Carbon and glass reinforced polymer based on solvent-free binders resistance to the impact of a moderate cold and moderate warm climate

Startsev V.O., Slavin A.V.
UDC
539.24:620.1
DOI
10.18577/2307-6046-2021-0-5-114-126
Article PDF (Russian) (1.04 MB)
How to cite
Startsev V.O., Slavin A.V. Carbon and glass reinforced polymer based on solvent-free binders resistance to the impact of a moderate cold and moderate warm climate // Proceedings of VIAM. 2021. No. 5. DOI: 10.18577/2307-6046-2021-0-5-114-126. URL: https://test.viam.ru/en/journal/2021/5/12
Keywords
carbon fiber reinforced polymer, glass fiber reinforced polymer, solvent-free binders, weathering, destruction, post cure, plasticization, strength, profilometry, moisture transfer.
Abstract

In this work has been investigated the climatic resistance of carbon and fiberglass polymers for aviation purposes based on solvent-free binders VST-1208, VSE-1212, VSR-3M after 3 years of exposure of these materials in the moderate cold climate of Moscow and the moderate warm climate of Gelendzhik. The effect of destruction, post curing, plasticization of binders on the compressive and flexural strengths of carbon plastics VKU-27L, VKU-39, VKU-46 and fiberglass plastics VPS-47/7781, VPS-48/778 was determined using the methods of profilometry, moisture transfer and dynamic mechanical analysis. It is shown that while determining the state of PCM after climatic exposure, it is necessary to take into account the effects of the reversible plasticizing action of moisture. A comparison is made of the climatic resistance of the investigated materials.

Reference list
  1. Kablov E.N. Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030». Aviacionnye materialy i tehnologii, 2015, no. 1 (34), pp. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
  2. Kablov E.N., Chursova L.V., Babin A.N., Mukhametov R.R., Panina N.N. Development of FSUE «VIAM» in the field of melt binders for polymer composite materials. Polimernyye materialy i tekhnologii, 2016, vol. 2, no. 2, pp. 37–42.
  3. Raskutin A.E. Structural carbon plastics based on new melt-type binders and PORCHER fabrics. Novosti materialovedeniya. Nauka i tekhnika, 2013, no. 5. Art. 01. URL: http://www.materialsnews.ru (accessed: March 28, 2021).
  4. Raskutin A.E. Russian polymer composite materials of new generation, their exploitation and implementation in advanced developed constructions. Aviacionnye materialy i tehnologii, 2017, no. S, pp. 349–367. DOI: 10.18577/2071-9140-2017-0-S-349-367.
  5. Popov Yu.O., Kolokoltseva T.V., Khrulkov A.V. The new generation of materials and technologies for helicopter blade spars. Aviacionnye materialy i tehnologii, 2014, no. S2, pp. 5–9. DOI: 10.18577/2071-9140-2014-0-S2-5-9.
  6. Gunyayeva A.G., Sidorina A.I., Kurnosov A.O., Klimenko O.N. Polymeric composite materials of new generation on the basis of binder VSE-1212 and the filling agents alternative to ones of Porcher Ind. and Toho Tenax. Aviacionnye materialy i tehnologii, 2018, no. 3 (52), pp. 18–26. DOI: 10.18577/2071-9140-2018-0-3-18-26.
  7. Startsev O.V., Prokopenko K.O., Litvinov A.A., Krotov A.S., Anikhovskaya L.I., Dementyeva L.A. Investigation of thermal and humidity aging of aviation fiberglass. Klei. Germetiki. Tekhnologii, 2009, no. 8, pp. 18–21.
  8. Startsev O.V., Vapirov Yu.M., Deev I.S., Yartsev V.A., Krivonos V.V., Mitrofanova E.A., Chubarova M.A. Influence of prolonged atmospheric aging on the properties and structure of carbon fiber. Mekhanika kompozitnykh materialov, 1986, no. 4, pp. 637–642.
  9. Startsev O.V., Meletov V.P., Perov B.V., Mashinskaya G.P. Investigations of the aging mechanism of organotextile in a subtropical climate. Mekhanika kompozitnykh materialov, 1986, no. 3, pp. 462–467.
  10. Nikolaev E.V., Barbotko S.L., Andreeva N.P., Pavlov M.R., Grashchenkov D.V. Complex research of influence of climatic and operational factors on new generation epoxy binding and polymeric composite materials on its basis. Part 4. Natural climatic tests of polymeric composite materials on the basis of epoxy matrix. Trudy VIAM, 2016, no. 6, paper no. 11. Available at: http://www.viam-works.ru (accessed: March 28, 2021). DOI: 10.18577/2307-6046-2016-0-6-11-11.
  11. Mishurov K.S., Pavlovskiy K.A., Imametdinov E.Sh. fiber reinforced plastic) VKU-27L. Trudy VIAM, 2018, no. 3 (63), paper no. 07. Available at: http://www.viam-works.ru (accessed: March 28, 2021). DOI: 10.18577/2307-6046-2018-0-3-60-67.
  12. Mishurov K.S., Mishkin S.I. Environmental effect on properties of CFRP (Carbon Fiber Reinforced Plastic) VKU-39. Trudy VIAM, 2016, no. 12 (48), paper no. 08. Available at: http://www.viam-works.ru (accessed: March 28, 2021). DOI: 10.18577/2307-6046-2016-0-12-8-8.
  13. Slavin A.V., Startsev O.V. Properties of aircraft glass- and carbonfibers reinforced plastics at the early stage of natural weathering. Trudy VIAM, 2018, no. 9 (69), paper no. 8. Available at: http://www.viam-works.ru (accessed: March 28, 2021). DOI: 10.18577/2307-6046-2018-0-9-71-82.
  14. Blaznov A.N., Zimin D.E., Anisimov E.E., Sinitsyn A.V., Zhurkovsky N.E. Investigation of the durability of composites under load and high humidity. Nauchno-tekhnicheskiy vestnik Povolzhya, 2018, no. 11, pp. 98–101.
  15. Andreeva N.P., Pavlov M.R., Nikolaev E.V., Kurnosov A.O. Research of climatic factors influence of cold, temperate (moderate) and tropical climates on properties of construction fibreglass. Trudy VIAM, 2019, no. 3 (75), paper no. 12. Available at: http://www.viam-works.ru (accessed: March 28, 2021). DOI: 10.18577/2307-6046-2019-0-3-105-114.
  16. Kablov E.N., Startsev V.O. Systematical analysis of the climatics influence on mechanical properties of the polymer composite materials based on domestic and foreign sources (review). Aviacionnye materialy i tehnologii, 2018, no. 2 (51), pp. 47–58. DOI: 10.18577/2071-9140-2018-0-2-47-58.
  17. Kablov E.N., Startsev O.V., Krotov A.S., Kirillov V.N. Climatic aging of composite materials for aviation purposes. I. Mechanisms of aging. Deformatsiya i razrusheniye materialov, 2010, no. 11, pp. 40–46.
  18. Kablov E.N., Startsev O.V., Krotov A.S., Kirillov V.N. Climatic aging of composite materials for aviation purposes. II. Relaxation of the initial structural nonequilibrium and the gradient of properties over thickness. Deformatsiya i razrusheniye materialov, 2010, no. 12, pp. 40–46.
  19. Panin S.V., Startsev V.O., Course M.G., Varchenko E.A. Development of climate methods mechanical testing of materials for mechanical engineering and construction at the GCCT VIAM named G.V. Akimova. Vse materialy. Entsiklopedicheskiy spravochnik. Kommentarii k standartam, TU, sertifikatam, 2016, no. 10, pp. 50–61.
  20. Startsev V.O. Climatic resistance of polymer composite materials and protective coatings in a moderately warm climate: thesis, Dr. Sc. (Tech.). Moscow: VIAM, 2018, 308 p.
  21. Nizina T.A., Selyaev V.P., Nizin D.R., Chernov A.N. Influence of the color of polymer composite materials on the mode of operation of protective and decorative coatings under the influence of natural climatic factors. Regional architecture and construction, 2016, no. 1 (26). S. 59–67.
  22. Vapirov Y.M., Krivonos V.V., Startsev O.V. Interpretation of the anomalous change in the properties of carbon-fiber-reinforced plastic KMU-1U during aging in different climatic regions. Mechanics of Composite Materials, 1994, vol. 30, pp. 190–194.
  23. Filistovich D.V., Startsev O.V., Kuznetsov A.A., Krotov A.S., Anikhovskaya L.I., Dementeva L.A. Effect of moisture on the anisotropy of the dynamic shear modulus of glass-reinforced plastics. Doklady Physics, 2003, vol. 48, no. 6, pp. 306–308.
  24. Startseva L.T., Panin S.V., Startsev O.V., Krotov A.S. Moisture diffusion in glass-fiber-reinforced plastics after their climatic aging. Doklady Physical Chemistry, 2014, vol. 456, pp. 77–81.
  25. Kablov E.N., Startsev O.V., Panin S.V. Moisture transfer in carbon-fiber-reinforced plastic with degraded surface. Doklady Physical Chemistry, 2015, vol. 461, pp. 80–83.
  26. Startseva L.T., Panin S.V., Startsev O.V., Krotov A.S. Diffusion of moisture in fiberglass after their climatic aging. Reports of the Academy of Sciences, 2014, vol. 345, no. 3, pp. 305–309.
  27. Kablov E.N., Startsev V.O., Inozemtsev A.A. The moisture absorption of structurally similar samples from polymer composite materials in open climatic conditions with application of thermal spikes. Aviacionnye materialy i tehnologii, 2017, no. 2 (47), pp. 56–68. DOI: 10.18577/2071-9140-2017-0-2-56-68.
  28. Startsev O.V., Medvedev I.M., Krotov A.S., Panin S.V. Dependence of the surface temperature of the samples on the characteristics of the climate during exposure in natural conditions. Korroziya: materialy, zashchita, 2013, no. 7, pp. 43–47.
  29. Startsev O.V., Sortyakov E.D., Isupov V.V., Nasonov A.D., Skurydin Yu.G., Kovalenko A.A., Nikishin E.F. Acoustic spectroscopy of polymer composite materials exposed in open space. Experimental methods in the physics of structurally inhomogeneous media: Proceedings of All-Rus. Scientific and Technical Conf. Barnaul, 1997. S. 32–39.
  30. Startsev O.V., Lebedev M.P. Glass transition temperature and characteristic temperatures of the α-transition of amorphous polymers as exemplified by polymethyl methacrylate. Vysokomolekulyarnyye soyedineniya A, 2018, vol. 60, no. 4S, pp. 3–16.
  31. Startsev O.V., Vapirov Yu.M., Lebedev M.P., Kychkin A.K. Comparison of glass-transition temperatures for epoxy polymers obtained by methods of thermal analysis. Mechanics of Composite Materials, 2020, vol. 56, pp. 227–240.
  32. Sousa J.M., Correia J.R., Cabral-Fonseca S. Durability of glass fibre reinforced polymer pultruded profiles: comparison between QUV accelerated exposure and natural weathering in a mediterranean climate. Experimental Technique, 2016, vol. 40, pp. 207–219.
  33. Hahn H.T. Residual Stresses in Polymer Matrix Composite Laminates. Journal of Composite Materials, 1976, vol. 10, pp. 266–278.
  34. Dutta P.K., Hui D. Low-temperature and freeze-thaw durability of thick composites. Composites, part B. 1996, vol. 27, pp. 371–379.
  35. Dutta P.K. Durability issues of composites in cold regions. Polymer Composites II. Applications of composites in infrastructure renewal and economic development. CRС Press, 2001, pp. 125–136.
  36. Jafari A., Ashrafi H., Bazli M., Ozbakkaloglu T. Effect of thermal cycles on mechanical response of pultruded glass fiber reinforced polymer profiles of different geometries. Composite Structures, 2019, vol. 223, art. 110959.