Effect of nano and ultradispersed silica particles (SiO2) on the impact strength of epoxy polymers
Pykhtin A.A., Simonov-Emelyanov I.D. Effect of nano and ultradispersed silica particles (SiO2) on the impact strength of epoxy polymers // Proceedings of VIAM. 2019. No. 6. DOI: 10.18577/2307-6046-2019-0-6-3-12. URL: https://test.viam.ru/en/journal/2019/6/1
Keywords
epoxy oligomers (EO), nanoparticles, nanocomposite, ultradispersed particles, white soot, toughness, impact strength, the disperse-filled polymeric composite material.
Abstract
Рresents the results of research work devoted to the study of the dependence of the structure and impact strength (ais) of dispersed-filled epoxy polymers on nanoscale particles (and their agglomerates) of WS-120 grade white soot and monolithic ultradispersed particles of a single-sized dust-like quartz (diameter ~150 nm) and chemical nature (SiO2).
For the first time it has been demonstrated that to increase the impact strength of epoxy dispersed systems, it is most effective to use white soot, which, when forming agglomerates with a diameter of ~150 nm, increases ais ~2 times, while introducing ultrafine particles of dusty quartz with the same diameter (~150 nm) – no more than 20%.
Reference list
- . Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] // Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
- Kablov E.N., Kondrashov S.V., Yurkov G.Yu. Perspektivy ispolzovaniya uglerodsoderzhashchikh nanochastits v svyazuyushchikh dlya polimernykh kompozitsionnykh materialov [Prospects for the use of carbon-containing nanoparticles in binders for polymer composite materials] // Rossiyskiye nanotekhnologii. 2013. T. 8. №3. S. 28–46.
- Kablov E.N. Materialy novogo pokoleniya [New generation materials] // Zashchita i bezopasnost. 2014. №4. S. 28–29.
- Kablov E.N., Solovyanchik L.V., Kondrashov S.V., Yurkov G.YU. i dr. Elektroprovodyashchiye gidrofobnyye polimernyye kompozitsionnyye materialy na osnove okislennykh uglerodnykh nanotrubok, modifitsirovannykh telomerami tetraftoretilena [Electrically Conductive Hydrophobic Polymer Composite Materials Based on Oxidized Carbon Nanotubes Modified by Terafluoroethylene Telomeres] // Rossiyskiye nanotekhnologii. 2016. T. 11. №12. S. 91–97.
- Kondrashov S.V., Shashkeev K.A., Popkov O.V., Solovyanchik L.V. Perspektivnye tehnologii polucheniya funkcionalnyh materialov konstrukcionnogo naznacheniya na osnove nanokompozitov s UNT (obzor) [Prospective producing methods for functional structural materials based on CNT-filled nanocomposites (review)] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2016. №3. St. 07. Available at: http://www.viam-works.ru (accessed: April 02, 2019). DOI: 10.18577/2307-6046-2016-0-3-7-7.
- Larionov S.A., Deev I.S., Petrova G.N., Bejder E.Ya. Vliyanie uglerodnyh napolnitelej na elektrofizicheskie, mehanicheskie i reologicheskie svojstva polietilena [Effect of carbon fillers on the electrical, mechanical and rheological properties of polyethylene] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2013. №9. St. 04. Available at: http://www.viam-works.ru (accessed: April 02, 2019).
- Raskutin A.E. Rossiiskie polimernye kompozitsionnye materialy novogo pokoleniia, ikh osvoenie i vnedrenie v perspektivnykh razrabatyvaemykh konstruktsiiakh [Russian polymer composite materials of new generation, their exploitation and implementation in advanced developed constructions] // Aviacionnye materialy i tehnologii. 2017. №S. S. 349–367. DOI: 10.18577/2071-9140-2017-0-S-349-367.
- Pykhtin A.A. Vysokotekhnologichnyye epoksidnyye nanodispersii i nanokompozity s reguliruyemoy strukturoy i kompleksom svoystv: dis. … kand. tekhn. nauk [High-tech epoxy nanodispersions and nanocomposites with adjustable structure and complex properties: thesis, Cand. Sc. (Tech.)]. M., 2017. 125 c.
- Ajayan P.M., Linda S., Schadler L.S., Braun P.V. Nanocomposite Science and Technology. Wiley-VCH, 2003. 236 p.
- Pol D., Baknell K. Polimernyye smesi [Polymer blends]. SPb.: Nauchnyye osnovy i tekhnologii, 2009. T. II: Funktsionalnyye svoystva. Per. s angl. / pod red. V.N. Kulezneva. 606 s.
- Trofimov N.N., Kanovich M.Z. Prochnost i nadezhnost kompozitov [Durability and reliability of composites]. M.: Nauka, 2014. 422 s.
- Kuleznev V.N. Smesi i splavy polimerov [Mixtures and alloys of polymers]. SPb.: Nauchnyye osnovy i tekhnologii, 2013. 216 s.
- Mir materialov i tekhnologiy. Polimernyye nanokompozity / pod red. Yu. Ving May, Yu. Zhong-Zhen [The world of materials and technology. Polymer nanocomposites / ed. Yu. Ving May, Yu. Zhong-Zhen]. M: Tekhnosfera, 2011. 688 s.
- Marakhovskiy P.S., Kondrashov S.V., Akatenkov R.V. i dr. O modifikatsii teplostoykikh epoksidnykh svyazuyushchikh uglerodnymi nanotrubkami [On the modification of heat-resistant epoxy binders with carbon nanotubes] // Vestnik MGTU im. N.E Baumana. Ser.: Mashinostroyeniye. 2015. №2. S. 118–127.
- Kakhramanov N.T., Azizov A.G., Osipchik V.S., Mamedli U.M., Arzumanova N.B. Nanostrukturirovannyye kompozity i polimernoye materialovedeniye [Nanostructured Composites and Polymer Materials Science] // Plasticheskiye massy. 2016. №1–2. S. 49–57.
- Pykhtin A.A., Simonov-Yemelyanov I.D. Tekhnologicheskiye svoystva nanodispersiy na osnove epoksidnogo oligomera marki DER-330 i beloy sazhi BS-50 [Technological properties of nanodispersions based on epoxy oligomer of the brand DER-330 and BS-50 white soot] // Tonkiye khimicheskiye tekhnologii. 2016. T. 11. №4. S. 63–67.
- Klenin V.I., Shchegolev S.Yu., Lavrushin V.I. Kharakteristicheskiye funktsii svetorasseyaniya dispersnykh system [Characteristic functions of dispersion of light scattering systems]. Saratov: Izd-vo Saratovskogo un-ta. 1977. 177 s.
- Lukyanovich V.M. Elektronnaya mikroskopiya v fiziko-khimicheskikh issledovaniyakh [Electron microscopy in physicochemical studies]. M.: Izd-vo AN SSSR, 1960. S. 90–116.
