FDM-printed functional materials (review)

Kondrashov S.V., Pykhtin A.A., Larionov S.A.
Kondrashov S.V., Pykhtin A.A., Larionov S.A. FDM-printed functional materials (review) // Proceedings of VIAM. 2021. No. 3. DOI: 10.18577/2307-6046-2021-0-3-44-57. URL: https://test.viam.ru/en/journal/2021/3/4
Keywords
additive technologies, FDM printing, electrical conductivity, thermal conductivity, magnetic properties, carbon nanomaterial, PLA ABS.
Abstract

The paper provides an overview of studies carried out in the field of obtaining functional materials the FDM printing method. Data on the influence of the type of polymer matrix, filler composition, and FDM printing technological modes on the functional and physical-mechanical properties of composites are presented. It is shown that the technology of layer-by-layer hot-melt printing makes it possible to obtain polymeric materials with electrical conductivity from 10-2 to 1.4·105 S/m, to increase the thermal conductivity to 0.9 W/(m∙K), and to manufacture magnetoplastics. It is noted that to obtain a high level of functional properties, it is required to use polymer matrices with a degree of filling of 5–75 wt %, which inevitably leads to a significant change in the physical and mechanical properties and heat resistance of the material. Possible directions for further research in this area are indicated.

Reference list
  1. Kablov E.N. Present and future of additive technologies. Metally Evrazii, 2017, no. 1, pp. 2–6.
  2. Kablov E.N. The dominant feature of the national technology initiative. Problems of accelerating the development of additive technologies in Russia. Metally Evrazii, 2017, no. 3, pp. 2–6.
  3. Kablov E.N. Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030». Aviacionnye materialy i tehnologii, 2015, no. 1 (34), pp. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
  4. Kablov E.N. New generation materials – the basis of innovation, technological leadership and national security of Russia. Intellekt i tekhnologii, 2016, no. 2 (14), pp. 16–21.
  5. Pavlyuk B.Ph. The main directions in the field of development of polymeric functional materials. Aviacionnye materialy i tehnologii, 2017, no. S, pp. 388–392. DOI: 10.18577/2071-9140-2017-0-S-388-392.
  6. Terekhov I.V., Shlenskiy V.A., Kurshev E.V., Lonskiy S.L., Dyatlov V.A. Researches of factors affecting the formation of epoxy-containing microcapsules for the self-healing compositions. Aviacionnye materialy i tehnologii, 2018, no. 3 (52), pp. 27–34. DOI: 10.18577/2071-9140-2018-0-3-27-34.
  7. Perov N.S. Design of polymeric materials on the molecular principles. II. The molecu-lar mobility in the cross-linked complex systems. Aviacionnye materialy i tehnologii, 2017, no. 4 (49), pp. 30–36. DOI: 10.18577/2071-9140-2017-0-4-30-36.
  8. Kondrashov S.V., Shashkeev K.A., Petrova G.N., Mekalina I.V. Constructional polymer composites with functional properties. Aviacionnye materialy i tehnologii, 2017, no. S, pp. 405–419. DOI: 10.18577/2071-9140-2017-0-S-405-419.
  9. Khosravani M.R., Reinicke T. Applications of additive manufacturing in fabrication of sensors-A review. Sensors and Actuators A: Physical, 2020, vol. 305, no. 4, pp. 111916.
  10. Kondrashov S.V., Pykhtin A.A., Larionov S.A., Sorokin A.E. Influence of the technological FDM-modes of the press and structure of used materials on physic-mechanical cha-racteristics of FDM-models (review). Trudy VIAM, 2019, no. 10 (82), paper no. 04. Available at: http://www.viam-works.ru (accessed: February 22, 2020). DOI: 10.18577/2307-6046-2019-0-10-34-49.
  11. Popescu D., Zapciu A., Amza C. et al. FDM process parameters influence over the mechanical properties of polymer specimens: A review. Polymer Testing, 2018, vol. 69, pp. 157–166.
  12. Ngo T.D., Kashani A., Imbalzano G. et al. Additive manufacturing (3D printing): A review of materials, methods, applications and challenges. Composites Part B: Engineering, 2018, vol. 143, pp. 172–196.
  13. Lipatov Yu.S. Interfacial phenomena in polymers. Kiev: Naukova Dumka, 1980, 260 p.
  14. Kondrashov S.V., Shashkeev K.A., Popkov O.V., Solovyanchik L.V. Prospective producing methods for functional structural materials based on CNT-filled nanocomposites (review). Trudy VIAM, 2016, no. 3 (39), paper no. 07. Available at: http://www.viam-works.ru (accessed: December 10, 2020). DOI: 10.18577/2307-6046-2016-0-3-7-7.
  15. Kondrashov S.V., Shashkeev K.A., Popkov O.V., Solovyanchik L.V. Mechanical properties of CNT nanocomposites (review). Trudy VIAM, 2016, no. 5 (41), paper no. 08. Available at: http://www.viam-works.ru (accessed: December 10, 2020). DOI: 10.18577/2307-6046-2016-0-5-8-8.
  16. Sezer H.K., Eren O. FDM 3D printing of MWCNT re-inforced ABS nano-composite parts with enhanced mechanical and electrical properties. Journal of Manufacturing Processes, 2019, vol. 37, pp. 339–347.
  17. Alig I., Lellinger D., Skipa T. Influence of thermo-rheological history on electrical and rheological properties of polymer–carbon nanotube composites. Polymer–Carbon Nanotube Composites, Woodhead Publishing, 2011, pp. 295–328.
  18. Shante V.K.S., Kirkpatrick S. An introduction to percolation theory. Advances in Physics, 1971, vol. 20, no. 85, pp. 325–357.
  19. Sorokin A.E., Pykhtin A.A., Larionov S.A., Belyaev A.A., Lonsky S.L., Kondrashov S.V., Lobanov M.V. et al. Structure and properties of CNT modified filaments based on ABS plastic. Vse materialy. Entsiklopedicheskiy spravochnik, 2020, no. 4, pp. 1–16.
  20. Jyoti J., Basu S., Singh B.P. et al. Superior mechanical and electrical properties of multiwall carbon nanotube reinforced acrylonitrile butadiene styrene high performance composites. Composites Part B: Engineering, 2015, vol. 83, pp. 58–65.
  21. Vacha J., Borůvka M. Mechanical properties of acrylonitrile butadiene styrene thermoplastic polymer matrix with carbon nanotubes. NANOCON, 2015. Available at: http://www.nanocon.eu/files/proceedings/23/index_en.htm (accessed: november 27, 2020).
  22. Villmow T., Pegel S., Pötschke P. et al. Influence of injection molding parameters on the electrical resistivity of polycarbonate filled with multi-walled carbon nanotubes. Composites Science and Technology, 2008, vol. 68, no. 3–4, pp. 777–789.
  23. Tiusanen J., Vlasveld D., Vuorinen J. Review on the effects of injection moulding parameters on the electrical resistivity of carbon nanotube filled polymer parts. Composites Science and Technology, 2012, vol. 72, no. 14, pp. 1741–1752.
  24. Yang L., Li S., Zhou X., Liu J. et al. Effects of carbon nanotube on the thermal, mechanical, and electrical properties of PLA/CNT printed parts in the FDM process. Synthetic Metals, 2019. Vol. 253, pp. 122–130.
  25. Spinelli G., Lamberti P., Tucci V. et al. Rheological and electrical behaviour of nanocarbon/poly (lactic) acid for 3D printing applications. Composites Part B: Engineering, 2019, vol. 167, pp. 467–476.
  26. Yu W.W., Zhang J., Wu J.R. et al. Incorporation of graphitic nano-filler and poly (lactic acid) in fused deposition modeling. Journal of Applied Polymer Science, 2017, vol. 134, no. 15, p. 44703.
  27. Postiglione G., Natale G., Griffini G. et al. Conductive 3D microstructures by direct 3D printing of polymer/carbon nanotube nanocomposites via liquid deposition modeling. Composites Part A: Applied Science and Manufacturing, 2015, vol. 76, pp. 110–114.
  28. Chizari K., Arjmand M., Liu Z. et al. Three-dimensional printing of highly conductive polymer nanocomposites for EMI shielding applications. Materials Today Communications, 2017, vol. 11, pp. 112–118.
  29. Kotsilkova R., Petrova-Doycheva I., Menseidov D. et al. Exploring thermal annealing and graphene-carbon nanotube additives to enhance crystallinity, thermal, electrical and tensile properties of aged poly(lactic)acid-based filament for 3D printing. Composites Science and Technology, 2019, vol. 181, p. 107712.
  30. Gnanasekaran K., Heijmans T., Van Bennekom S. et al. 3D printing of CNT-and graphene-based conductive polymer nanocomposites by fused deposition modeling. Applied Materials Today, 2017, vol. 9, pp. 21–28.
  31. Ye W., Wu W., Hu X. et al. 3D printing of carbon nanotubes reinforced thermoplastic polyimide composites with controllable mechanical and electrical performance. Composites Science and Technology, 2019, vol. 182, pp. 107671.
  32. Wei X., Li D., Jiang W., Gu Z. et al. 3D printable graphene composite. Scientific reports, 2015, vol. 5, pp. 11181.
  33. Singh R., Sandhu G.S., Penna R. et al. Investigations for thermal and electrical conductivity of ABS-graphene blended prototypes. Materials, 2017, vol. 10, no. 8, pp. 881–890.
  34. Leigh S.J., Bradley R.J., Purssell C.P. et al. A simple, low-cost conductive composite material for 3D printing of electronic sensors. PloS one, 2012, vol. 7, no. 11. DOI: 10.1371/journal.pone.0049365.
  35. Kwok S.W., Goh K.H.H., Tan Z.D. et al. Electrically conductive filament for 3D-printed circuits and sensors. Applied Materials Today, 2017, vol. 9, pp. 167–175.
  36. Cruz M.A., Ye S., Kim M.J. et al. Multigram synthesis of Cu–Ag Core–shell nanowires enables the production of a highly conductive polymer filament for 3D printing electronics. Particle & Particle Systems Characterization, 2018, vol. 35, no. 5, pp. 1700385.
  37. Tan J.C., Low H.Y. Embedded electrical tracks in 3D printed objects by fused filament fabrication of highly conductive composites. Additive Manufacturing, 2018, vol. 23, pp. 294–302.
  38. Lei Z., Chen Z., Peng H. et al. Fabrication of highly electrical conductive composite filaments for 3D-printing circuits. Journal of Materials Science, 2018, vol. 53, no. 20, pp. 14495–14505.
  39. Pang H., Xu L., Yan D.X. et al. Conductive polymer composites with segregated structures. Progress in Polymer Science, 2014, vol. 39, no. 11, pp. 1908–1933.
  40. Iron-filled Metal Composite PLA. Available at: https://www.proto-pasta.com/products/magnetic-iron-pla (accessed: November 27, 2020).
  41. Bollig L.M., Hilpisch P.J., Mowry G.S. et al. 3D printed magnetic polymer composite transformers. Journal of Magnetism and Magnetic Materials, 2017, vol. 442, pp. 97–101.
  42. Chernavsky P.A., Pankina G.V., Lunin V.V. Methodological developments for practical work on the special course «Methods of magnetometry in heterogeneous catalysis». Moscow: Moscow State University. M.V. Lomonosov, 2017, pp. 19–21.
  43. Khatri B., Lappe K., Noetzel D. et al. A 3D-printable polymer-metal soft-magnetic functional composite – Development and characterization. Materials, 2018, vol. 11, no. 2, pp. 189–201.
  44. Palmero E.M., Rial J., de Vicente J. et al. Development of permanent magnet MnAlC/polymer composites and flexible filament for bonding and 3D-printing technologies. Science and Techno-logy of advanced Materials, 2018, vol. 19, no. 1, pp. 465–473.
  45. Huber C., Abert C., Bruckner F. et al. 3D Printing of Polymer Bonded Rare-Earth Magnets With a Variable Magnetic Compound Density for a Predefined Stray Field. Available at: https://www.nature.com/articles/s41598-017-09864-0 (accessed: November 27, 2020).
  46. Jabr R.A. Application of geometric programming to transformer design. IEEE Transactions on Magnetics, 2005, vol. 41, no. 11, pp. 4261–4269.
  47. Leigh S.J., Purssell C.P., Billson D.R. et al. Using a magnetite/thermoplastic composite in 3D printing of direct replacements for commercially available flow sensors. Smart materials and structures, 2014, vol. 23, no. 9, pp. 095039.
  48. Gubin S.P., Koksharov Yu.A., Khomutov G.B., Yurkov G.Yu. Magnetic nanoparticles: methods of preparation, structure and properties. Uspekhi khimii, 2005, vol. 74, no. 6, pp. 539–574.
  49. Arie M.A., Shooshtari A.H., Tiwari R. et al. Experimental characterization of heat transfer in an additively manufactured polymer heat exchanger. Applied Thermal Engineering, 2017, vol. 113, pp. 575–584.
  50. Hymas D.M., Arie M.A., Singer F. et al. Enhanced air-side heat transfer in an additively manufactured polymer composite heat exchanger. 16th IEEE Intersociety Conference on Thermal and Thermomechanical Phenomena in Electronic Systems (ITherm). 2017, pp. 634–638.
  51. Nikzad M., Masood S.H., Sbarski I. Thermo-mechanical properties of a highly filled polymeric composites for fused deposition modeling. Materials & Design, 2011, vol. 32, no. 6, pp. 3448–3456.
  52. Hwang S., Reyes E.I., Moon K.S. et al. Thermo-mechanical characterization of metal/polymer composite filaments and printing parameter study for fused deposition modeling in the 3D printing process. Journal of Electronic Materials, 2015, vol. 44, no. 3, pp. 771–777.
  53. Quill T.J., Smith M.K., Zhou T. et al. Thermal and mechanical properties of 3D printed boron nitride–ABS composites. Applied Composite Materials, 2018, vol. 25, no. 5, pp. 1205–1217.
  54. Waheed S., Cabot J.M., Smejkal P. et al. Three-Dimensional Printing of Abrasive, Hard, and Thermally Conductive Synthetic Microdiamond–Polymer Composite Using Low-Cost Fused De- position Modeling Printer. ACS applied materials & interfaces, 2019, vol. 11, no. 4, pp. 4353–4363.
  55. Jia Y., He H., Geng Y. et al. High through-plane thermal conductivity of polymer based product with vertical alignment of graphite flakes achieved via 3D printing. Composites Science and Technology, 2017, vol. 145, pp. 55–61.