Determination of beryllium in modern aviation materials by atomic emission spectrome-try with inductively coupled plasma

Dvoretskov R.M., Volkova O.S., Radzikovskaya V.N., Burova V.N.
UDC
669.725:543.42
DOI
10.18577/2307-6046-2016-0-4-5-5
Article PDF (Russian) (477.44 KB)
How to cite
Dvoretskov R.M., Volkova O.S., Radzikovskaya V.N., Burova V.N. Determination of beryllium in modern aviation materials by atomic emission spectrome-try with inductively coupled plasma // Proceedings of VIAM. 2016. No. 4. DOI: 10.18577/2307-6046-2016-0-4-5-5. URL: https://test.viam.ru/en/journal/2016/4/5
Abstract

Research on selection of sample preparation conditions for various beryllium-bearing aviation materials and selection of analytical lines for different ranges of Be content in these materials was carried out. The measurement technique of the mass fraction of beryllium in aviation materials by atomic emission spectrometry with inductively coupled plasma (ICP-AES) in combination with microwave sample preparation was developed. The technique allows determining both high (more than 2,5% wt.) and low (0,0001% wt.) concentrations of beryllium. It has been shown that ICP-AES technique is less long and labour-intensive and safer as compared with gravimetry technique. Work is executed within implementation of the complex scientific direction 8.6. «Elinvar, wear-resistant alloys and high-strength beryllium-bearing steels for devices and units» («The strategic directions of development of materials and technologies of their processing for the period till 2030»)

Reference list
  1. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] // Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33.
  2. Kablov E.N. Materialy dlya izdeliya «Buran» – innovacionnye resheniya formirovaniya shestogo tehnologicheskogo uklada [Materials for «Buran» spaceship – innovative solutions of formation of the sixth technological mode] //Aviacionnye materialy i tehnologii. 2013. №S1. S. 3–9.
  3. Fridlyander I.N., Yatsenko K.P. Berillievye splavy – perspektivnoe napravlenie aerokosmicheskogo materialovedeniya [Beryllium alloys – the perspective direction of space materials science] // Aviacionnye materialy i tehnologii. 2000. №4. S. 6–13.
  4. Kaskov V.S. Berillij i materialy na ego osnove [Beryllium and materials on its basis] // Aviacionnye materialy i tehnologii. 2012. №S. S. 222–226.
  5. Kablov E.N., Solncev S.S., Rozenenkova V.A., Mironova N.A. Kompozicionnye steklometallicheskie pokrytiya dlya zashhity berilliya pri vysokih temperaturah [Composition steklometallichesky coverings for protection of beryllium at high temperatures] // Steklo i keramika. 2012. №4. S. 12–15.
  6. Rozenenkova V.A., Solntsev St.S., Mironova N.A. Kompleksnaya zashhita berillievyh splavov ot okisleniya i sublimacii toksichnyh parov berilliya [Complex protection of beryllium alloys against oxidation and sublimation of toxic vapors of beryllium] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2013. №5. St. 03. Available at: http://www.viam-works.ru (accessed: June 19, 2015).
  7. Tuzov Yu.V., Markushkin Yu.E. Berillij – sostoyanie, vozmozhnosti i perspektivy primeneniya v termoyadernoj tehnike [Beryllium – condition, opportunities and application perspectives in thermonuclear equipment] // Voprosy atomnoj nauki i tehniki. Ser.: Termoyadernyj sintez. 2011. №2. S. 21–27.
  8. Papirov I.I., Tihinskij G.F. Fizicheskoe metallovedenie berilliya [Physical metallurgical science of beryllium]. M.: Atomizdat, 1968. 452 s.
  9. Papirov I.I. Berillij v splavah: spravochnik [Beryllium in alloys: directory]. M.: Energoatomizdat, 1986. S. 3–4.
  10. Kaskov V.S. Berillij – konstrukcionnyj material dlya mnogorazovoj kosmicheskoj sistemy [Beryllium – constructional material for reusable space system] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2013. №3. St. 03. Available at: http://www.viam-works.ru (accessed: June 19, 2015).
  11. Fokanov A.N., Podurazhnaya V.F., Tebyakin A.V., Kaskov V.S. Izgotovlenie folgi iz tehnicheskogo spechennogo berilliya povyshennoj chistoty [Foil manufacturing from the technical sintered beryllium of higher purity] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2015. №6. St. 03. Available at: http://www.viam-works.ru (accessed: June 19, 2015). DOI: 10.18577/2307-6046-2015-0-6-3-3.
  12. Fokanov A.N., Kaskov V.S., Podurazhnaya V.F. Pajka berilliya so splavom monel pri izgotovlenii rentgenovskih okon [Beryllium brazing with monel alloy in production x-ray windows] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2014. №8. St. 02. Available at: http://www.viam-works.ru (accessed: June 19, 2015). DOI: 10.18577/2307-6046-2014-0-8-2-2.
  13. GOST 10994–74 «Splavy precizionnye. Marki» [State standard 10994–74 «Alloys precision. Brands»]. Kaluga: Kaluzhskaya tipografiya standartov, 2004. 18 s.
  14. Shcherbakov A.I., Mosolov A.N., Kalitsev V.A. Vosstanovlenie tehnologii polucheniya berillijsoderzhashhej stali VNS-32-VI [Recovery of technology for the beryllium-containing steel VNS-32-VI obtaining] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2014. №5. St. 01. Available at: http://www.viam-works.ru (accessed: June 19, 2015). DOI: 10.18577/2307-6046-2014-0-5-1-1.
  15. Fridlyander I.N., Bratuhin A.G., Gorbunov P.Z., Gal V.V., Yatsenko K.P., Fokanov A.N. Al-Be-splavy – metallicheskie kompozicionnye materialy shirokogo naznacheniya [Al-Be-alloys – multipurpose metal composite materials] // MiTOM. 1996. №9. S. 23–26.
  16. GOST 11739.3–82 «Splavy alyuminievye litejnye i deformiruemye. Metody opredeleniya berilliya» [State standard 11739.3–82 «Alloys aluminum foundry and deformable. Methods of definition of beryllium»]. M.: Izdatelstvo standartov, 1989. 10 s.
  17. GOST 15027.13–77 «Bronzy bezolovyannye. Metody opredeleniya berilliya» [State standard 11739.3–82 «Bronze without the tin. Methods of definition of beryllium»]. M.: Izdatelstvo standartov, 2002. 4 s.
  18. GOST 23687.1–79 «Ligatura medno-berillievaya. Metody opredeleniya berilliya» [State standard 11739.3–82 «Ligature copper-beryllium. Methods of definition of beryllium»]. M.: Izdatelstvo standartov, 1979. 7 s.
  19. Sanitarnye pravila pri rabote s berilliem i ego soedineniyami: Sanitarnye pravila №393–72: utv. glavnym sanitarnym vrachom SSSR P.N. Burgasovym 16.11.1972 [Health regulations at work with beryllium and its connections: Health regulations No. 393-72: approved by Chief Health Officer of the USSR P.N. Burgasov 11/16/1972]. M., 1973. 5 s.
  20. Pupyshev A.A., Danilova D.A. Ispolzovanie atomno-emissionnoj spektrometrii s induktivno-svyazannoj plazmoj dlya analiza materialov i produktov chernoj metallurgii [Use of nuclear and emission spectrometry with the inductive and connected plasma for the analysis of materials and products of ferrous metallurgy] // Analitika i kontrol. 2007. T. 11. №2–3. S. 131–181.
  21. Evdokimova O.V., Majorova A.V., Pechishheva N.V., Karachevcev F.N., Shunyaev K.Yu. Teoreticheskij vybor vnutrennego standarta pri ISP-AES opredelenii legiruyushhih komponentov zharoprochnyh nikelevyh splavov [Theoretical choice of internal standard at the ISP-nuclear power plant definition of alloying components of heat resisting nickel alloys ] // Novosti materialovedeniya. Nauka i tehnika: elektron. nauch.-tehnich. zhurn. 2014. №2. St. 05. Available at: http://www.materialsnews.ru (accessed: June 19, 2015).
  22. Adryshev A.K., Sokolov V.M., Samojlov V.I. Ohrana truda pri proizvodstve i ispolzovanii berilliya i ego soedinenij [Labor protection by production and use of beryllium and its connections] // Vestnik Rossijskogo universiteta druzhby narodov. Ser. «Inzhenernye issledovaniya». 2007. №3. S. 104–110.
  23. Tyutyunnik O.A., Gecina M.L., Toropchenova E.S., Kubrakova I.V. Mikrovolnovaya probopodgotovka prirodnyh obektov k atomno-absorbcionnomu opredeleniyu rtuti i drugih toksichnyh elementov [Microwave preparation of tests of natural objects for nuclear absorbing definition of mercury and other toxic elements] // Zhurnal analiticheskoj himii. 2013. T. 68. №5. S. 420.
  24. Novoselova A.V., Batsanova L.R. Analiticheskaya himiya berilliya [Analytical chemistry of beryllium]. M.: Nauka, 1966. S. 50–59.
  25. Berillijsoderzhashhie produkty. Metody opredeleniya soderzhaniya berilliya: OST 95.442–76: utv. zamestitelem rukovoditelya organizacii p/ya V-2688 [Beryllium containing products. Methods of definition of the content of beryllium: OST 95.442–76: approved by Deputy Head of the organization of p.ya. V-2688]. M., 1976.
  26. Vasilev V. P. Analiticheskaya himiya. V 2-h ch. [Analytical chemistry. In 2 parts]. M.: Vysshaya shkola, 1989. Ch. 1. Gravimetricheskij i titrimetricheskij metody analiza. 320 s.
  27. Vernidub O.D., Lomakina G.E. Analiz materialov chernoj metallurgii atomno-jemissionnym s ISP metodom s primeneniem MAES [The analysis of materials of ferrous metallurgy by nuclear and emission method with ISP using MAES] // Zavodskaya laboratoriya. Diagnostika materialov. 2007. T. 73. №S. S. 54–57.
  28. Pupyshev A.A., Danilova D.A. Ispolzovanie atomno-emissionnoj spektrometrii s induktivno-svyazannoj plazmoj dlya analiza materialov i produktov chernoj metallurgii [Use of nuclear and emission spectrometry with the inductive and connected plasma for the analysis of materials and products of ferrous metallurgy] // Analitika i kontrol. 2007. T. 11. №2–3. S. 131–181.
  29. Letov A.F., Karachevtsev F.N., Gundobin N.V., Titov V.I. Razrabotka standartnyh obrazcov sostava splavov aviacionnogo naznacheniya [Development of standard samples of structure of alloys of aviation assignment] // Aviacionnye materialy i tehnologii. 2012. №S. S. 393–398.