Determination of impurities in nickel alloys by the method of park optical emission spectroscopy

Alekseev A.V., Petrov P.S.
UDC
543.51; 669.1
DOI
10.18577/2307-6046-2023-0-5-124-133
Article PDF (Russian) (806.06 KB)
How to cite
Alekseev A.V., Petrov P.S. Determination of impurities in nickel alloys by the method of park optical emission spectroscopy // Proceedings of VIAM. 2023. No. 5. DOI: 10.18577/2307-6046-2023-0-5-124-133. URL: https://test.viam.ru/en/journal/2023/5/11
Keywords
optical emission spectroscopy, atomic emission spectroscopy, nickel alloys, IOES, nickel analysis, impurity determination
Abstract

Impurities (the concentration of most elements is less than 0,01 % wt.) As, Ca, Zr, Pb, Nb, La, Nd and Fe in a nickel alloy were determined by spark optical emission spectroscopy (ISES). The equipment settings were selected to maximize the analytical signals from all the elements being determined. The analysis was carried out without the use of standard samples using the calibration dependences embedded in the software of the equipment. The correctness of the obtained results was confirmed by a comparative analysis by inductively coupled plasma mass spectrometry.

Reference list
  1. Kablov E.N., Bondarenko Yu.A., Echin A.B. Development of technology of cast superalloys directional solidification with variable controlled temperature gradient. Aviacionnye materialy i tehnologii, 2017, no. S, pp. 24–38. DOI: 10.18577/2071-9140-2017-0-S-24-38.
  2. Bondarenko Yu.A. Trends in the development of high-temperature metal materials and technologies in the production of modern aircraft gas turbine engines. Aviacionnye materialy i tehnologii, 2019, no. 2 (55), pp. 3–11. DOI: 10.18577/2071-9140-2019-0-2-3-11.
  3. Grigorenko V.B., Morozova L.V. Application of the scanning electron microscopy for studying of initial destruction stages. Aviacionnye materialy i tehnologii, 2018, no. 1 (50), pp. 77–87. DOI: 10.18577/2071-9140-2018-0-1-77-87.
  4. Kablov E.N., Sidorov V.V., Kablov D.E., Min P.G. The metallurgical fundamentals for high quality maintenance of single crystal heat-resistant nickel alloys. Aviacionnye materialy i tehnologii, 2017, no. S, pp. 55–71. DOI: 10.18577/2071-9140-2017-0-S-55-71.
  5. Lomberg B.S., Ovsepjan S.V., Bakradze M.M., Letnikov M.N., Mazalov I.S. The application of new wrought nickel alloys for advanced gas turbine engines. Aviacionnye materialy i tehnologii, 2017, no. S, pp. 116–129. DOI: 10.18577/2071-9140-2017-0-S-116-129.
  6. Min P.G., Vadeev V.E., Kramer V.V. The development of the new VZhM200 superalloy and the technology of its production for casting of the advanced engines’ blades by the directional crystallization. Aviation materials and technologies, 2021, no. 3 (64), paper no. 02. Available at: http://www.journal.viam.ru (accessed: Fedruaru 02, 20232). DOI: 10.18577/2071-9140-2021-0-3-11-18.
  7. Kablov E.N., Chabina E.B., Morozov G.A., Muravskaya N.P. Conformity assessment of new materials using high-level RM and MI. Kompetentnost, 2017, no. 2, pp. 40–46.
  8. State Standard 6689.13–92. Nickel. Nickel and copper-nickel alloys. Methods for the determination of arsenic. Moscow: Publishing house of standards, 1992, pp. 2–5.
  9. State Standard 6689.5–92. Nickel. Nickel and copper-nickel alloys. Methods for the determination of iron. Moscow: Publishing house of standards, 1992, pp. 2–4.
  10. State Standard 6689.24–92. Nickel. Nickel and copper-nickel alloys. Methods for the determination of calcium. Moscow: Publishing house of standards, 1992, pp. 2–4.
  11. State Standard 6689.20–92. Nickel. Nickel and copper-nickel alloys. Methods for the determination of lead. Moscow: Publishing house of standards, 1992, pp. 2–4.
  12. Hu J., Wang H. Determination of Trace Elements in Super Alloy by ICP-MS. Mikrochimica Acta, 2001, vol. 137, pp. 149–155.
  13. Fundamentals of analytical chemistry. Ed. Yu.A. Zolotova. Moscow: Academy, 2012, 102 p.
  14. Karpov Yu.A., Gimelfard F.A., Savostin A.P., Salnikov V.D. Analytical control of metallurgical production. Moscow: Metallurgiya, 1995, 98 p.
  15. Gorsky E.V., Livshits A.M. Accounting for interelement influences in the analysis of high-alloy steels on the Papuas-4 emission spectrometer. Zavodskaya laboratoriya. Diagnostika materialov, 2017, vol. 83, no. 2, pp. 26–30.
  16. Popova A.N., Sukhomlinov V.S., Mustafaev A.S. Accounting for Interelement in Atomic Emission Spectroscopy: A Nonlinear Theory. Applied Sciences, 2021, vol. 11, pp. 11–23.
  17. Kuznetsov A.A., Slepterev V.A., Peleznev A.V. Implementation of mobile calibration characteristics of instruments for spectral analysis of materials using virtual standards. Omskiy nauchnyy vestnik, 2013, no. 3 (125), pp. 241–246.
  18. Tables of Spectral Lines. Eds. S.L. Mandelstam, S.M. Raisky. Moscow: GONTI NKTP USSR, 1938, 321 p.
  19. Kuznetsov A.A., Meshkova O.B., Slepterev V.A. Investigation of the factors influencing the results of measurement of intensities in the spectral analysis of materials. Omskiy nauchnyy vestnik, 2011, no. 3 (103), pp. 242–245.