. 4. S. 420–426.
  13. Sytyj Ju.V., Kisljakova V.I., Sagomonova V.A., Nikolaeva M.F. Novyj mnogoslojnyj uplotnitel'nyj material VTP-2P [Новый многослойный уплотнительный материал ВТП-2П] //Aviacionnye materialy i tehnologii. 2011. №4. S. 32–34.
  14. Sunil Jose T., Anoop Anand K. Joseph Rani. On the Mechanical Properties of EPDM/CIIR Blends Cured with Reactive Phenolic Resin //International Journal of Polymeric Materials. 2010. V. 59. №7. Р. 488–497.
  15. Gao Jungang, Jiang Chaojie, Su Xiaohui Synthesis and Thermal Properties of Boron – Nitrogen Containing Phenol Formaldehyde Resin/MMT Nanocomposites //International Journal of Polymeric Materials. 2010. V. 59. №8. Р. 544–552.
  16. Xie Chan, Jia Zhixin, Jia Demin, Luo Yuanfang, You Changjiang. The Effect of Dy (III) Complex with 2-Mercaptobenzimidazole on the Thermo-Oxidation Aging Behavior of Natural Rubber Vulcanizates //International Journal of Polymeric Materials. 2010. V. 59. №9. Р. 663–679.
  17. Samatadze A.I., Parahin I.V., Porosova N.F., Tumanov A.S. Poluchenie fenolo-kauchukovyh penoplastov metodom «bessernoj» vulkanizacii [Preparation of phenol-rubber foam method «bessernoy» vulcanization] //Aviacionnye materialy i tehnologii. 2013. №3. S. 49‒52.
  18. Parahin I.V., Tumanov A.S. Fenol'no-kauchukovyj penoplast marki VPP-4 [Phenolic foam rubber stamps Runway 4] //Aviacionnye materialy i tehnologii. 2014. №1.
  19. S. 42‒46.
  20. Patel Hasmukh S., Patel Bhavdeep K., Morekar Manish M., Dixit Bharat C. Synthesis, Characterization and Glass Reinforcement of Urea-Formaldehyde-Phenol Resins //International Journal of Polymeric Materials. 2009. V. 58. №11. Р. 604–611.
  21. Kablov E.N. Strategicheskie napravlenija razvitija materialov i tehnologij ih pererabotki na period do 2030 goda [Strategic directions of development of materials and technologies to process them for the period up to 2030] //Aviacionnye materialy i tehnologii. 2012. №S. S. 7–17.