Study of the resistance of carbon fibers to oxidation

Sidorina A.I., Safronov A.M.
Sidorina A.I., Safronov A.M. Study of the resistance of carbon fibers to oxidation // Proceedings of VIAM. 2022. No. 7. DOI: 10.18577/2307-6046-2022-0-7-63-73. URL: https://test.viam.ru/en/journal/2022/7/6
Keywords
carbon fibers, reinforcing fillers, thermal oxidative resistance of carbon fibers, thermal oxidation
Abstract

Presents the results of a study of the resistance to oxidation of various types and manufacturers carbon fibers by exposure to a given temperature for a certain time. High-strength carbon fibers with standard and intermediate Young’s modulus were investigated. The obtained results of short-term and long-term tests correlate with the results of thermogravimetric analysis. It is shown that among the studied fibers, high-strength carbon fibers with intermediate Young’s modulus have the greatest thermal oxidative resistance.

Reference list
  1. Kablov E.N. Formation of domestic space materials science. Vestnik RFFI, 2017, no. 3, pp. 97–105.
  2. Sidorina A.I. Multiaxial carbon fabrics in the products of aviation technology (review). Aviation materials and technologies, 2021, no. 3 (64), paper no. 10. Available at: http://www.journal.viam.ru (accessed: April 1, 2022). DOI: 10.18577/2713-0193-2021-0-3-105-116.
  3. Gunyaeva A.G., Sidorina A.I., Kurnosov A.O., Klimenko O.N. Polymeric composite materials of new generation on the basis of binder VSE-1212 and the filling agents alternative to ones of Porcher Ind. and Toho Tenax. Aviacionnye materialy i tehnologii, 2018, no. 3 (52), pp. 18–26. DOI: 10.18577/2071-9140-2018-0-3-18-26.
  4. Park S.-J. Carbon Fibers. Singapore: Springer Verlag, 2019, 358 p.
  5. Varshavsky V.Ya. Carbon fibres. Moscow: Varshavsky V.Ya., 2007, 496 p.
  6. Mikhailin Yu.A. Structural polymeric composite materials. Moscow: Nauchnye osnovy i tekhnologii, 2008, 822 p.
  7. Carbon fibers and carbon composites. Ed. E. Fitzer. Moscow: Mir, 1988, 338 p.
  8. Govorov A.V., Galiguzov A.A., Tikhonov N.A. et al. Investigation of the kinetics of oxidation of carbon fibers of various types. Novye ogneupory, 2015, no. 11, pp. 34–39.
  9. Comprehensive Composite Materials. Ed. A. Kelly, C. Zweben. Oxford: Pergamon Press, 2000, 6000 p.
  10. Tagawa M., Ohmae N., Umeno M. et al. Surface Characterization of Carbon Fibers Exposed to 5 eV Energetic Atomic Oxygen Beam Studied by Wetting Force Measurements. Japanese Journal of Applied Physics, 1991, vol. 30, pp. 2134–2138.
  11. Laptev A.B., Nikolayev E.V., Kolpachkov E.D. Thermodynamic characteristics of aging of polymeric composite materials under conditions of real exploitation. Aviaсionnye materialy i tehnologii, 2018, no. 3, pp. 80–88. DOI: 10.18577/2071-9140-2018-0-3-80-88.
  12. Kablov E.N. The role of fundamental research in the creation of new generation materials. Reports of the XXI Mendeleev Congress on General and Applied Chemistry: in 6 vols. St. Petersburg, 2019, vol. 4, p. 24.
  13. Vetrova E.Yu., Shchekin V.K., Kurs M.G. Comparative evaluation of methods for the determination of corrosion aggressivity of the atmosphere. Aviacionnye materialy i tehnologii, 2019, no. 1 (54), pp. 74–81. DOI: 10.18577/2071-9140-2019-0-1-74-81.
  14. Tong Y., Wang X., Su H., Xu L. Oxidation kinetics of polyacrylonitrile-based carbon fibers in air and the effect on their tensile properties. Corrosion Science, 2011, vol. 53, pp. 2484–2488.
  15. Kablov E.N. Materials of a new generation and digital technologies for their processing. Vestnik Rossiyskoy akademii nauk, 2020, vol. 90, no. 4, pp. 331–334.
  16. Wang Z.M., Yamashita N., Wang Z.X. et al. Air oxidation effects on microporosity, surface property, and CH4 adsorptivity of pitch-based activated carbon fibers. Journal of Colloid Interface Science, 2004, vol. 276, is. 1, pp. 143–150.
  17. Rong H., Ryu Z., Zheng J., Zhang Y. Effect of air oxidation of Rayon-based activated carbon fibers on the adsorption behavior for formaldehyde. Carbon, 2002, vol. 40, pp. 2291–2300.
  18. Poila E.J., Serra J.L. Oxidation of Carbon Fiber-Reinforced Silicon Carbide Matrix Composites at Reduced Oxygen Partial Pressures. Journal of the American Ceramic Society, 2011, vol. 94, is. 7, pp. 2185–2192.
  19. Hosokai S., Kishimoto K., Norinaga K. et al. Characteristics of Gas-Phase Partial Oxidation of Nascent Tar from the Rapid Pyrolysis of Cedar Sawdust at 700–800 °C. Energy & Fuels, 2010, vol. 24, pp. 2900–2009.
  20. Gourdin C. Ageing of carbon fibres of various origins. 4th Int. SAMPE Conference. Bourdeaux, 1983, pp. 49–61.
  21. Morgan P. Carbon Fibers and Their Composites. Florida: CRC Press, 2005, 1200 p.