Use of modifiers for increase of operational properties of paint coatings on the basis of the epoxy film-forming (review)

Kuznetsova V.A., Emelyanov V.V., Shapovalov G.G., Kovrizhkina N.A.
Kuznetsova V.A., Emelyanov V.V., Shapovalov G.G., Kovrizhkina N.A. Use of modifiers for increase of operational properties of paint coatings on the basis of the epoxy film-forming (review) // Proceedings of VIAM. 2021. No. 12. DOI: 10.18577/2307-6046-2021-0-12-63-72. URL: https://test.viam.ru/en/journal/2021/12/8
Keywords
epoxy oligomers, hardeners, modifiers, adhesion, water absorption, physicomechanical properties, ingibiruyushchy pigments.
Abstract

Epoxy oligomers are one of the most widespread synthetic polymers who during already enough long time apply to manufacturing of paint and varnish materials. Possessing number of valuable properties, epoxy paint and varnish materials have also shortcomings for which elimination use different receptions, including physical and chemical updatings using different mono- and elastomeric, silicon- and organophosphorous and other connections. The main attention is given to use of different modifiers for improvement of operational properties of anticorrosion paint coatings.

Reference list
  1. Kablov E.N., Petrova A.P. History of Aviation Materials Science. VIAM – 75 years of search, creativity, discoveries. Moscow: Nauka, 2007. 343 p.
  2. Kablov E.N. Aviation materials science: results and prospects. Vestnik Rossiyskoy akademii nauk, 2002, vol. 72, no. 1, pp. 3–12.
  3. Kablov E.N. Materials and chemical technologies for aviation technology. Vestnik Rossiyskoy akademii nauk, 2012, vol. 82, no. 6, pp. 520–530.
  4. Fomina M.A., Karimova S.A. Analysis of the corrosion state of materials of the airframe of aircraft of the "Su" type after long-term operation. Korroziya: materialy, zashchita, 2014, no. 9, pp. 20–24.
  5. Kablov E.N., Startsev O.V., Medvedev I.M. Review of international experience on corrosion and corrosion protection. Aviacionnye materialy i tehnologii, 2015, no. 2 (35), pp. 76–87. DOI: 10.18577/2071-9140-2015-0-2-76-87.
  6. Zheleznyak V.G. Modern paint and varnish materials for use in aviation equipment products. Trudy VIAM, 2019, no. 5 (77), paper no. 07. Available at: http://www.viam-works.ru. (accessed: June 24, 2021). DOI: 10.18577/2307-6046-2019-0-5-62-67.
  7. Pavlyuk B.Ph. The main directions in the field of development of polymeric functional materials. Aviacionnye materialy i tehnologii, 2017, no. S, pp. 388–392. DOI: 10.18577/2071-9140-2017-0-S-388-392.
  8. Semenova L.V., Malova N.E., Kuznetsova V.A., Pozhoga A.A. Paint and varnish materials and coatings. Aviacionnye materialy i tehnologii, 2012, no. S, pp. 315–327.
  9. Kozlova A.A., Kondrashov Je.K. Systems of paint coatings for anticorrosive protection of magnesium alloys. Aviacionnye materialy i tehnologii, 2014, no. 2, pp. 44–47. DOI: 10.18577/2071-9140-2014-0-2-44-47.
  10. Kablov E.N. Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030». Aviacionnye materialy i tehnologii, 2015, no. 1 (34), pp. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
  11. Eselev A.D., Bobylev V.A. Epoxy resins and hardeners for the production of paints and varnishes. Lakokrasochnyye materialy i ikh primenenie, 2005, no. 10, pp. 16–25.
  12. Blagonravova A.A., Nepomnyashchy A.I. Epoxy lacquer resins. Moscow: Khimiya, 1970, 248 p.
  13. Paints and varnishes. Trans. from English. Ed. H.V. Chetfield. Moscow: Khimiya, 1988, 640 p.
  14. Reibman A.I. Protective paints and varnishes. Leningrad: Chemistry, 1978, 296 p.
  15. Goldberg M.M. Materials for paints and varnishes. Moscow: Chemistry, 1972, 343 p.
  16. Bobylev V.A. State and development prospects of epoxy materials. Special resins. Kompozitnyy mir, 2006, no. 6, pp. 14–17.
  17. Lapitskaya T.V., Lapitsky V.A. Epoxy materials. Kompozitnyy mir, 2006, no. 7, pp. 16–17.
  18. Kochnova Z.A., Lark E.S., Chalykh A.E. Epoxy resins and hardeners: industrial products. Moscow: Paint Media LLC, 2006, 200 p.
  19. Chebotareva E.G., Ogrel L.Yu. Modern trends in the modification of epoxy oligomers. Fundamentalnye issledovaniya, 2008, no. 4, pp. 102–104.
  20. Mayorova N.V., Karjakina M.I., Kargin V.A. et al. Influence of plasticization on the processes of structure formation and properties of paint coatings. Lakokrasochnyye materialy i ikh primenenie, 1969, no. 3, pp. 17–19.
  21. Baev A.A., Mikitaev A.K. Reducing the flammability of epoxy resins using halogen-containing epoxy compounds. Plasticheskiye massy, 1986, no. 2, pp. 51–53.
  22. Kirillov A.N., Sof'ina A.N., Garipov R.M., Deberdeev R.Ya. Modification of epoxyamine compositions with epoxyurethane oligomers. Lakokrasochnyye materialy i ikh primenenie, 2003, no. 4, pp. 25–28.
  23. Problems of protective coatings: a review of the materials of the European conference "Protective coating", Dusseldorf (Germany). Lakokrasochnye materialy i ikh primenenie, 2013, no. 9, pp. 33–35.
  24. Lark E.S., Senchikhin I.N., Pchelintsev I.E., Roldugin V.I. Determination of the optimal mode of epoxyamine systems according to TTT diagrams. Vysokomolekulyarnye soedineniya, Ser. B, 2018, vol. 60, no. 2, pp. 140–146.
  25. Moshinsky L.Ya. Epoxy resins and hardeners. Tel Aviv: Arcadia Press Ltd, 1995, pp. 40–42.
  26. Chebotarevsky V.V., Eselev A.D., Smirnova L.I., Gabitov I.Z. New epoxy-polyamide primers and enamels. Lakokrasochnye materialy i ikh primenenie, 1970, no. 3, pp. 22–25.
  27. Mostovoy A.S., Panova L.G. Investigation of the possibility of using low molecular weight polyamide PO-300 as a "cold" hardener for epoxy oligomers. Plasticheskiye massy, 2016, no. 1–2, pp. 16–18.
  28. Lark E.S., Senchikhin I.N., Kolesnikova E.F. et al. Features of curing mixtures of dianic and aliphatic epoxy oligomers with different reactivity. Vysokomolekulyarnye soedineniya, Ser. B, 2010, vol. 52, no. 4, pp. 706–714.
  29. Sukhareva L.A., Mironova T.A., Fedyakova N.V. et al. Properties and structure of modified epoxy-polyamine coatings. Lakokrasochnye materialy i ikh primenenie, 1989, no. 5, pp. 50–52.
  30. Composition for protective coating: pat. 2402585 Rus. Federation; filed 31.03.09; publ. 27.10.10.
  31. Kuznetsova V.А., Zheleznyak V.G., Kurshev E.V., Yemelyanov V.V. Research of fuel- and water resistance of coatings based on the filled epoxy-thiokol polymeric compositions. Aviacionnye materialy i tehnologii, 2021, no. 2 (63), paper no. 10. Available at: http://www.journal.viam.ru (accessed: June 24, 2021). DOI: 10.18577/2713-0193-2021-0-2-93-102.
  32. Lyalushko D.S. Modification of epoxy oligomers with carboxylated butadiene-acrylonitrile rubbers in order to create aviation fuel-resistant coatings: thesis abstract, Cand. Sc. (Tech.). Moscow, 1983, pp. 13–14.
  33. Chalykh A.E., Lark E.S., Kochnova Z.A., Kiselev M.R. Structure formation in binary mixtures carboxyl-containing rubber – epoxy oligomer. Khimicheskaya fizika, 2009, vol. 28, no. 6, pp. 91–96.
  34. Kochnova Z.A., Lark E.S., Kotova A.V. Peculiarities of obtaining epoxy-rubber compositions based on liquid nitrile-butadiene rubbers and epoxy oligomers. Lakokrasochnye materialy i ikh primenenie, 1998, no. 11, pp. 27–28.
  35. Pyrikov A.V., Loiko D.P., Kochergin Yu.S. Modification of epoxy resins with liquid polysulfide and carboxylate butadiene rubbers. Klei. Germetiki, Tekhnologii, 2010, no. 1, pp. 28–33.
  36. Kuznetsova V.A., Kozlova A.A., Zheleznyak V.G., Shapovalov G.G. Influence of elastomeric modifiers on properties of metal-polymeric compositions. Trudy VIAM, 2019, no. 8 (80). Art. 06. URL: http://www.viam-works.ru (date of access: June 24, 2021). DOI: 10.18577/2307-6046-2019-0-8-46-55.
  37. Chalykh A.E., Kochnova Z.A., Lark E.S., Baru R.L. Chemical transformations and rheokinetics in the carboxyl-containing rubber-epoxy oligomer system. Izvestiya vuzov. Khimiya i khimicheskaya tekhnologiya, 2007, vol. 50, no. 1, pp. 43–47.
  38. Lark E.S., Senchikhin I.N. Estimation of the cross-linking density of a densely reticulated polymer taking into account the rigidity of the chain fragment between the network nodes. Vysokomolekulyarnye soedineniya, Ser. B, 2019. vol. 61, no. 4, pp. 282–288.
  39. Chalykh A.E., Kochnova Z.A., Lark E.S. Compatibility and diffusion in systems epoxy oligomers – liquid carboxylate rubbers. Vysokomolekulyarnye soedineniya, Ser. A, 2001, vol. 43, no. 12, pp. 2147–2155.
  40. Chalykh A.E., Lark E.S., Kochnova Z.A. Interaction of carboxyl-containing nitrile rubber and epoxy oligomer. Vysokomolekulyarnye soedineniya, Ser. B, 2010, vol. 52, no. 5, pp. 880–887.
  41. Lark E.S. Multicomponent polymer networks based on epoxy oligomers with active polyfunctional groups: thesis abstract, Cand. Sc. (Tech.). Moscow, 2019, pp. 35–39.
  42. Composition for coatings on metal: pat. 2260610 Rus. Federation; filed 13.05.04; publ. 20.09.05.
  43. Composition for protective coating of polymer composite materials: pat. 2480499 Rus. Federation; filed 04.07.11; publ. 10.01.13.
  44. Composition for anti-corrosion protective coating: pat. 2284342 Rus. Federation; filed 28.04.05; publ. 7.09.06.
  45. Composition for priming covering: pat. 100007 JP; filed 10.07.05; publ. 04.19.07.
  46. Covering for inner surface of large-size containers: pat. 101210147 CN; filed 12.21.07; publ. 02.07.08.
  47. Water deluting composition for coverings: pat. 0242387 WO; filed 27.11.01; publ. 30.05.02.
  48. Zakharova A.A. Investigation of the curing process of epoxy oligomers with aminoalkoxysilanes: abstracts thesis, Cand. Sc. (Chem.). Moscow, 1981, pp. 3–7.
  49. Sorokin M.F., Kochnova Z.A., Zakharova A.A., Golova N.A. Curing of epoxy oligomers with aminoalkoxysilanes. Lakokrasochnye materialy i ikh primenenie, 1986, no. 5, pp. 24–28.
  50. Van Ngan N., Kostromina N.V., Osipchik V.S. et al. Polysiloxane-containing epoxyurethane oligomers and coatings based on them. Plasticheskiye massy, 2019, no. 3-4. S. 3–6.
  51. Severny V.V., Karyugin M.A., Kisin A.V., Sokolskaya I.B. Analysis of the structural composition of oligoorganosiloxanes using Si NMR spectroscopy. Zavodskaya laboratory. 1990, no. 6, pp. 61–64.
  52. Kuznetsova V.A., Deev I.S., Semenova L.V. Influence of modification of epoxy film-forming compositions on their phase microstructure and adhesion to aluminum alloy. Aviation materials and technologies. 2016, no. 1 (40). S. 72–77. DOI: 10.18577 / 2071-9140-2016-0-1-72-78.
  53. Vedyakin S.V., Shode L.G., Smekhov F.M., Zeitlin G.M. Modification of epoxyamine systems with organosilicon epoxyurethanes. Paints and varnishes and their application. 1991, no. 2, pp. 1–3.
  54. Vedyakin S.V., Shode L.G., Zeitlin G.M. Epoxyurethane oligomers modified with organosilicon carbofunctional glycols. Paints and varnishes and their application. 1990, no. 6, pp. 12–16.
  55. Strekachinskaya L.S. Study of the formation process, structure and properties of exfoliated paint and varnish coatings: author. dis. ... Cand. chem. sciences. M., 1980. S. 6–10.
  56. Grozinskaya ZP, Strekachinskaya L.S., Verkholantsev V.V. Improvement of some characteristics of coatings due to delamination of the film former. Paints and varnishes and their application. 1980, no. 5. S. 30–32.
  57. Strekachinskaya L.S., Verkholantsev V.V., Grozinskaya Z.P. Regularities of delamination of solutions of mixtures of oligomers. Paints and varnishes and their application. 1980, no. 4, pp. 13–15.
  58. Kuznetsova V.A., Semenova L.V., Shapovalov G.G., Chesnokov D.V. Development trends in the field of anticorrosive polymer compounds for corrosion protection of fasteners of contact pairs of combined structures (review). Aviation materials and technologies. 2017, no. 1 (46). S. 25–31. DOI: 10.18577 / 2071-9140-2017-0-1-25-31.
  59. Snopkov A.Yu., Glazer E.A., Zeitlin G.M. et al. Coatings based on epoxy resins modified by rubbers. Paintwork materials and their application. 1989, no. 3, pp. 66–71.
  60. Polymer composition for corrosion protection of welded joints: US Pat. 2273653 Rus. Federation; filed 10/05/2004; publ. 10.04.06.
  61. Composition for anti-corrosion coating: US Pat. 2574512 Rus. Federation; filed 11/10/14; publ. 02/10/16.
  62. Beskhromatny primer composition: pat. 2008118950 US; filed 09/26/08; publ. 02.10.08.
  63. A waterborne epoxy corrosion resistant primer comprises a waterborne epoxy, a curing agent, and a non-chromate containing corrosion-inhibiting pigment: pat. US 6758887; filed 11/29/02; publ. 06.07.04.
  64. Zheludkevich M.L., Tedim J., Ferreira V.G.S. "Smart" coating for active corrosion protection based on multifunctional micro and nanocontainers. Electrochimica Acta. 2012, vol. 82. Nov, pp. 314–323.
  65. Composition for application: US Pat. 2284342 Rus. Federation; filed 04/28/05; publ. 09/27/06.