The use of epoxy resin system VSE-30, processed by the infusion technology, for the manufacture of low and medium loaded structural polymer composite materials

Kudryavtseva A.N., Tkachuk A.I., Grigoreva K.N., Gurevich Y.M.
UDC
678.072, 678.078
DOI
10.18577/2307-6046-2019-0-1-31-39
Article PDF (Russian) (609.55 KB)
How to cite
Kudryavtseva A.N., Tkachuk A.I., Grigoreva K.N., Gurevich Y.M. The use of epoxy resin system VSE-30, processed by the infusion technology, for the manufacture of low and medium loaded structural polymer composite materials // Proceedings of VIAM. 2019. No. 1. DOI: 10.18577/2307-6046-2019-0-1-31-39. URL: https://test.viam.ru/en/journal/2019/1/4
Keywords
epoxy resin, energy-efficient curing mode, glass transition temperature, vacuum infusion technology, carbon and fiberglass.
Abstract

In the present work, the main physicochemical and thermomechanical characteristics of a two-component epoxy resin system VSE-30, processed by infusion technology and developed at the FSUE «VIAM», are considered. The DSC method is used to study the kinetic parameters of the curing process and to study the effect of the final curing temperature on the level of mechanical and thermomechanical properties of the cured binder VSE-30. The comparison of obtained data with domestic and foreign analogues are given. It has been established that lowering the curing temperature has little effect on the total thermal effect of the reaction. The optimum curing mode of the epoxy resin system VSE-30 at a low temperature is chosen, which allows to obtain materials with a slight decrease in their glass transition temperature and strength properties.

Reference list
  1. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] // Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
  2. Kablov E.N. Materialy novogo pokoleniya – osnova innovatsiy, tekhnologicheskogo liderstva i natsionalnoy bezopasnosti Rossii [Materials of the new generation - the basis of innovation, technological leadership and national security of Russia] // Intellekt i tekhnologii. 2016. №2. S. 16–22.
  3. Kablov E.N., Chursova L.V., Babin A.N., Mukhametov R.R., Panina N.N. Razrabotki FGUP «VIAM» v oblasti rasplavnykh svyazuyushchikh dlya polimernykh kompozitsionnykh materialov [Developments of FSUE «VIAM» in the field of melt binders for polymer composite materials] // Polimernyye materialy i tekhnologii. 2016. T. 2. №2. S. 37–42.
  4. Veshkin E.A. Tekhnologii bezavtoklavnogo formovaniya nizkoporistykh polimernykh kompozitsionnykh materialov i krupnogabaritnykh konstruktsiy iz nikh: dis. … kand. tekhn. Nauk [Technologies of non-autoclaving molding of low-porous polymer composite materials and large-sized structures of them: thesis, Cand. Sc. (Tech.)]. M., 2016. 146 s.
  5. Grigorev M.M., Hrulkov A.V., Gurevich Ya.M., Panina N.N. Izgotovlenie stekloplastikovyh obshivok metodom vakuumnoj infuzii s ispolzovaniem epoksiangidridnogo svyazuyushhego i polupronicaemoj membrany [Manufacture of fiberglass skins using vacuum infusion using epoxyanhydride resin and a semipermeable membrane] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2014. №2. St. 04. Available at: http://viam-works.ru (accessed: November 20, 2018). DOI: 10.18577/2307-6046-2014-0-2-4-4.
  6. Kablov E.N. Kompozity: segodnya i zavtra [Composites: today and tomorrow] // Metally Evrazii. 2015. №1. S. 36–39.
  7. Dry fibrous material for subsequent resin infusion: pat. WO 2013096377; filed 20.12.11; publ. 27.06.13.
  8. Michelsa J., Widmann R., Czaderski C., Allahvirdizadeh R., Motavalli M. Glass transition evaluation of commercially available epoxy resins used for civil engineering applications // Composites Part B: Engineering 2015. Vol. 77. P. 484–493. DOI: 10.1016/j.compositesb.2015.03.053.
  9. Ricciardi M.R., Antonucci V., Durante M. et al. A new cost-saving vacuum infusion process for fiber-reinforced composites: Pulsed infusion // Journal of Composite Materials. 2014. Vol. 48 (11). R. 1365–1373.
  10. Kompaniya «KORSIL TREYD» Lamborghini vybirayet Araldite® [Company «KORSIL TRADE» Lamborghini chooses Araldite®] // Kompozitnyy mir. 2013. №4. S. 34–36.
  11. Shchepotova A., Raykhlin L., Yatsenko S. Nekotoryye aspekty infuzii krupnogabaritnykh konstruktsiy [Some aspects of the infusion of large structures] // Kompozitnyy mir. 2013. №4. S. 44–51.
  12. Arulappan C., Duraisamy A., Adhikari D., Gururaja S. Investigations on pressure and thickness profiles in carbon fiber-reinforced polymers during vacuum assisted resin transfer molding // Journal of Reinforced Plastics and Composites. 2015. Vol. 34. Is. 1. P. 3–18.
  13. Savin S.P. Primeneniye sovremennykh polimernykh kompozitsionnykh materialov v konstruktsii planera samoletov semeystva MS-21 [The use of modern polymer composite materials in the construction of a glider of airplanes of the MS-21 family] // Izvestiya Samarskogo nauchnogo tsentra Rossiyskoy akademii nauk. 2012. T. 14. №4 (2). S. 686–693.
  14. Chursova L.V., Kim M.A., Panina N.N., Shvetsov E.P. Nanomodificirovannoe epoksidnoe svyazuyushhee dlya stroitelnoj industrii [Nanomodified epoxy binder for the construction industry] // Aviacionnye materialy i tehnologii. 2013. №1. S. 40–47.
  15. Chursova L.V., Grebeneva T.A., Panina N.N., Tsybin A.I. Svyazuyushchiye dlya polimernykh kompozitsionnykh materialov stroitelnogo naznacheniya [Binders for polymeric composite materials for construction] // Vse materialy. Entsiklopedicheskiy spravochnik. 2015. №8. S. 13–17.
  16. Mishkin S.I., Raskutin A.E., Evdokimov A.A., Gulyaev I.N. Tehnologii i osnovnye etapy stroitelstva pervogo v Rossii arochnogo mosta iz kompozicionnyh materialov [Technologies and the main stages of construction of the arch bridge first in Russia from composite materials] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2017. №6 (54). St. 05. Available at: http://www.viam-works.ru (accessed: November 20, 2018). DOI: 10.18577/2307-6046-2017-0-6-5-5.
  17. Doneckij K.I., Karavaev R.Yu., Raskutin A.E., Panina N.N. Svojstva ugle- i stekloplastikov na osnove pletenyh preform [Properties of carbon fiber and fiberglass on the basis of braiding preforms] // Aviacionnye materialy i tehnologii. 2016. №4 (45). S. 54–59. DOI: 10.18577/2071-9140-2016-0-4-54-59.
  18. Chursova L.V., Babin A.N., Panina N.N., Tkachuk A.I., Terekhov I.V. Ispolzovaniye aromaticheskikh aminnykh otverditeley dlya sozdaniya epoksidnykh svyazuyushchikh dlya PKM konstruktsionnogo naznacheniya [Usage of aromatic amine curing agents for epoxy resins binders for production of structural PCM] // Trudy VIAM: electron. nauch.-tehnich. zhurn. 2016. №6 (42). St. 04. Available at: http://www.viam-works.ru (accessed: November 20, 2018). DOI: 10.18577/2307-6046-2016-0-6-4-4.
  19. Donetskiy K.I., Khrulkov A.V. Printsipy «zelenoy khimii» v perspektivnykh tekhnologiyakh izgotovleniya izdeliy iz PKM [Principles of «green chemistry» in perspective manufacturing technologies of PCM articles] // Aviacionnye materialy i tehnologii. 2014. №S2 (44). S. 24–28. DOI: 10.18577/2071-9140-2014-0-s2-24-28.
  20. Antyufeeva N.V., Aleksashin V.M., Stolyankov Yu.V. Opredelenie stepeni otverzhdeniya PKM metodami termicheskogo analiza [Polymer composite curing degree evaluation by thermal analysis test methods] //Aviacionnye materialy i tehnologii. 2015. №3 (36). S. 79–83.