The influence of climatic ageing on the properties of PCM-based epoxy resin systems

Evdokimov A.A., Petrova A.P., Pavlovsky K.A., Gulyaev I.N.
UDC
620.1:678.8
DOI
10.18577/2307-6046-2021-0-3-128-136
Article PDF (Russian) (814.36 KB)
How to cite
Evdokimov A.A., Petrova A.P., Pavlovsky K.A., Gulyaev I.N. The influence of climatic ageing on the properties of PCM-based epoxy resin systems // Proceedings of VIAM. 2021. No. 3. DOI: 10.18577/2307-6046-2021-0-3-128-136. URL: https://test.viam.ru/en/journal/2021/3/12
Keywords
carbon fiber, fiberglass, epoxy vinyl ester binder, full-scale exposure, elastic-strength properties, physical properties.
Abstract

The article presents the results of studies of the properties of carbon fiber of the VKU-51 brand and fiberglass of the VPS-58 brand, made on the basis of the epoxy vinyl ester binder of the VSV-43 brand, after exposure in full-scale conditions of moderate and subtropical climate for 5 years with intermediate removals after 1 and 3 years. Physical and mechanical characteristics (strength and modulus of elasticity under tension, compression and bending) and glass transition temperature are determined. Studies have shown a high preservation of properties at 20 °C: 90–100% in VKU-51 and 73–100% in VPS-58, depending on the type of test.

Reference list
  1. The decisions taken are aimed at creating infrastructural conditions for the further development of the Northern Sea Route and coastal territories: Order of the Government of the Russian Federation No. 3120-р (December 21, 2019). Available at: http://www.government.ru/docs/38714 (accessed: December 07, 2020).
  2. On national goals and strategic objectives of the development of the Russian Federation for the period until 2024: Decree of the President of the Russian Federation No. 204 (May 07, 2018). Available at: http://www.kremlin.ru/acts/bank/43027 (accessed: December 07, 2020).
  3. National Program for the Development of the Far East: Order of the Government of the Russian Federation No. 2464-р (September 24, 2020). Available at: http://www.government.ru/docs/40487 (accessed: December 07, 2020).
  4. Kablov E.N. VIAM: new generation materials for PD-14. Krylya Rodiny, 2019, no. 7-8, pp. 54–58.
  5. Mishkin S.I., Raskutin A.E., Evdokimov A.A., Gulyaev I.N. Technologies and the main stages of construction of the arch bridge first in Russia from composite materials. Trudy VIAM, 2017, no. 6 (54), paper no. 05. Available at: http://www.viam-works.ru (accessed: December 10, 2020). DOI: 10.18577/2307-6046-2017-0-6-5-5.
  6. Evdokimov A.A., Raskutin A.E., Mishkin S.I., Mikhaldykin E.S. Arched bridges with the use of carbon-fiber arched elements. Konstruktsii iz kompozitsionnykh materialov, 2019, no. 2 (154), pp. 22-29.
  7. Gladkikh A.V., Kurs I.S., Kurs M.G. Analysis of the data of full-scale climatic tests combined with the application of operational factors of nonmetallic materials (review). Trudy VIAM, 2018, no. 10 (70), paper no. 09. Available at: http://www.viam-works.ru (accessed: December 06, 2020). DOI: 10.18577/2307-6046-2018-0-10-74-82.
  8. Kablov E.N., Kirillov V.N., Zhirnov A.D., Startsev O.V., Vapirov Yu.M. Centers for climatic testing of aviation PCM. Aviatsionnaya promyshlennost, 2009, no. 4, pp. 36–46.
  9. Kablov E.N., Startsev O.V. The basic and applied research in the field of corrosion and ageing of materials in natural environments (review). Aviacionnye materialy i tehnologii, 2015, no. 4 (37), pp. 38–52. DOI: 10.18577/2071-9140-2015-0-4-38-52.
  10. Kablov E.N., Startsev V.O. Systematical analysis of the climatics influence on mechanical properties of the polymer composite materials based on domestic and foreign sources (review). Aviacionnye materialy i tehnologii, 2018, no. 2 (51), pp. 47–58. DOI: 10.18577/2071-9140-2018-0-2-47-58.
  11. Aviation materials: reference book in 13 vols. Ed. E.N. Kablov. 7th ed., rev. and add. Moscow: VIAM, 2015, vol. 13: Climatic and microbiological resistance of non-metallic materials, 270 p.
  12. Kablov E.N., Startsev V.O., Inozemtsev A.A. The moisture absorption of structurally similar samples from polymer composite materials in open climatic conditions with application of thermal spikes. Aviacionnye materialy i tehnologii, 2017, no. 2 (47), pp. 56–68. DOI: 10.18577/2071-9140-2017-0-2-56-68.
  13. Laptev A.B., Barbotko S.L., Nikolaev E.V. The main research areas of the persistence properties of materials under the influence of climatic and operational factors. Aviacionnye materialy i tehnologii, 2017, no. S, pp. 547–561. DOI: 10.18577/2071-9140-2017-0-S-547-561.
  14. Roylance D., Roylance M. Weathering of fiber-reinforced epoxy composites. Polymer Engineering and Science, 1978, vol. 18, no. 4, pp. 249–254.
  15. Belec L., Nguyen T.H., Nguyen D.L., Chailan J.F. Comparative effects of humid tropical weathe-ring and artificial ageing on a model composite properties from nano- to macro-scale. Composites, part A, 2015, vol. 68, no. 1, pp. 235–241.
  16. De Bruijn J.C.M., Meijer H.D.F. The design and application of a microfoil tensile test apparatus for monitoring the degree of ultraviolet degradation of polymers. Review of Scientific Instruments, 1991, no. 62, pp. 1620–1623.
  17. De Bruijn J.C.M. Degradation profiles of thick high-density polyethylene samples after outdoor and artificial weathering. Polymer durability: degradation, stabilization, and lifetime prediction. Washington: American Chemical Society, 1996, pp. 599–620.
  18. Gu X., Dickens B., Stanley D. et al. Linking accelerating laboratory test with outdoor performance results for a model epoxy coating system. Iowa State University, 2008, pp. 1–47.
  19. Deev I.S., Kuryshev E.V., Lonsky S.L., Zhelezina G.F. Influence of long-term climatic aging on the surface microstructure of epoxy organoplastics and the nature of its destruction under bending conditions. Voprosy materialovedeniya, 2016, no. 3 (87), pp. 104-114.
  20. Startsev V.O. Climatic resistance of polymer composite materials and protective coatings in moderately warm climates: thesis, Dr. Sc. (Tech.). Moscow: VIAM, 2018, 308 p.
  21. Startsev V.O., Valevin E.O., Gulyaev A.I. The influence of polymer composite materials’ surface weathering on its mechanical properties. Trudy VIAM, 2020, no. 8 (90), paper no. 07. Available at: http://www.viam-works.ru (accessed: December 11, 2020). DOI: 10.18577/2307-6046-2020-0-8-64-76.