Research of influence of modifiers of varied nature on the thermo-oxidative stability of a model silicone binder

Shitov R.O., Kitaeva N.S., Shiryakina Yu.M., Kurshev E.V.
UDC
667.621
DOI
10.18577/2307-6046-2020-0-67-19-28
Article PDF (Russian) (875.75 KB)
How to cite
Shitov R.O., Kitaeva N.S., Shiryakina Yu.M., Kurshev E.V. Research of influence of modifiers of varied nature on the thermo-oxidative stability of a model silicone binder // Proceedings of VIAM. 2020. No. 6-7. DOI: 10.18577/2307-6046-2020-0-67-19-28. URL: https://test.viam.ru/en/journal/2020/6-7/3
Keywords
thermostable siloxanes, film-foming silicone binder, modifier, thermo-oxidative stability.
Abstract

The literature data on the use of various modifiers as additives that increase heat resistance of polymer binders in an oxidizing environment are analyzed. Influence of the nature of modifiers – pyrogenic silicon dioxide (aerosil A-380), cristobalite, asbestos (processed for adhesives), wollastonite, iron oxide (III), cerium (IV) oxide on the thermo-oxidative stability of a model silicone binder, and their concentration patterns have been investigated. Microphase structure of modified samples with a cured matrix of a model silicone binder was evaluated.

Reference list
  1. Kablov E.N. The main directions of the development of materials for aerospace engineering 21st century. Perspektivnyye materialy, 2000, no. 3, pp. 27–36.
  2. Kablov E.N., Startsev O.V., Deev I.S., Nikishin E.F. Properties of polymer composite materials after exposure to outer space in near-Earth orbits. Part 2. All materials. Encyclopedic reference book, 2012, no, 11, pp. 2–16.
  3. Kablov E.N. Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030». Aviacionnye materialy i tehnologii, 2015, no. 1 (34), pp. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
  4. Aldoshin S.M., Badamshina E.R., Kablov E.N. Polymer nanocomposites - a new generation of polymer materials with enhanced performance. Abstracts of scientific technol. sections I Int. nanotechnology forum Rusnanotech'08. Moscow: RUSNANO, 2008, vol. 1, pp. 385–387.
  5. Devendra K., Rangaswamy T. Determination of mechanical properties of Al2O3, Mg(OH)2 and SiC filled E-glass/epoxy composites. International Journal of Engineering Research and Applications, 2012, vol. 2, pp. 2028–2033.
  6. Ajayan P.M., Linda S., Schadler L.S., Braun P.V. Nanocomposite Science and Technology. Wiley-VCH, 2003, 236 p.
  7. Petrucci R., Torre L. Filled Polymer Composites. Modification of Polymer Properties. William Andrew Publishing, 2017, pp. 23–46.
  8. Thostenson E.T., Ren Z., Chou T.W. Advances in the science and technology of carbon nanotube and their composites: a review. Composite science Technology, 2001, vol. 61, no. 13, pp. 1899–1912.
  9. Ponomareva E.A., Yakovenko T.V. Influence of preparation with nanoparticle of silver on properties of textile materials. Aviacionnye materialy i tehnologii, 2013, no. 4, pp. 35–38.
  10. Yurkov G.Yu., Kondrashov S.V., Kraev I.D. Nanocomposites based on high-density polyethylene and cobalt nanoparticles: synthesis, structure and properties. Aviacionnye materialy i tehnologii, 2014, no. S2, pp. 29–33. DOI: 10.18577/2071-9140-2014-0-S2-29-33.
  11. Gunyaev G.M., Chursova L.V., Komarova O.A., Gunyaeva A.G. Constructional carbon the plastics modified by nanoparticles. Aviacionnye materialy i tehnologii, 2012, no. S, pp. 277–286.
  12. Kovrizhkina N.A., Kuznetsova V.A., Silaeva A.A., Marchenko S.A. Ways to improve the properties of paint coatings by adding different fillers (review). Aviacionnye materialy i tehnologii, 2019, no. 4 (57), pp. 41–48. DOI: 10.18577/2071-9140-2019-0-4-41-48.
  13. Roger R. Fillers for Polymer Applications. Polymers and Polymeric Composites: A Reference Series. Springer International Publishing, 2017, 489 p.
  14. Yue Y., Zhang C., Zhang H. et al. Rheological behaviors of fumed silica filled polydimethylsiloxane suspensions. Composites: Part A, 2013, vol. 53, pp. 152–159.
  15. Pykhtin A.A., Simonov-Emelyanov I.D. Effect of nano and ultradispersed silica particles (SiO2) on the impact strength of epoxy polymers. Trudy VIAM, 2019, no. 6 (78), paper no. 01. Available at: http://www.viam-works.ru (accessed: February 20, 2020). DOI: 10.18577/2307-6046-2019-0-6-3-12.
  16. Pratapa S., Wahyuni T., Fauziyah N.A. et al. Synthesis and thermomechanical characterization of PEG/cristobalite composites. Journal of Mechanical Science and Technology, 2017, vol. 31, no. 8, pp. 3653–3656.
  17. Hamdani S., Longuet C., Lopez-Cuesta J., Ganachaud F. Calcium and aluminium-based fillers as flame-retardant additives in silicone matrices. I. Blend preparation and thermal properties. Polymer Degradation and Stability, 2010, vol. 95, pp. 1911–1919.
  18. Park E.-S. Mechanical Properties and Processibilty of Glass-, Fiber-, Wollastonite-, and Fluoro-Rubber-Reinforced Silicone Rubber Composites. Wiley InterScience, 2006, vol. 105, no. 2. P. 460–468.
  19. Petrova A.P. Adhesive materials: reference book. Moscow: Kauchuk i rezina, 2002, 196 p.
  20. Xu X., Liu J., Chen P. et al. The effect of ceria nanoparticles on improving heat resistant properties of fluorosilicone rubber. Journal of Applied Polymer Science, 2016, vol. 133, no. 42, pp. 44117–44124.
  21. Han R., Wang Z., Zhang Y., Niu K. Thermal stability of CeO2/graphene/phenyl silicone rubber composites. Polymer Testing, 2019, vol. 75, pp. 277–283.
  22. Hamdani S., Longuet C., Perrin D., Lopez-cuesta J.-M., Ganachaud F. Flame retardancy of silicone-based materials. Polymer Degradation and Stability, 2009, vol. 94, pp. 465–495.
  23. Kondrashov E.K., Kitaeva N.S., Shiryakina Yu.M., Novikova A.A., Malova N.E., Shimkin A.A., Ponomarenko S.A., Apalkov A.V., Fedosov I.A. Chemical modification of branched polyorganosiloxanes as a molecular design method for solving the problem of creating a polymer base for highly heat-resistant cold cured coatings. Bulletin of the Russian Foundation for Basic Research, 2015, no. 1. (85), pp. 60–71.
  24. Zhu B., Katsoulis D.E., Keryk J.R., McGarry F.J. Toughening of a polysilsesquioxane network by homogeneous incorporation of polydimethylsiloxane segments. Polymer, 2000, vol. 41, pp. 7559–7573.
  25. Buch R.R. Rates of heat release and related fire parameters for silicones. Fire Safety Journal, 1991, vol. 17, no. 1, pp. 1–12.
  26. Hshieh F.-Y. Shielding effects of silica-ash layer on the combustion of silicones and their possible applications on the fire retardancy of organic polymers. Fire and Materials, 1998, vol. 22, no. 2, pp. 69–76.
  27. Guseva М.А. The use of the rheological tests in the development of polymeric ma-terials for various purposes. Trudy VIAM, 2018, no. 11 (71), paper no. 05. Available at: http://www.viam-works.ru (accessed: February 20, 2020). DOI: 10.18577/2307-6046-2018-0-11-35-44.