Ceramics based on organosilicon polymers-precursors: microstructure and properties (review)

Part 2
Shestakov A.M.
UDC
678.84
DOI
10.18577/2307-6046-2021-0-9-22-32
Article PDF (Russian) (849.06 KB)
How to cite
Shestakov A.M. Ceramics based on organosilicon polymers-precursors: microstructure and properties (review). Part 2 // Proceedings of VIAM. 2021. No. 9. DOI: 10.18577/2307-6046-2021-0-9-22-32. URL: https://test.viam.ru/en/journal/2021/9/3
Keywords
silicon carbonitride, ceramics, organosilicon polymers, microstructure, silicon oxycarbide, pyrolysis, electron microscopy, NMR spectroscopy.
Abstract

Shows the scientific approaches of various authors to the study of the microstructure of ceramics, the purpose of which is to elucidate its structural organization at the micro- and nanoscale, as well as the influence of the microstructure on the complex of material properties. Various instrumental methods for studying ceramics (NMR spectroscopy, electron microscopy, х-ray structural analysis, etc.) are considered, the permissible capabilities of research methods and analysis of the results obtained with their correct interpretation are shown. The special role of theoretical modeling in understanding the structure of the considered ceramic materials is noted.

Reference list
  1. Kablov E.N. Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030». Aviacionnye materialy i tehnologii, 2015, no. 1 (34), pp. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
  2. Kablov E.N. Composites: Today and Tomorrow. Metally Evrazii, 2015, no. 1, pp. 36–39.
  3. Grashchenkov D.V. Strategy of development of non-metallic materials, metal composite materials and heat-shielding. Aviacionnye materialy i tehnologii, 2017, no. S, pp. 264–271. DOI: 10.18577/2071-9140-2017-0-S-264-271.
  4. Grashchenkov D.V., Evdokimov S.A., Zhestkov B.E., Solntsev S.St., Shtapov V.V. Research of thermochemical influence of the air plasma flow on high-temperature ceramic composite material. Aviacionnye materialy i tehnologii, 2017, no. 2 (47), pp. 31–40. DOI: 10.18577/2071-9140-2017-0-2-31-40.
  5. Kablov E.N., Nikiforov A.A., Demin S.A., Chesnokov D.V., Vinogradov S.S. Promising coatings for corrosion protection of carbon steels. Stal, 2016, no. 6, pp. 70–81.
  6. Grashchenkov D.V., Efimochkin I.Yu., Bolshakova A.N. High-temperature metal-matrix composite materials reinforced with particles and fibers of refractory compounds. Aviacionnye materialy i tehnologii, 2017, no. S, pp. 318–328. DOI: 10.18577/2071-9140-2017-0-S-318-328.
  7. Kablov E.N., Grashchenkov D.V., Isaeva N.V., Solntsev S.S., Sevastianov V.G. High-temperature structural composite materials based on glass and ceramics for advanced aircraft products. Steklo i keramika, 2012, no. 4, pp. 7–11.
  8. Sorokin O.Yu., Grashhenkov D.V., Solntsev S.St., Evdokimov S.A. Ceramic composite materials with high oxidation resistance for the novel aircrafts (review). Trudy VIAM, 2014, no. 6, paper no. 8. Available at: http://www.viam-works.ru (accessed: May 24, 2021). DOI: 10.18577/2307-6046-2014-0-6-8-8.
  9. Kablov E.N., Grashchenkov D.V., Isaeva N.V., Solntsev S.St. Promising high-temperature ceramic composite materials. Rossiyskiy khimicheskiy zhurnal, 2010, vol. LIV, no. 1, pp. 20–24.
  10. Prokopyev A.L., Postnov V.I. Production of launchers of unguided aircraft missiles from polymer composite materials. Reports of the Youth Innovation Forum of the Volga Federal District. Competition of scientific and technical creativity of youth (STTM). Ulyanovsk, 2011. Available at: https://docplayer.ru/45967293-Proizvodstvo-puskovyh-ustanovok-neupravlyaemyh-aviacionnyh-raket-iz-polimernyh-kompozicionnyh-materialov.html (accessed: April 12, 2021).
  11. Sorokin O.Yu. On the issue of the mechanism of interaction between carbon materials and Si melt (review). Aviacionnye materialy i tehnologii, 2015, no. 1 (34), pp. 65–70. DOI: 10.18577/2071-9140-2015-0-1-65-70.
  12. Colombo P., Mera G., Riedel R., Soraru G.D. Polymer-Derived Ceramics: 40 Years of Research and Innovation in Advanced Ceramics. Journal of the American Ceramic Society, 2010, vol. 93, no. 7, pp. 1805–1837.
  13. Shestakov A.M. Ceramics based on organosilicon polymers-precursors: methods of preparation and properties (review). Trudy VIAM, 2020, no. 11 (93), paper no. 9. Available at: http://www.viam-works.ru (accessed: April 12, 2021). DOI: 10.18577/2307-6046-2020-0-11-76-92.
  14. Shestakov A.M. Ceramics based on organosilicon polymers-precursors: microstructure and properties (review). Part 1. Trudy VIAM, 2021, no.8 (102), paper no. 03. Available at: http://www.viam-works.ru (accessed: April 12, 2021). DOI: 10.18577/2307-6046-2021-0-8-21-33.
  15. Riedel R., Passing G., Schönfelder H., Brook R.J. Synthesis of dense silicon-based ceramics at low temperatures. Nature, 1992, vol. 355, pp. 714–717.
  16. Kleebe H.-J., Störmer H., Trassl S., Ziegler G. Thermal stability of SiCN ceramics studied by spectroscopy and electron microscopy. Applied Organometallic Chemistry, 2001, vol. 15, no. 10, pp. 858–866.
  17. Mera G., Tamayo A., Nguyen H., Sen S., Riedel R. Nanodomain Structure of Carbon-Rich Silicon Carbonitride Polymer-Derived Ceramics. Journal of the American Ceramic Society, 2010, vol. 93, no. 4, pp. 1169–1175.
  18. Jiang T., Wang Ya., Wang Yi. et al. Quantitative Raman Analysis of Free Carbon in Polymer-Derived Ceramics. Journal of the American Ceramic Society, 2009, vol. 92, no. 10, pp. 2455–2458.
  19. Cançado L.G., Takai K., Enoki T. et al. General equation for the determination of the crystallite size La of nanographite by Raman spectroscopy. Applied Physics Letters, 2006, vol. 88, no. 16, art. 163106.
  20. Ferrari A.C., Robertson J. Interpretation of Raman spectra of disordered and amorphous carbon. Physical Review B, 2000, vol. 61, no. 20, pp. 14095–14107.
  21. Ferrari A.C., Meyer J.C., Scardaci V. et al. Raman Spectrum of Graphene and Graphene Layers. Physical Review Letters, 2006, vol. 97, no. 18, pp. 187401.
  22. Pimenta M.A., Dresselhaus G., Dresselhaus M.S. et al. Studying disorder in graphite-based systems by Raman spectroscopy. Physical Chemistry Chemical Physics, 2007, vol. 9, no. 11, pp. 1276–1290.
  23. Riedel R., Mera G., Hauser R., Klonczynski A. Silicon-Based Polymer-Derived Ceramics: Synthesis Properties and Applications – A Review. Journal of the Ceramic Society of Japan, 2006, vol. 114, no. 1330, pp. 425–444.
  24. Iwamoto Y., Völger W., Kroke E. et al. Crystallization Behavior of Amorphous Silicon Carbonitride Ceramics Derived from Organometallic Precursors. Journal of the American Ceramic Society, 2001, vol. 84, no. 10, pp. 2170–2178.
  25. Mera G., Riedel R., Poli F., Müller K. Carbon-rich SiCN ceramics derived from phenyl-containing poly(silylcarbodiimides). Journal of the European Ceramic Society, 2009, vol. 29, no. 13. P. 2873–2883.
  26. Morcos R.M., Mera G., Navrotsky A. et al. Enthalpy of Formation of Carbon-Rich Polymer-Derived Amorphous SiCN Ceramics. Journal of the American Ceramic Society, 2008, vol. 91, no. 10, pp. 3349–3354.
  27. Gervais C., Babonneau F., Ruwisch L. et al. Solid state NMR investigations of the polymer route to SiBCN ceramics. Canadian Journal of Chemistry, 2003, vol. 81, no. 11, pp. 1359–1369.
  28. Dasgupta K., Sathiyamoorthy D. Disordered carbon – its preparation, structure, and characterization. Materials Science and Technology, 2003, vol. 19, no. 8, pp. 995–1002.
  29. Shvets N.I., Minakov V.T., Papkov V.S., Buzin M.I., Bad'ina L.Yu., Shimkin A.A. Investigation of thermochemical transformations of polycarbosilane precursors into a ceramic matrix. Zhurnal prikladnoy khimii, 2014, vol. 87, is. 6, pp. 793–799.
  30. Riedel R., Kleebe H.-J., Schönfelder H., Aldinger F. A covalent micro/nano-composite resistant to high-temperature oxidation. Nature, 1995, vol. 374, pp. 526–528.
  31. Rouxel T., Soraru G.D., Vicens J. Creep Viscosity and Stress Relaxation of Gel-Derived Oxycarbide Glasses. Journal of the American Ceramic Society, 2001, vol. 84, no. 5, pp. 1052–1058.
  32. Raj R., An L., Shah S. et al. Oxidation Kinetics of an Amorphous Silicon Carbonitride. Journal of the American Ceramic Society, 2001, vol. 84, no. 8, pp. 1803–1810.
  33. Störmer H., Kleebe H.-J., Ziegler G. Metastable SiCN glass matrices studied by energy-filtered electron diffraction analysis. Journal of Non-Crystalline Solids, 2007, vol. 353, no. 30–31, pp. 2867–2877.
  34. Heidenreich R.D., Hess W.M., Ban L.L. A test object and criteria for high resolution electron microscopy. Journal of Applied Crystallography, 1968, vol. 1, part 1, pp. 1–19.
  35. Delverdier O., Monthioux M., Oberlin A. et al. Thermal behaviour of polymer-derived ceramics II: Si–C–N system from a new PVSZ precursor. Journal of High Temperature Chemical Processes, 1992, vol. 1, pp. 139–149.
  36. Gregori G., Kleebe H.-J., Blum Y.D., Babonneau F. Evolution of C-rich SiOC ceramics: Part II. Characterization by high lateral resolution techniques: electron energy-loss spectroscopy, high-resolution TEM and energy-filtered TEM. International Journal of Materials Research, 2006, vol. 97, no. 6, pp. 710–720.
  37. Kroke E., Li Y.-L., Konetschny C. et al. Silazane derived ceramics and related materials. Materials Science and Engineering: R: Reports, 2000, vol. 26, no. 4–6, pp. 97–199.
  38. Saha A., Raj R., Williamson D.L., Kleebe H.-J. Characterization of Nanodomains in Polymer-Derived SiCN Ceramics Employing Multiple Techniques. Journal of the American Ceramic Society, 2005, vol. 88, no. 1, pp. 232–234.
  39. Saha A., Raj R., Williamson D.L. A Model for the Nanodomains in Polymer-Derived SiCO. Journal of the American Ceramic Society, 2006, vol. 89, no. 7, pp. 2188–2195.
  40. Peña-Alonso R., Soraru G.D., Raj R. Preparation of Ultrathin-Walled Carbon-Based Nanoporous Structures by Etching Pseudo-Amorphous Silicon Oxycarbide Ceramics. Journal of the American Ceramic Society, 2006, vol. 89, no. 8, pp. 2473–2480.
  41. Dürr J., Lamparter P., Bill J. et al. An X-ray and neutron scattering investigations on precursor-derived Si24C43N33 ceramics. Journal of Non-Crystalline Solids, 1998, vol. 232–234, pp. 155–161.
  42. Matsunaga K., Iwamoto Y., Fisher C.A.J., Matsubara H. Molecular Dynamics Study of Atomic Structures in Amorphous Si–C–N Ceramics. Journal of the Ceramic Society of Japan, 1999, vol. 107, no. 1251, pp. 1025–1031.
  43. Amkreutz M., Frauenheim T. Understanding precursor-derived amorphous Si–C–N ceramics on the atomic scale. Physical Review B, 2002, vol. 65, no. 13, pp. 134113.
  44. Resta N., Kohler Ch., Trebin H.-R. Molecular Dynamics Simulations of Amorphous Si–C–N Ceramics: Composition Dependence of the Atomic Structure. Journal of the American Ceramic Society, 2003, vol. 86, no. 8, pp. 1409–1414.
  45. Golczewski J.A., Aldinger F. Thermodynamic modeling of amorphous Si–C–N ceramics derived from polymer precursors. Journal of Non-Crystalline Solids, 2004, vol. 347, no. 1–3, pp. 204–210.
  46. Kroll P. Modelling polymer-derived ceramics. Journal of the European Ceramic Society, 2005, vol. 25, no. 2–3, pp. 163–174.
  47. Kroll P. Modeling Amorphous Ceramic Structures. Ceramics Science and Technology. Wiley-VCH Verlag GmbH & Co., 2013, vol. 1: Structures, pp. 39–69.
  48. Kroll P. Modeling the «free carbon» phase in amorphous silicon oxycarbide. Journal of Non-Crystalline Solids, 2005, vol. 351, no. 12–13, pp. 1121–1126.