Influence of testing temperature on Ti3SiC2 titanium carbosilicide tribological properties

Sevostyanov N.V., Burkovskaya N.P., Bolsunovskaya T.A., Efimochkin I.Yu.
UDC
66.017
DOI
10.18577/2307-6046-2019-0-8-36-45
Article PDF (Russian) (855.17 KB)
How to cite
Sevostyanov N.V., Burkovskaya N.P., Bolsunovskaya T.A., Efimochkin I.Yu. Influence of testing temperature on Ti3SiC2 titanium carbosilicide tribological properties // Proceedings of VIAM. 2019. No. 8. DOI: 10.18577/2307-6046-2019-0-8-36-45. URL: https://test.viam.ru/en/journal/2019/8/5
Keywords
Ti3SiC2, SPS, MAX phase, titanium carbosilicide, spark plasma sintering, friction coefficient, wear, layered structure.
Abstract

The tribotechnical characteristics data of materials based on titanium carbosilicide obtained by various researchers is comprised in the paper. A comparative assessment of crystal structure and lattice parameters of titanium carbosilicide in comparison with layered materials such as graphite and tetragonal boron nitride are given. The authors obtained a material based on titanium carbosilicide synthesized by spark plasma sintering. The temperature influence on friction coefficient of synthesized material was studied against counter bodies of EP866 bearing-grade steel or VK-6 hard alloy. A significant increase in the friction coefficient of titanium carbosilicide in the temperature range from 100 to 200°C has been established.

Reference list
  1. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] // Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
  2. Kablov E.N. Materialy novogo pokoleniya – osnova innovatsiy, tekhnologicheskogo liderstva i natsionalnoy bezopasnosti Rossii [Materials of a new generation - the basis of innovation, technological leadership and national security of Russia] // Intellekt i tekhnologii. 2016. №2 (14). S. 16–21.
  3. Kuznetsov B.Yu., Sorokin O.Yu., Vaganova M.L., Osin I.V. Sintez modelnykh vysokotemperaturnykh keramicheskikh matrits metodom iskrovogo plazmennogo spekaniya i izucheniye ikh svoystv dlya polucheniya kompozitsionnykh materialov [Synthesis of model high-temperature ceramic matrices by the method of spark plasma sintering and the study of their properties for the production of composite materials] // Aviacionnye materialy i tehnologii. 2018. №4 (53). S. 37–44. DOI: 10.18577/2071-9140-2018-0-4-37-44.
  4. Buznik V.M., Kablov E.N. Arkticheskoye materialovedeniye [Arctic materials sciences]. Tomsk: Izd-vo Tomsk. gos. un-ta. 2018. Vyp. 3. 44 s.
  5. Farafonov D.P., Migunov V.P., Aleshina R.Sh. Issledovanie tribotehnicheskih harakteristik materialov, primenyaemyh dlya uprochneniya bandazhnyh polok rabochih lopatok turbin GTD [Tribotechnical characteristics research of materials used for gas turbine engines blade shroud hardening] // Aviacionnye materialy i tehnologii. 2016. № S1. S. 24–30. DOI: 10.18577/2071-9140-2016-0-S1-24-30.
  6. Souchet A., Fontaine J., Belin M. et al. Tribological duality of Ti3SiC2 // Tribology Letters. 2005. Vol. 18. No. 3. P. 341–352.
  7. Myhra S., Summers J.W.B., Kisi E.H. Ti3SiC2 a layered ceramics exhibiting ultra-low friction // Materials Letters. 1999. Vol. 39. P. 6–11.
  8. El-Raghy T., Blau P., Barsoum M.W. Effect of grain size on friction and wear behavior of Ti3SiC2 // Wear. 2000. Vol. 238 (2). P. 125–130.
  9. Sun Z.M., Zhou Y.C., Li S. Tribological Behavior of Ti3SiC2-based Material // Journal of Materials Science & Technology. 2002. Vol. 18. No. 2. P. 142–145.
  10. Zang Y., Ding G.P., Zhou Y.C., Cai B.C. Ti3SiC2 – a self-lubricating ceramic // Materials Letters. 2002. Vol. 55. P. 285–289.
  11. Barsoum M.W., El-Raghy T. Synthesis and Characterization of a Remarkable Ceramic: Ti3SiC2 // Journal of the American Chemical Society. 1996. Vol. 79. P. 1953–1956.
  12. Yuanyuan Zhu, Aiguo Zhou, Yiqiu Ji et al. Tribological properties of Ti3SiC2 coupled with different counter faces // Ceramics International. 2015. Vol. 41. P. 6950–6955.
  13. Huang Z., Zhai H., Guan M. et al. Oxide-film-dependent tribological behaviors of Ti3SiC2 // Wear. 2007. Vol. 262. P. 1079–1085.
  14. Sarkar D., Basu B., Cho S.J. et al. Tribological properties of Ti3SiC2 // Journal of the American Chemical Society. 2005. Vol. 88 (11). P. 3245–3248.
  15. Chandraghosh N. Synthesis and Tribological Characterization of In-Situ Spark Plasma Sintered Ti3SiC2 and Ti3SiC2–TiC Composites: thesis, Oklahoma State University, 2009. P. 105.
  16. Barsoum M.W. The Mn+1AXn phases: A new class of solids: Thermodynamically stable nanolaminates // Progress of Solid State Chemistry. 2000. Vol. 28 (1–4). P. 201–205.
  17. Zhang H.B., Bao Y.W., Zhou Y.C. Current Status in Layered Ternary Carbide Ti3SiC2, a Review // Journal of Materials Science & Technology. 2009. Vol. 25. No. 1. P. 1–38.
  18. Naydich Yu.V., Kolisnechenko G.A. Vzaimodeystviye metallicheskikh rasplavov s poverkhnostyu almaza i grafita [Interaction of metal melts with the surface of diamond and graphite] . Kiev: Naukova dumka, 1967. 89 s.
  19. Kisi E.H., Crossley J.A.A., Myhra S., Barsoum M.W. Structure and crystal chemistry of Ti3SiC2 // Journal of Physics and Chemistry of Solids. 1998. Vol. 59. P. 1437–1443.
  20. Gorbunov D.A. Adgezionnoye vzaimodeystviye na kontakte pri trenii grafita: dis. … kand. fiz.-mat. Nauk [Gorbunov D.A. Adhesive interaction on a contact during graphite friction: thesis, Cand. Sc. (Phys. & Math.)]. M.: NIIgrafit, 1981. 210 s.
  21. Klinger L.L., Gorbunov D.A. Modelirovaniye sluchaynykh bluzhdaniy po granitsam zeren [Modeling of random walks along grain boundaries] // Fiziko-khimicheskaya mekhanika materialov. 1986. T. 61. №6. S. 1084–1088.
  22. Barsoum M.W. MAX Phases. Properties of Machinable Ternary Carbides and Nitrides. Wiley-VCH Verlag GmbH & Co. KGaA, 2013. 437 p.
  23. Sorokin O.Yu., Solntsev S.St., Evdokimov S.A., Osin I.V. Metod gibridnogo iskrovogo plazmennogo spekaniya: princip, vozmozhnosti, perspektivy primeneniya [Hybrid spark plasma sintering method: principle, possibilities, future prospects] // Aviacionnye materialy i tehnologii. 2014. №S6. S. 11–16. DOI: 10.18577/2071-9140-2014-0-s6-11-16.
  24. Grashchenkov D.V., Sevostyanov N.V., Efimochkin I.Yu., Burkovskaya N.P. Sintez karbosilitsida titana Ti3SiC2 metodom iskrovogo plazmennogo spekaniya [Synthesis of titanium carbosilicide Ti3SiC2 by spark plasma sintering] // Konstruktsii iz kompozitsionnykh materialov. 2016. №4. S. 23–26.
  25. Treniye, iznashivaniye i smazka: spravochnik v 2-kh kn. / pod red. I.V. Kragelskogo, V.V. Alisina [Friction, wear and lubrication: a reference book in 2 books. / ed. I.V. Kragelsky, V.V. Alisin]. M.: Mashinostroyeniye, 1978. Kn. 1. 400 s.