Technological features of obtaining high temperature polyimide carbons. Foreign experience (review)

Valueva M.I., Zelenina I.V., Nacharkina A.V., Akhmadieva K.R.
Valueva M.I., Zelenina I.V., Nacharkina A.V., Akhmadieva K.R. Technological features of obtaining high temperature polyimide carbons. Foreign experience (review) // Proceedings of VIAM. 2022. No. 6. DOI: 10.18577/2307-6046-2022-0-6-80-95. URL: https://test.viam.ru/en/journal/2022/6/8
Keywords
polymer composite materials (PCMs), high temperature PCMs, high temperature carbon fiber reinforced plastics, polyimide binders, production, processing
Abstract

The article presents an overview of scientific and technical information in the field of technological features of the process of obtaining high-temperature carbon plastics based on thermosetting polyimide binders. The parameters of molding are given and their comparative analysis, areas of application and recommended operating temperatures of high-temperature polyimide carbon-fiber reinforced plastics, developed and produced by foreign companies, whose products have been successfully implemented in practice in structural elements of aerospace engineering products, are presented.

Reference list
  1. Kablov E.N. New generation Materials and technologies for their digital Processing. Vestnik Russiyskoy akademii nauk, 2020, vol. 90, no. 2, pp. 225–228.
  2. Kablov E.N. Materials of a new generation – the basis of innovation, technological leadership and national security of Russia. Intellekt i tekhnologii, 2016, no. 2 (14), pp. 16–21.
  3. Kablov E.N. Composites: today and tomorrow. Metally of Evrazii, 2015, no. 1, pp. 36–39.
  4. Mukhametov R.R., Petrova A.P. Thermosetting binders for polymer composites (review). Aviacionnye materialy i tehnologii, 2019, no. 3 (56), pp. 48–58. DOI: 10.18577/2071-9140-2019-0-3-48-58.
  5. Valueva M.I., Zelenina I.V., Akhmadieva K.R., Zharinov M.A., Khaskov M.A. Developments of FSUE "VIAM" in the field of high-temperature carbon plastics: directions and prospects. Materials of IV All-Rus. conf. “The role of fundamental research in the implementation of the “Strategic directions for the development of materials and technologies for their processing for the period up to 2030”. Moscow: VIAM, 2018, pp. 71–76.
  6. Gunyaeva A.G., Kurnosov A.O., Gulyaev I.N. High-temperature polymer composite ma-terials developed FSUE «VIAM» for aero-space engineering: past, present and future (review). Trudy VIAM, 2021, no. 1 (95), paper no. 05. Available at: http://www.viam-works.ru (accessed: December 4, 2021). DOI: 10.18577/2307-6046-2021-0-1-43-53.
  7. Kablov E.N., Valueva M.I., I.V. Zelenina, Khmelnitskiy V.V., Aleksashin V.M. Carbon plastics based on benzoxazine oligomers – perspective materials. Trudy VIAM, 2020, no. 1, paper no. 07. Available at: http://www.viam-works.ru (accessed: December 4, 2021). DOI: 10.18577/2307-6046-2020-0-1-68-77.
  8. Way of receiving rasplavny poliimidny binding polimerizatsionny type: pat. 2666734 Rus. Federation, no. 2017135540; filed 05.10.17; publ. 12.09.18.
  9. Zharinov M.A., Shimkin A.A., Akhmadiyeva K.R., Zelenina I.V. Features and properties of solvent-free PMR-type polyimide resin. Trudy VIAM, 2018, no. 12 (72), paper no. 05. Available at: http://www.viam-works.ru (accessed: December 4, 2021). DOI: 10.18577/2307-6046-2018-0-12-46-53.
  10. Valueva M.I., Zelenina I.V., Zharinov M.A., Khaskov M.A. High-temperature carbon plastics based on thermosetting polyimide binder. Voprosy materialovedeniya, 2020, no. 3 (103), pp. 89–102.
  11. Mikhailin Yu.A. Heat-resistant polymers and polymeric materials. St. Petersburg: Professiya, 2006, 624 p.
  12. Mikhailin Yu.A. Heat, thermal and fire resistance of polymeric materials. St. Petersburg: Nauchnye osnovy i tekhnologii, 2011, 416 p.
  13. Kerber M.L., Vinogradov V.M., Golovkin G.S. et al. Polymer composite materials: structure, properties, technology: textbook. St. Petersburg: Profession, 2008, 560 p.
  14. Valueva M.I., Zelenina I.V., Zharinov M.A., Akhmadieva K.R. World market of high temperature polyimide carbon plastic (review). Trudy VIAM, 2019, no. 12 (84), paper no. 08. Available at: http://www.viam-works.ru (accessed: December 4, 2021). DOI: 10.18577/2307-6046-2019-0-12-67-79.
  15. Yang S.-Y., Advance polyimide materials: synthesis, characterization, and applications. 1st ed. Elsevier, 2018, 498 p.
  16. Médard Abadie M.J. High Performance Polymers – Polyimides Based – From Chemistry to Applications. Croatia: INTECH, 2012, 244 p.
  17. Kuznetsov A.A., Semenova G.K. Promising high-temperature thermosetting binders for polymer composite materials. Rossiyskiy khimicheskiy zhurnal, 2010, vol. 53, no. 4, pp. 86–96.
  18. Kurnosov A.O., Raskutin A.E., Mukhametov R.R., Melnikov D.A. Polymer composite materials based on thermosetting polyimide binders. Voprosy materialovedeniya, 2016, no. 4, pp. 50–62.
  19. Cho D., Drzal L.T. Phenylethynyl-terminated polyimide, exfoliated graphite nanoplatelets, and the composites: an overview. Carbon letters, 2016, vol. 19, pp. 1–11.
  20. Aerospace. Advance Composite Materials Selector Guide. Available at: https://www.toraytac.com/media/ca3eea73-6961-4ea8-adc7-5d1b861684f6/Bxgrfg/TAC/Documents/Selector%20Guides/Toray_Advanced_Composite_Material_Portfolio_Selector_Guide.pdf (accessed: December 4, 2021).
  21. Whitley K.S., Collins T.J. Mechanical Properties of T650-35/AFR-PE-4 at Elevated Temperatures for Lightweight Aeroshell Designs. Available at: https://ntrs.nasa.gov/search.jsp?R=20060013437 2018-02-25T20:16:46+00:00Z (accessed: December 4, 2021).
  22. Solvay Avimid®R Polyimide Composite. Available at: https://matweb.com/search/datasheettext.aspx?matguid=3dcb6c37bd39469c8e92b27045a13ea4 (accessed: December 4, 2021).
  23. Solvay Avimid®RB Polyimide Composite. Available at: https://www.matweb.com/search/datasheettext.aspx?matguid=d3d9f6997a2145d087bfc9342a8ee61b (accessed: December 4, 2021).
  24. CYCOM®2237. Solvay. 2012. Available at: https://www.solvay.com/en/product/cycom-2237 (December 4, 2021).
  25. MVK-10. RTM Polyimide. Product description. Available at: http://www.maverickcorp.com/_CE/pagecontent/Documents/MVK-10.pdf (December 4, 2021).
  26. MVK-14 FREEFORM®. High temperature polyimide. Available at: http://www.maverickcorp.com/high-temperature-resins/material-options-high/mvk-14-freeform/ (accessed: December 4, 2021).
  27. Bain S., Ozawa S., Jim M. Criss Jr. Development of a Cure/Postcure Cycle for PETI-330 Laminates Fabricated by Resin Transfer Molding. Available at: https://www.academia.edu/5559484/Development_of_a_Cure_Postcure_Cycle_for_PETI-330_Laminates_Fabricated_by_Resin_Transfer_Molding (accessed: December 4, 2021).
  28. High tempereture composite materials. Available at: https://pdf4pro.com/amp/view/high-tempereture-composite-materials-upilex-5a5302.html (accessed: December 4, 2021).
  29. Connell J.W., Smith J.G., Jr., Hergenrother P.M., Criss J.M. High Temperature Transfer Molding Resins: Status of PETI-298 and PETI-330. Available at: https://www.cs.odu.edu/~mln/ltrs-pdfs/NASA-2003-35sampe-jwc.pdf (accessed: December 4, 2021).
  30. Ghose S., Cano R.J., Watson K.A. et al. High temperature VARTM of phenilethynyl terminated imides. Available at: https://www.iccm-central.org/Proceedings/ICCM17proceedings/Themes/Industry/AEROSPACE%20APPLICATIONS/A2.8%20Ghose.pdf (accessed: December 4, 2021).
  31. Fernberg P., Gong G., Mannberg P. Processing and properties of new polyimide composites with high temperature ability. ECCM16 – 16th European Conference on Composite Materials. Available at: http://www.escm.eu.org/eccm16/assets/0600.pdf (accessed: December 4, 2021).
  32. Tsampas S., Fernberg P., Joffe R. Development of novel high Tg polyimide-based composites. Part II: Mechanical characterization. Journal of Composite Materials, 2018, vol. 52, no. 2, pр. 261–274.
  33. Tsampas S., Fernberg P., Joffe R. Mechanical performance on novel high Tg polyimide matrix carbon fibre-reinforced laminates. 20th International Conference on Composite Materials. Available at: https://iccm-central.org/Proceedings/ICCM20proceedings/papers/paper-3213-1.pdf (accessed: December 4, 2021).
  34. Varna J., Zrida H. Analysis of Microdamage in Thermally Aged CF/Polyimide Laminates. Mechanics of Composite Materials, 2017, vol. 53, no. 1, pp. 45–58.
  35. Lee C.-S. A process simulation model for the manufacture of composite laminates from fiber-reinforced, polyimide matrix prepreg materials: a dissertation submitted to the faculty of the Virginia Polytechnic Institute and State University in partial fulfillment of the requirements for the degree of Doctor of Philosophy in Engineering Mechanics. Blacksburg, 1993, 205 p.
  36. Wilson D. PMR-15 Processing, Properties and Problems – a Review. British Polymer Journal, 1988, no. 20, pp. 405–416.
  37. Sheppard C.H., Hoggatt J.T., Symonds W.A. Quality control developments for graphite/PMR-15 polyimide composites materials. NASA, 1979, 181 p.
  38. RTM and RI processable polyimide resins: pat. US 7129318 B2; filed 30.08.04; publ. 31.10.06.
  39. Thamilselvan G. Methodology for fabricating high temperature composite panel and evaluation. Toronto, 2021, 98 p.
  40. Kolpachkov E.D., Vavilova M.I., Kurnosov A.O., Gunyaeva A.G. Glass-reinforced plastics based on thermosetting polyimide binders. All-Rus. Sci.-Tech. Conf. "Polymer composite materials of a new generation for civil industries": proceedings of conf. Available at: https://conf.viam.ru/sites/default/files/uploads/proceedings/1294.pdf (accessed: December 4, 2021).
  41. Zharinov M.A., Petrova A.P., Babchuk I.V., Akhmadieva K.R. Heat-resistant polyimide structural adhesives (review). Klei. Germetiki. Tekhnologii, 2021, no. 4, pp. 2–8.
  42. Dolmatovsky M.G., Sokolov I.I., Stepanov A.V. Destruction and control of honeycomb structures with spheroplasts. Konstruktsii iz kompozitsionnykh materialov, 2009, no. 2, pp. 97–103.