Research of the effect of epoxy resins on the properties of benzoxazine monomer BA-a and theirs copolymers

Khmelnitskiy V.V., Sarychev I.A. S, Khaskov M.A., Guseva M.A.
UDC
678.072
DOI
10.18577/2307-6046-2020-0-1-38-46
Article PDF (Russian) (990.14 KB)
How to cite
Khmelnitskiy V.V., Sarychev I.A. S, Khaskov M.A., Guseva M.A. Research of the effect of epoxy resins on the properties of benzoxazine monomer BA-a and theirs copolymers // Proceedings of VIAM. 2020. No. 1. DOI: 10.18577/2307-6046-2020-0-1-38-46. URL: https://test.viam.ru/en/journal/2020/1/4
Keywords
benzoxazines, polymeric benzoxazines, epoxy resin, thermosets, polymer resin, thermal properties.
Abstract

One of the important properties of benzoxazines as a class of polymers is their high chemical compatibility with various resins. In the present work compositions based on benzoxazine monomer and epoxy resins of various structures were obtained. Their rheological characteristics in special dynamic viscosity at different temperatures and profiles in dynamic mode were determinated. Water absorption and glass transition temperature of polymer matrix samples were investigated. Conclusions about modification of benzoxazine monomers with epoxy resins have been made.

Reference list
  1. Kablov E.N. Materials of a new generation – the basis of innovation, technological leadership and national security of Russia. Intellekt i tekhnologii, 2016, no. 2 (14), pp. 16–21.
  2. Raskutin A.E. Russian polymer composite materials of new generation, their exploitation and implementation in advanced developed constructions. Aviacionnye materialy i tehnologii, 2017, no. S, pp. 349–367. DOI: 10.18577/2071-9140-2017-0-S-349-367.
  3. Kablov E.N. Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030». Aviacionnye materialy i tehnologii, 2015, no. 1 (34), pp. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
  4. Kondrashov S.V., Shashkeev K.A., Petrova G.N., Mekalina I.V. Constructional polymer composites with functional properties. Aviacionnye materialy i tehnologii, 2017, no. S, pp. 405–419. DOI: 10.18577/2071-9140-2017-0-S-405-419.
  5. Kablov E.N., Startsev V.O. Systematical analysis of the climatics influence on mechanical properties of the polymer composite materials based on domestic and foreign sources (review). Aviacionnye materialy i tehnologii, 2018, no. 2 (51), pp. 47–58. DOI: 10.18577/2071-9140-2018-0-2-47-58.
  6. Anastas P., Eghbali N. Green chemistry: principles and practice. Chemical Society Reviews, 2010, vol. 39, no. 1, pp. 301-312.
  7. Kablov E.N., Chursova L.V., Babin A.N., Mukhametov R.R., Panina N.N. Developments of FSUE VIAM in the field of melt binders for polymer composite materials. Polimernye materialy i tekhnologii, 2016, vol. 2, no. 2, pp. 37–42.
  8. Advanced and emerging polybenzoxazine science and technology / H. Ishida, P. Froimowicz. Elsevier, 2017, pp. 9–21.
  9. Ghosh N.N., Kiskan B., Yagci Y. Polybenzoxazines – new high performance thermosetting resins: synthesis and properties. Progress in Polymer Science, 2007, vol. 32, pp. 1344–1391.
  10. Dunkers J., Zarate E.A., Ishida H. Crystal structure and hydrogen-bonding characteristics of N, N-bis (3,5-dimethyl-2-hydroxybenzyl) methylamine, a benzoxazine dimer. The Journal of Physical Chemistry, 1996, vol. 100, pp. 13514–13520.
  11. Kim H. D., Ishida H. Model compounds study on the network structure of polybenzoxazines. Macromolecules, 2003, vol. 36, pp. 8320–8329.
  12. Khmelnitsky V.V., Shimkin A.A. Polymeric benzoxazines – a new type of high temperature polymer resins (review). Trudy VIAM, 2019, no. 2 (74), paper no. 05. Available at: http://viam-works.ru (accessed: December 05, 2019). DOI: 10.18577 / 2307-6046-2019-0-2-43-57.
  13. Rimdusit S., Hemvichian K., Kasemsiri P., Dueramae I. Shape memory polymers from benzoxazine-modified epoxy. Smart Materials Structures, 2013, vol. 22, pp. 12. DOI: 10.1088/0964-1726/22/7/075033.
  14. Handbook of thermoset plastics / H. Dodiuk, S.H. Goodman. William Andrew, 2013, pp. 253–295.
  15. Takeichi T., Guo Y., Rimdusit S. Performance improvement of polybenzoxazine by alloying with polyimide: effect of preparation method on the properties. Polymer, 2005, vol. 46, pp. 4909–4916.
  16. Rimdusit S. et al. Toughening of polybenzoxazine by alloying with urethane prepolymer and flexible epoxy: a comparative study. Polymer Engineering & Science, 2005, vol. 45, pp. 288–296.
  17. Kumar K.S.S., Nair C.P. R., Ninan K.N. Investigations on the cure chemistry and polymer properties of benzoxazine – cyanate ester blends. European Polymer Journal, 2009, vol. 45, pp. 494–502.
  18. Ishida H. Process for preparation of benzoxazine compounds in solventless systems: pat. US5543516; filed 18.05.1994; publ. 06.08.1996.
  19. Rimdusit S., Bangsen W., Kasemsiri P. Chemorheology and thermomechanical characteristics of benzoxazine urethane copolymers. Journal of Applied Polymer Science, 2011, vol. 121, pp. 3669–3678.
  20. Abdelkader A.F., White J.R. Water absorption in epoxy resins: The effects of the crosslinking agent and curing temperature. Journal of Applied Polymer Science, 2005, vol. 98, pp. 2544–2549.
  21. Rimdusit S., Kunopast P., Dueramae I. Thermomechanical properties of arylamine-based benzoxazine resins alloyed with epoxy resin. Polymer Engineering & Science, 2011, vol. 51, pp. 1797–1807.