Modern trends in the field of heat treatment and thermomechanical processing of metastable β-titanium alloys

Shiryaev A.A., Nochovnaya N.A.
Shiryaev A.A., Nochovnaya N.A. Modern trends in the field of heat treatment and thermomechanical processing of metastable β-titanium alloys // Proceedings of VIAM. 2023. No. 8. DOI: 10.18577/2307-6046-2023-0-8-35-51. URL: https://test.viam.ru/en/journal/2023/8/4
Keywords
manufacturing of semi-finished products, heat treatment, thermomechanical processing, microstructure, mechanical properties
Abstract

Presents the classification and features of various subgroups of metastable β-titanium alloys, considers typical approaches for their heat treatment and thermomechanical processing. The results of recent studies that form trends for further development in the field of heat treatment and thermomechanical processing technologies for metastable β-titanium alloys are presented. It is noted that the main trend of most publications is the use of modern high-tech research methods: SEM, HRTEM, EBSD. Among the most important trends in the study area, one can single out works related to obtaining and controlling the characteristics of a bimodal and multimodal structure in order to increase the level and ensure a balance of the complex of mechanical and operational properties.

Reference list
  1. Dzunovich D.A., Lukina E.A., Yakovlev A.L. Influence of heat treatment parameters on producibility and mechanical properties of sheets made from high-strength titanium alloy VT23. Aviacionnye materialy i tehnologii, 2018, no. 3 (52), pp. 3–10. DOI: 10.18577/2071-9140-2018-0-3-3-10.
  2. Moiseev V.N. Beta-titan alloys and prospects for their development. Metallovedeniye i termicheskaya obrabotka metallov, 1998, no. 12, pp. 11–14.
  3. Bania P.J. Beta Titanium Alloys and Their Role in the Titanium Industry// JOM, 1994, no. 7, pp. 16–19.
  4. Belogur V.P. Elastic elements of titanium alloys. Pruzhiny, 2016, no. 1, pp. 12–14
  5. Shaboldo O.P., Vitorsky Y.M., Karashtin E.A. et al. Spring materials with special properties from hard to and formed highly alloyed, thermomechanically strengthened alloys based on titanium, nickel and niobium. Metalloobrabotka, 2011, no. 2 (62), pp. 28–35.
  6. Nyakana S.L., Fanning J.C., Boyer R.R. Quick Reference Guide for β Titanium Alloys in the 00s. Journal of Materials Engineering and Performance, 2005, vol. 14 (6), pp. 799–811.
  7. Boyer R.R., Briggs R.D. The Use of β Titanium Alloys in the Aerospace Industry. Journal of Materials Engineering and Performance, 2005, vol. 14 (6), pp. 681–685.
  8. Duyunova V.A., Putyrskiy S.V., Arislanov A.A., Krokhina V.A., Shiryaev A.A. Analysis of the effect of heat treatment on the structure and mechanical proper-ties of bars made of VT47 titanium alloy. Aviation materials and technologies, 2021, no. 4 (65), paper no. 03. Available at: http://www.journal.viam.ru (accessed: April 15, 2023). DOI: 10.18577/2713-0193-2021-0-4-26-34.
  9. Dzunovich D.A., Alekseyev E.B., Panin P.V., Lukina E.A., Novak A.V. Structure and properties of sheet semi-finished products from various wrought intermetallic titanium alloys. Aviacionnye materialy i tehnologii, 2018, no. 2 (51), pp. 17–25. DOI: 10.18577/2071-9140-2018-0-2-17-25.
  10. Kablov E.N. New Generation Materials and Technologies for Their Digital Processing. Herald of the Russian Academy of Sciences, 2020, vol. 90, no. 2, pp. 225–228.
  11. Shchetinina N.D., Rudchenko A.S., Selivanov A.A. The approaches that are used for developed of optimal strain modes of aluminum-lithium alloys (review). Trudy VIAM, 2020, no. 8 (90), paper no. 03. Available at: http://www.viam-works.ru (accessed: April 04, 2023). DOI: 10.18577/2307-6046-2020-0-8-20-34.
  12. Titanium alloys. Metallography of titanium alloys. Ed. N.F. Anoshkin, A.F. Belov, S.G. Glazunov, V.I. Slutkin. Moscow: Metallurgiya, 1980, 464 p.
  13. Lyasotskaya V.S. Thermal processing of welded joints of titanium alloys. Moscow: Ekomet, 2003. 352 p.
  14. Ilyin A.A., Kolachev B.A., Polkin I.S. Titanium alloys. Composition, structure, properties: reference. Moscow: VILS; MATI, 2009, 520 p.
  15. Titanium and titanium alloys. Fundamentals and applications. Ed. C. Leyens, Peters M. Wiley–VCH, 2003, 513 p.
  16. Kolli R.P., Devaraj A. A review of metastable beta titanium alloys. Metals, 2018, vol. 8, pp. 1–41.
  17. Lütjering G., Williams J.C. Titanium. Engineering Materials Processes. Second ed. Springer Berlin, Heidelberg, 2007, 442 p.
  18. Weiss I., Semiatin S.L. Thermomechanical processing of beta titanium alloys – an overview. Material Science and Engineering: A, 1998, vol. 243, pp. 46–65.
  19. Ilyin A.A. The mechanism and kinetics of phase and structural transformations in titanium alloys. Moscow: Nauka, 1994, 304 p.
  20. Boyer R. Aerospace applications of beta titanium alloys. JOM, 1994, no. 6, pp. 20–23.
  21. Cotton J.D., Briggs R.D., Boyer R.R. et al. State of the Art in Beta Titanium Alloys for Airframe Applications. JOM, 2015, vol. 67, no. 6, pp. 1281–1303.
  22. Zhao X., Niinomi M., Nakai M., Hieda J. Effect of Deformation-Induced ω Phase on the Mechanical Properties of Metastable β-Type Ti–V Alloys. Materials Transactions, 2012, vol. 53, no. 8, pp. 1379–1384.
  23. Panin P.V., Nochovnaya N.A., Kablov D.E., Alekseev E.B., Shiryaev A.A., Novak A.V. Practical guide for metallography of alloys based on titanium and its intermetallids: textbook. Ed. E.N. Kablov. Moscow: VIAM, 2020, 200 p.
  24. Donachie M.J. Titanium: A Technical Guide. 2nd ed. ASM International: Materials Park, OH, USA. 2000, 367 p.
  25. Kablov E.N., Nochovnaya N.A., Shiryaev A.A., Davydova E.A. Investigation of structural and phase transformations in metastable β-titanium alloys and effect of cooling rate from homogenization temperature on structure and properties of VT47 alloy. Part 1. Trudy VIAM, 2020, no. 6–7 (89), paper no. 01. Available at: http://www.viam-works.ru (accessed: April 15, 2023). DOI: 10.18577/2307-6046-2020-67-3-10.
  26. Chen W., Yu G., Li K. et al. Plastic instability in Ti‒6Cr‒5Mo‒5V‒4Al metastable β-Ti alloy containing the β-spinodal decomposition structures. Materials Science & Engineering A, 2021, vol. 811, art. 141052. DOI: 10.1016/j.msea.2021.141052.
  27. Bania P.A., Lenning G.A., Hall J.A. Development and Properties of Ti–15V–3Cr–3Sn–3Al (Ti15-3). Beta Titanium Alloys in the 80’s. Eds. R.R. Boyer, H.W. Rosenberg. TMS Warrendale, PA, 1984, pp. 209–228.
  28. Schmidt P., El-Chaikh A., Christ H.-J. Effect of Duplex Aging on the Initiation and Propagation of Fatigue Cracks in the Solute-rich Metastable β Titanium Alloy Ti 38-644. Metallurgical and Materials Transactions A, 2011, vol. 42A, pp. 2652–2667.
  29. Zhanga Y., Xianga S., Tana Y.B., Jia X.M. Study on ω-assisted α nucleation behavior of metastable β-Ti alloys from phase transformation mechanism. Journal of Alloys and Compounds, 2021, vol. 890, art. 161686. DOI: 10.1016/j.jallcom.2021.161686.
  30. Poulose P.K., Imam M.A. The effect of microstructure on tensile properties and fracture toughness of Ti-15-3 Alloy. Titanium ‘95: Science and Technology. Eds. P.A. Blenkinsop, W.J. Evans, H.M. Flower. London: Institute of Metals, 1996, pp. 988–995.
  31. Shiryaev A.A., Nochovnaya N.A. Increasing the characteristics of the fatigue of the pseudo-β-titan alloy VT47 by improving the regime of strengthening heat treatment. New materials and technologies for deep processing of raw materials-the basis of innovative development of the Russian economy: Materials of the III Intern. Sci.-tech. Conf. M.: NRC «Kurchatov Institute» – VIAM, 2022, pp. 411–429.
  32. Boyer R.R., Rack H.J., Venkatesh V. The influence of thermomechanical processing on the smooth fatigue properties of Ti–15V–3Cr–3Al–3Sn. Materials Science and Engineering A, 1998, vol. 243, pp. 97–102.
  33. Yumak N., Aslantas K. Effect of Heat Treatment Procedure on Mechanical Properties of Ti‒15V‒3Al‒3Sn‒3Cr Metastable β Titanium Alloy. Journal of Materials Engineering and Performance, 2021, vol. 30, pp. 1066–1074.
  34. Mantri S.A., Choudhuri D., Alam T. et al. Tuning the scale of α precipitates in β-titanium alloys for achieving high strength. Scripta Materialia, 2018, vol. 154, pp. 139–144.
  35. Gao J., Rainforth W.M. The Effect of Heating Rate on Discontinuous Grain Boundary Alpha Formation in a Metastable Beta Titanium Alloy. Metallurgical and Materials Transactions A, 2020, vol. 51A, pp. 3766–3771.
  36. Furuhara T., Maki T., Makino T. Microstructure control by thermomechanical processing in β-Ti-15-3 alloy. Journal of Materials Processing Technology, 2001, vol. 117, pp. 318–323.
  37. Markovsky P.E., Ikeda M. Balancing of mechanical properties of Ti‒4.5Fe‒7.2Cr‒3.0Al using thermomechanical processing and rapid heat treatment. Materials Transactions, 2005, vol. 46, no. 7, pp. 1515–1524.
  38. Furuhara T. Role of Defects on Microstructure Development of Beta Titanium Alloys. Metals and materials, 2000, vol. 6, no. 3, pp. 221–224.
  39. Okada M. Strengthening of Ti‒15V‒3Cr‒3Sn‒3Al by Thermo-mechanical Treatments. ISIJ International, 1991, vol. 31, no. 8, pp. 834–839.
  40. Suzuki T., Niwa N., Goto K., Kobayashi M., Moroyama T., Takatori H. Effect of aging on mechanical properties of beta titanium alloys of Ti‒13V‒11Cr‒3Al, Ti‒15V‒3Cr‒3Sn‒3Al and Ti‒3Al‒8V‒6Cr‒4Mo‒4Zr. Titanium ‘95: Science and Technology. London: Institute of Metals, 1996, pp. 1294–1301.
  41. Nochovnaya N.A., Shiryaev A.A., Davydova E.A. Influence of manufacturing parameters on pseudo-β-titanium alloy VT47 sheet structural state and mechanical property anisotropy. Metallurgist, 2023, vol. 66, no. 9–10, pp. 1216–1224.
  42. Zhua W., Tanb C., Xiaoa R., Suna Q., Sun J. Slip behavior of Bi-modal structure in a metastable titanium alloy during tensile deformation. Journal of Materials Science & Technology, 2020, vol. 57, pp. 188–196.
  43. Putyrskiy S.V., Yakovlev A.L., Nochovnaya N.A., Krokhina V.A. Research of different heat treatment modes influence on properties of semi-finished products and welded joints from titanium alloy ВТ22М. Aviacionnye materialy i tehnologii, 2019, no. 1 (54), pp. 3–10. DOI: 10.18577/2071-9140-2019-0-1-3-10.
  44. Krokhina V.A., Putyrskiy S.V., Gribkov M.S. Analysis of structure and mechanical properties of welded joint from titanium alloy VT22M. Aviation materials and technologies, 2022, no. 2 (67), paper no. 05. Available at: http://www.journal.viam.ru (accessed: April 15, 2023). DOI: 10.18577/2713-0193-2022-0-2-52-62.
  45. Basak K. The role of crystallographic relationships between alpha(α) and beta(β) phases on the elevated temperature isothermal phase transformation kinetics in Timetal LCB (Ti‒6.5Mo‒4.5Fe‒1.5Al), 2008. Available at: https://tigerprints.clemson.edu/all_theses/429 (accessed: April 15, 2023).
  46. Jha S.K., Ravichandran K.S. High-cycle fatigue resistance in beta-titanium alloys. JOM, 2000, no. 3, pp. 30–35.
  47. Miyano N., Norimura T., Inaba T., Ameyama K. Reasons for Formation of Triangular Precipitates in Ti–15V–3Cr–3Sn–3Al Titanium Alloy. Materials Transactions, 2006, vol. 47, no. 2, pp. 341–347.
  48. Dehghan-Manshadi A., Dippenaar R.J. Development of α-phase morphologies during low temperature isothermal heat treatment of a Ti–5Al–5Mo–5V–3Cr alloy. Materials Science and Engineering A, 2011, vol. 528, pp. 1833–1839.
  49. Wang S., Chen L., Chen XB. et al. Effect of aging treatment on microstructure and tensile properties of Ti‒4Al‒6Mo‒2V‒5Cr‒2Zr. Journal of materials research and technology, 2023, vol. 22, pp. 2008–2016.
  50. Zhu W., Lei J., Tan C. et al. A novel high-strength β-Ti alloy with hierarchical distribution of α-phase: The superior combination of strength and ductility. Materials and Design, 2019, vol. 168, pp. 1–8.
  51. Zhu W., Kou W., Tan C. et al. Face centered cubic substructure and improved tensile property in a novel β titanium alloy Ti–5Al–4Zr–10Mo–3Cr. Materials Science & Engineering A, 2020, vol. 771, art. 138611. DOI: 10.1016/j.msea.2019.138611.