Influence of elastomeric modifiers on properties of metalpolymer compositions

Kuznetsova V.A., Kozlova A.A., Zheleznyak V.G., Shapovalov G.G.
UDC
66.017
DOI
10.18577/2307-6046-2019-0-8-46-55
Article PDF (Russian) (737.95 KB)
How to cite
Kuznetsova V.A., Kozlova A.A., Zheleznyak V.G., Shapovalov G.G. Influence of elastomeric modifiers on properties of metalpolymer compositions // Proceedings of VIAM. 2019. No. 8. DOI: 10.18577/2307-6046-2019-0-8-46-55. URL: https://test.viam.ru/en/journal/2019/8/6
Keywords
metal-polymer composition, filling materials, epoxies, low molecular rubbers, spherical aluminium powder.
Abstract

In work possibility of application of low molecular elastomer for updating of metal-polymeric compositions which are used as the putty is investigated. Influence of the maintenance of elastomeric modifiers in metal-polymeric composition on mechanical, technological properties, adhesive durability, and also hardness of the modified metal-polymeric compositions is investigated. It is shown that application of low molecular rubbers PDI-3AK and PPG-3A as modifiers of metal-polymeric compositions promotes increase of their elasticity.

Reference list
  1. Kablov E.N. Klyuchevaya problema – materialy [The key problem is materials] // Tendentsii i oriyentiry innovatsionnogo razvitiya Rossii. M.: VIAM, 2015. S. 458–464.
  2. Kablov E.N. Rol khimii v sozdanii materialov novogo pokoleniya dlya slozhnykh tekhnicheskikh sistem [The role of chemistry in the creation of new generation materials for complex technical systems] // Tez. dokl. XX Mendeleyevskogo sezda po obshchey i prikladnoy khimii. UrO RAN, 2016. S. 25–26.
  3. Kablov E.N. Bez novykh materialov – net budushchego [Without new materials – there is no future] // Metallurg. 2013. №12. S. 4–8.
  4. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] // Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
  5. Kondrashov E.K., Kuznetsova V.A., Semenova L.V., Lebedeva T.A. Osnovnyye napravleniya povysheniya ekspluatatsionnykh, tekhnologicheskikh i ekologicheskikh kharakteristik lakokrasochnykh pokrytiy dlya aviatsionnoy tekhniki [The main directions of increasing the operational, technological and environmental characteristics of coatings for aircraft] // Rossiyskiy khimicheskiy zhurnal. 2010. T. LIV. №1. S. 96–102.
  6. Pavlyuk B.Ph. Osnovnye napravleniya v oblasti razrabotki polimernyh funktsionalnyh materialov [The main directions in the field of development of polymeric functional materials] // Aviacionnye materialy i tehnologii. 2017. №S. S. 388–392. DOI: 10.18577/2071-9140-2017-0-S-388-392.
  7. Kondrashov E.K., Kuznetsova V.A., Semenova L.V., Lebedeva T.A., Malova N.E. Razvitiye aviatsionnykh lakokrasochnykh materialov [Development of aviation paints and varnishes] // Vse materialy. Entsiklopedicheskiy spravochnik. 2012. №5. S. 49–54.
  8. Zheleznyak V.G. Sovremennyye lakokrasochnyye materialy dlya primeneniya v izdeliyakh aviatsionnoy tekhniki [Modern paint and varnish materials for use in aviation equipment products] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2019. №5 (77). St. 07. Available at: http://www.viam-works.ru. (accessed: May 17, 2019). DOI: 10.18577/2307-6046-2019-0-5-62-67.
  9. Metallopolimernaya kompozitsiya: pat. 2574212C1 Ros. Federatsiya [Metal-polymer composition: pat. 2574212C1 Rus. Federation]; zayavl. 10.11.14; opubl. 12.01.16.
  10. Metallopolimernaya kompozitsiya: pat. 2618031C1 Ros. Federatsiya [Metal-polymer composition: pat. 2618031C1 Rus. Federation]; zayavl 02.06.16; opubl. 02.05.17.
  11. Kuznetsova V.A., Deyev I.A., Kuznetsov G.V., Kondrashov E.K. Vliyaniye napolnitelya na ustalostnuyu prochnost i mikrostrukturu svobodnykh polimernykh plenok pri tsiklicheskom rastyazhenii [The effect of filler on the fatigue strength and microstructure of free polymer films under cyclic tension] // Zavodskaya laboratoriya. 2014. T. 80. №5. S. 35–39.
  12. Sosnina S.A., Kuleshova I.D. Regulirovaniye vzaimodeystviya komponentov v napolnennykh lakokrasochnykh kompozitsiyakh [Regulation of the interaction of components in filled paint compositions] // Lakokrasochnyye materialy i ikh primeneniye 2011. №1. S. 60–62.
  13. Narisava I. Prochnost polimernykh materialov. Per. s yap. [Strength of polymer materials. Line from Jap.]. M.: Khimiya, 1987. 364 s.
  14. Kuznetsova V.A., Emelyanov V.V., Marchenko S.A., Silayeva A.A. Primeneniye metallopolimernykh kompozitsiy dlya zadelki defektov lit'ya i vyravnivaniya poverkhnosti na detalyakh i izdeliyakh aviatsionnoy tekhniki [Application of metalpolymeric compositions for seal of casting defects and surface alignment on details and products of aviation engineering] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2019. №4 (76). St. 08. Available at: http://www.viam-works.ru. (accessed: June 18, 2019). DOI: 10.18577/2307-6046-2019-0-4-67-75.
  15. Yakovlev A.D., Yakovlev S.A. Lakokrasochnyye pokrytiya funktsionalnogo naznacheniya [Functional coatings]. SPb.: Khimizdat, 2016. 272 s.
  16. Petrov G.N., Sinayskiy A.G., Dalgren I.V. Zhidkiye uglevodopodnyye kauchuki i oblasti ikh ppimeneniya [Liquid hydrocarbon rubbers and their applications] // Klei. Germetiki. Tekhnologii. 2009. №10. S. 24–27.
  17. Yulovskaya V.D. Oligomery. Kauchuk-oligomernyye kompozitsii, struktura i svoystva // uchebnoye posobiye [Oligomers. Rubber-oligomeric compositions, structure and properties: textbook] / Federalnoye agentstvo po obrazovaniyu, Moskovskaya gos. akad. tonkoy khimicheskoy tekhnologii im. M.V. Lomonosova. M., 2008. 46 s.
  18. Pyrikov A.V., Loyko D.P., Kochergin YU.S. Modifikatsiya epoksidnykh smol zhidkimi polisulfidnymi i kapboksilatnymi butadiyenovymi kauchukami [Modification of epoxy resins with liquid polysulfide and carboxylate butadiene rubbers] // Klei. Germetiki. Tekhnologii. 2010. №1. S. 28–33.
  19. Chalykh A.E., Kochnova Z.A., Zhavoronok E.S. Sovmestimost i diffuziya v sistemakh epoksidnyye oligomery–zhidkiye karboksilatnyye kauchuki [Compatibility and diffusion in systems epoxy oligomers – liquid carboxylate rubbers] // Vysokomolekulyarnyye soyedineniya. Ser.: A. 2001. T. 43. №12. S. 1–9.
  20. Lutsenko A.N., Slavin A.V., Erasov V.S., Khvackij K.K. Prochnostnye ispytaniya i issledovaniya aviacionnyh materialov [Strength tests and researches of aviation materials] // Aviacionnye materialy i tehnologii. 2017. №S. S. 527–546. DOI: 10.18577/2071-9140-2017-0-S-527-546.
  21. Vladimirskiy V.N., Ofitserova M.G., Novikova T.A., Karimova S.A., Pavlovskaya T.G. Tekhnologiya remonta LKP na vneshney poverkhnosti izdeliy AT [Technology of repair of paint coatings on exterior surface of products of aviation engineering] // Aviatsionnyye materialy i tekhnologii. 2003. №2. S. 86–89.
  22. Semenova L.V., Nefedov N.I., Belova M.V., Laptev A.B. Sistemy lakokrasochnyh pokrytij dlya vertoletnoj tehniki [Systems of paint coatings for helicopter equipment] // Aviacionnye materialy i tehnologii. 2017. №4 (49). S. 56–61. DOI: 10.18577/2071-9140-2017-0-4-56-61.
  23. Kablov V.F. Sistemnaya tekhnologiya kauchuk-oligomernykh kompozitsiy [System technology of rubber-oligomer compositions] // Oligomery-2009 / Rossiyskaya akademiya nauk, Ministerstvo obrazovaniya i nauki RF. M., 2009. S. 162–191.
  24. Davydova V.N., Lukasik V.A., Antsupov Yu.A., Petrukhina E.V. Svyaz tekhnologii izgotovleniya i svoystv kauchuk-oligomernoy kompozitsii [The connection of manufacturing technology and properties of rubber-oligomeric composition] // Izvestiya Volgogradskogo gosudarstvennogo tekhnicheskogo universiteta. 2004. №2. S. 114–116.
  25. Kalinina N.K., Sakina A.I., Babina K.S., Osipchik V.S. Kauchuk-oligomernyye kompozitsii na osnove khlorsulfirovannogo polietilena [Rubber-oligomeric compositions based on chlorosulfonated polyethylene] // Plasticheskiye massy. 2016. №7–8. S. 45–47.