The structure and properties of permanent magnetic alloys UNDK25BA, manufacturing by directional solidification methods with liquid metal cooler

Cherednichenko I.V., Bondarenko Yu.A., Kolodiazniy M.Yu., Kuzmina N.A., Shubakov V.S., Zhukov D.G.
Cherednichenko I.V., Bondarenko Yu.A., Kolodiazniy M.Yu., Kuzmina N.A., Shubakov V.S., Zhukov D.G. The structure and properties of permanent magnetic alloys UNDK25BA, manufacturing by directional solidification methods with liquid metal cooler // Proceedings of VIAM. 2017. No. 11. DOI: 10.18577/2307-6046-2017-0-11-4-4. URL: https://test.viam.ru/en/journal/2017/11/4
Keywords
cast permanent magnets Alnico, column grain structure magnets, single-crystal magnets, directional solidification, liquid-metal cooler, magnetic properties, high coercive station.
Abstract

Influence of direct crystallizations parameters for crystalline structure, structure of high coercive station and magnetic properties permanent magnetic alloys UNDK25BA with niobium, silicon and sulfur has been investigated. It is established that UNDK25BA alloys have tendency to formation of a regular crystal structures (column or single-crystal); there is an opportunity to make such magnets on the equipment UVNS-5 intended for smelting of shovels for gas-turbine engines. The contains providing the greatest magnetic properties exceeding requirements of GOST 17809–72 and the level of foreign analogs are defined.

Reference list
  1. Mishima T. Nickel-aluminum steel for permanent magnets // Stahl und Eisen. 1931. Vol. 53. P. 79.
  2. Oliver D.A., Shedden J.W. Cooling of Permanent Magnet Alloys in a Constant Magnetic Field // Nature. 1938. Vol. 142. Issue 3587. P. 209.
  3. Pucykin G.G., Pashkov P.P., Vejcil M.Ya. Issledovanie teplofizicheskih uslovij polucheniya i struktury kristallicheski anizotropnyh postoyannyh magnitov [Research of heatphysical conditions of receiving and structure crystal anisotropic constant magnets] // Fizika metallov i metallovedenie. 1963. T. 15. Vyp. 4. S. 118–123.
  4. Lobyncev E.S., Glushko I.M., Kuznecov V.M. Poluchenie magnitov so stolbchatoj strukturoj metodom lit'ya v sotovye formy [Receiving magnets with stolbchaty structure casting method in cellular forms] // Elektrotehnicheskaya promyshlennost. Elektrotehnicheskie stali. 1974. Vyp. 9 (38). S. 15–19.
  5. Livshic B.G., Enikeev G.H., Blatov V.G. Poluchenie magnitov vysokih energij iz splava YuNDK35T5BA v promyshlennyh usloviyah [Receiving magnets of high energy from alloy YuNDK35T5BA in industrial conditions] // IV Vsesoyuz. konf. po postoyannym magnitam. Novocherkassk: AN SSSR, 1971. S. 38.
  6. Sklyarov A.E., Chaban I.P., Gridnev A.I., Vlasov V.G. Poluchenie monokristallov splavov dlya postoyannyh magnitov v promyshlennyh usloviyah [Receiving monocrystals of permanent magnet alloys in industrial conditions] // Vyrashhivanie tugoplavkih redkih metallov. M.: Nauka, 1973. S. 8–11.
  7. Pikunov M.V., Belyaev I.V., Sidorov E.V. Kristallizaciya splavov i napravlennoe zatverdevanie otlivok [Crystallization of alloys and directional solidification of molding]. Vladimir: Vladimirskij gosudarstvennyj universitet. 2002. 213 s.
  8. Cherednichenko I.V., Ospennikova O.G., Piskorskij V.P., Valeev R.A., Buzenkov A.V. Ekonomicheskie aspekty proizvodstva postoyannyh magnitov (obzor) [The economics aspects of manufacturing permanents magnets (review)] // Novosti materialovedeniya. Nauka i tehnika: elektron. nauch.-tehnich. zhurn. 2016. №4 (22). St. 06. Available at: http://materialsnews.ru (accessed: October 02, 2017).
  9. Sergeev V.V., Bulygina T.I. Magnitotverdye materialy [Magneto firm materials]. M.: Energiya, 1980. 222 s.
  10. GOST 21559–76. Materialy magnitotverdye spechennye [State Standard 21559–76. Magneto firm sintered materials]. M.: Izd-vo standartov, 1976. 20 s.
  11. GOST 17809–72. Materialy magnitotverdye litye [State Standard 17809–72. Magneto firm molded materials]. M.: Izd-vo standartov, 2001. 7 s.
  12. GOST R 52956–2008. Materialy magnitotverdye spechennye na osnove splava neodim-zhelezo-bor [State Standard P 52956–2008. Materials magneto firm sintered on the basis of alloy neodim-iron-boron]. M.: Standartinform, 2008. 8 s.
  13. Kekalo I.B., Samarin B.A. Fizicheskoe metallovedenie precizionnyh splavov. Splavy s osobymi magnitnymi svojstvami [Physical metallurgical science of precision alloys. Alloys with special magnetic properties]. M.: Metallurgiya, 1989. 497 s.
  14. Kablov E.N., Piskorskij V.P., Burhanov G.S., Valeev R.A., Moiseeva N.S., Stepanova S.V., Petrakov A.F., Tereshina I.S., Repina M.V. Termostabilnye kolcevye magnity s radialnoj teksturoj na osnove Nd(Pr)–Dy–Fe–Co–B [Thermostable ring magnets with radial structure on the basis of Nd(Pr)–Dy–Fe–Co–B] // Fizika i himiya obrabotki materialov. 2011. №3. S. 43–47.
  15. Kablov E.N., Petrakov A.F., Piskorskij V.P., Valeev R.A., Nazarova N.V. Vliyanie disproziya i kobalta na temperaturnuyu zavisimost namagnichennosti i fazovyj sostav materiala sistemy Nd–Dy–Fe–Co–B [Influence of dysprosium and cobalt on temperature dependence of magnetization and phase structure of material of Nd–Dy–Fe–Co–B system] // Metallovedenie i termicheskaya obrabotka metallov. 2007. №4. S. 3–10.
  16. Kablov E.N., Petrakov A.F., Piskorskij V.P., Valeev R.A., Chabina E.B. Vliyanie prazeodima na magnitnye svojstva i fazovyj sostav materiala sistemy Nd–Pr–Dy–Fe–Co–B [Influence praseodymium on magnetic properties and phase structure of material of Nd–Pr–Dy–Fe–Co–B system ] // MiTOM. 2005. №6. S. 12–16.
  17. Petrakov A.F., Piskorskij V.P., Burhanov G.S., Repina M.V., Ivanov S.I. Osobennosti spekaniya magnitov Nd(Pr)–Dy–Fe–Co–B c vysokim soderzhaniem So [Features of agglomeration of magnets of Nd(Pr)–Dy–Fe–Co–B with the high contents With] // MiTOM. 2012. №7. S. 3–9.
  18. Kablov E.N., Ospennikova O.G., Piskorskij V.P., Rezchikova I.I., Valeev R.A., Davydova E.A. Fazovyj sostav spechennyh materialov sistemy Pr–Dy–Fe–Co–B [Phase composition of the Pr–Dy–Fe–Co–B sintered materials] // Aviacionnye materialy i tehnologii. 2015. №S2 (39). S. 5–10. DOI: 10.18577/2071-9140-2015-0-S2-5-10.
  19. Kablov E.N., Ospennikova O.G., Rezchikova I.I., Piskorskij V.P., Valeev R.A., Korolev D.V. Zavisimost svojstv spechennyh materialov sistemy Nd–Dy–Fe–Co–B ot tehnologicheskih parametrov [Properties dependence of the Nd–Dy–Fe–Co–B sintered materials on technological parameters] // Aviacionnye materialy i tehnologii. 2015. №S2 (39). S. 24–29. DOI: 10.18577/2071-9140-2015-0-S2-24-29.
  20. Kablov E.N., Ospennikova O.G., Korolev D.V., Piskorskij V.P., Valeev R.A., Rezchikova I.I. Mehanizm vliyaniya soderzhaniya bora i termoobrabotki na svojstva magnitov sistemy Nd–Fe–Al–Ti–B [Influence mechanisms of boron content and heat treatment on the properties of Nd–Fe–Al–Ti–B magnets] // Aviacionnye materialy i tehnologii. 2015. №S2 (39). S. 30–34. DOI: 10.18577/2071-9140-2015-0-S2-30-34.
  21. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] // Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
  22. Kolyadov E.V., Gerasimov V.V., Visik E.M. Lite metodom napravlennoj kristallizacii s upravlyaemym gradientom temperatury na fronte kristallizacii [Molding by method of the directed crystallization with managed temperature gradient at the front crystallization] // Litejnoe proizvodstvo. 2016. №8. S. 24–26.
  23. Bondarenko Yu.A., Echin A.B. Napravlennaya kristallizaciya zharoprochnogo splava s peremennym upravlyaemym gradientom [The directed crystallization of hot strength alloy with variable managed gradient] // Voprosy materialovedeniya. 2016. №3 (87). S. 5–58.