Study of the rheological and structural characteristics of the epoxy resins, modified by polyisocyanate
Babin A.N., Guseva M.A., Grebeneva T.A., Tkachuk A.I. Study of the rheological and structural characteristics of the epoxy resins, modified by polyisocyanate // Proceedings of VIAM. 2016. No. 1. DOI: 10.18577/2307-6046-2016-0-1-90-98. URL: https://test.viam.ru/en/journal/2016/1/11
Abstract
The effect of the quantity of polyisocyanate entering into reaction with epoxy oligomers containing hydroxyl groups with formation of urethane, on viscosity and change of structure of epoxy oligomers has been studied by methods of rotational viscometry and IR spectroscopy. Stability of the received epoxy-urethane oligomers is investigated at heat treatment.
Reference list
- Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] // Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33.
- Kablov E.N. Materialy i himicheskie tehnologii dlya aviacionnoj tehniki [Materials and chemical technologies for aviation engineering] // Vestnik Rossijskoj akademii nauk. 2012. T. 82. №6. S. 520–530.
- Kablov E.N. Rossii nuzhny materialy novogo pokoleniya [Materials of new generation are necessary to Russia] // Redkie zemli. 2014. №3. S. 813.
- Vlasenko F.S., Raskutin A.E. Primenenie polimernyh kompozicionnyh materialov v stroitelnyh konstrukciyah [Applying FRP in building structures] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2013. №8. St. 03. Available at: http://www.viam-works.ru (accessed: June 17, 2015).
- Tkachuk A.I., Grebeneva T.A., Chursova L.V., Panina N.N. Termoplastichnye svjazujushhie. Nastojashhee i budushhee [Thermoplastic binders. The present and the future] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2013. №11. St. 07. Available at: http://www.viam-works.ru (accessed: June 17, 2015).
- Morev F.V., Prokopchuk N.R., Krutko E.T. Modificirovanie epoksidianovyh smol poliizocianatami [Modifying of epoksidianovy pitches by polyisocyanates] // Trudy BGTU. 2012. №4. S. 88–91.
- Lapickij V.A., Kricuk A.A. Fiziko-himicheskie svojstva jepoksidnyh polimerov i stekloplastikov [Physical and chemical properties of epoxy polymers and fibreglasses]. Kiev: Naukova dumka, 1986. 96 s.
- Sycheva M.V., Garipov R.M., Deberdeev R.Ja. Modifikacija jepoksidnyh materialov izocianatami [Updating of epoxy materials by isocyanates] // Vestnik Kazanskogo tehnologicheskogo universiteta. 2009. №6. S. 193–198.
- Nikolaeva N.P., Kuzmin M.V., Koltsov N.I. Sintez i issledovanie svojstv jepoksiuretanov, poluchennyh psevdoforpolimernym metodom [Synthesis and research of properties epoksiuretanov, received pseudoprepolymer method] // Vestnik Kazanskogo tehnologicheskogo universiteta. 2013. T. 16. №1. S. 136–138.
- Barcia F.L., Abrahão M.A., Soares B.G. Modification of epoxy resin by isocyanate-terminated polybutadiene // Journal of Applied Polymer Science. 2002. V. 83. №4. P. 838–849.
- Kadurina T.I., Laevskaya L.I. Sintez epoksiizocianuratnyh blokoligomerov i polimerov na ih osnove [Synthesis of epoxideisocyanurate blockoligomers and polymers on their base] // Voprosy himii i himicheskoj tehnologii. 2004. №1. S. 103–107.
- Guseva M.A. Cianovye efiry – perspektivnye termoreaktivnye svyazujushhie (obzor) [Cyanic esters are prospective thermosetting binders (review)] // Aviacionnye materialy i tehnologii. 2015. №2. S. 45–50.
- Nistratov A.V. Fiziko-himicheskie principy razrabotki receptur i tehnologii kompozicij na osnove oligotiolov, oligodienov i oligoefirov, ispolzuemyh dlya polucheniya polimernyh materialov s uluchshennymi tehniko-ekspluatacionnymi harakteristikami [Physical and chemical principles of development of compoundings and technology of compositions on basis oligothiol, oligodienes and oligoethers used for receiving polymeric materials with improved technical utilization properties]: avtoref. dis. … dokt. tehn. nauk. Volgograd, 2014. 48 s.
- Timoshkov P.N., Hrulkov A.V. Sovremennye tehnologii pererabotki polimernyh kompozicionnyh materialov, poluchaemyh metodom propitki rasplavnym svjazujushhim [Modern technologies of hotmelt polymer composite materials processing] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2014. №8. St. 04. Available at: http://www.viam-works.ru (accessed: June 17, 2015). DOI: 10.18577/2307-6046-2014-0-8-4-4.
- Zheleznyak V.G., Chursova L.V. Modifikaciya svyazujushhih i matric na ih osnove s celyu povysheniya vyazkosti razrusheniya [Modification of binders and matrixes based on them to increase fracture toughness] // Aviacionnye materialy i tehnologii. 2014. №1. S. 47–50.
- Merkulova Yu.I., Muhametov R.R. Nizkovyazkoe epoksidnoe svyazuyushhee dlya pererabotki metodom vakuumnoj infuzii [Development of a low-viscosity epoxy binder for processing by vacuum infusion] // Aviacionnye materialy i tehnologii. 2014. №1. S. 39–41.
- Nakanisi K. Infrakrasnye spektry i stroenie organicheskih soedinenij: per. s angl. [Infrared spectrums and structure of organic connections: trans. from English]. M.: Mir, 1965. 216 s.
- Kirienko T.A., Balinova Yu.A. Vliyanie atmosfernoj vlazhnosti na reologiju tonkih sloev koncentrirovannyh vodnyh rastvorov sistemy «neorganicheskie soli–organicheskij polimer» [Influence of atmospheric humidity on a rheology of thin layers of the concentrated water solutions of system «inorganic salts–organic polymer»] // Aviacionnye materialy i tehnologii. 2014. №2. S. 56–58.
- Gulyaev A.I., Zhuravleva P.L. Metodologicheskie voprosy analiza fazovoj morfologii materialov na osnove sinteticheskih smol, modificirovannyh termoplastami (obzor) [Methodological aspects of the phase morphology analysis in materials based on synthetic resins modified by thermoplastics] // Trudy VIAM. 2015. №6. St. 09. Available at: http://www.viam-works.ru (accessed: June 17, 2015). DOI: 10.18577/2307-6046-2015-0-6-9-9.
