Influence of titanium dioxide on structure nanoorganizations of binary copolymers

Losev A.V.
UDC
541.64.539.199
DOI
10.18577/2307-6046-2024-0-4-64-82
Article PDF (Russian) (916.03 KB)
How to cite
Losev A.V. Influence of titanium dioxide on structure nanoorganizations of binary copolymers // Proceedings of VIAM. 2024. No. 4. DOI: 10.18577/2307-6046-2024-0-4-64-82. URL: https://test.viam.ru/en/journal/2024/4/5
Keywords
nanoorganization, titanium dioxide, fluorine rubber, composite
Abstract

The formation of several types of nanoformations with a size of 4–80 nm in fluorine rubbers, depending on the history, was detected using XRD. The process of changing the structure of their nanoorganization with the manifestation of phase transitions is also influenced by the chemical structure of junctions in macromolecules, which determines, in particular, the complex and unequal nature of changes in their dynamic viscosity. Titanium dioxide not only facilitates the formation of new types of nano-formations in fluoro-rubbers, but also the polymorphic transition of vinylidene fluoride links from the trans-gosh-trans-gosh conformation to the «flat zigzag» conformation

Reference list
  1. Kablov E.N. Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030». Aviacionnye materialy i tehnologii, 2015, no. 1 (34), pp. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
  2. Kablov E.N. New generation materials are the basis of innovation, technological leadership and national security of Russia. Intellekt i tekhnologiya, 2016, no. 2 (14), pp. 16–21.
  3. Kablov E.N., Chursova L.V., Lukina N.F., Kutsevich K.E., Rubtsova E.V., Petrova A.P. Study of epoxy-polysulfone polymer systems as the basis for high-strength aviation adhesives. Klei. Germetiki. Tekhnologii, 2017, no. 3, pp. 7–12.
  4. Chaykun A.M., Bobrova I.I., Gerasimov D.M., Sergeyev A.V. Elastomers for sealing harness materials: properties, methods of receiving and feature of manufacturing. Trudy VIAM, 2023, no. 7 (125), paper no. 05. Available at: http://www.viam-works.ru (accessed: December 12, 2023). DOI: 10.18577/2307-6046-2023-0-7-56-68.
  5. Losev A.V. Properties and features of protective coatings based on polyvinylidene fluoride and its copolymers (review). Trudy VIAM, 2023, no. 4 (122), paper no. 08. Available at: http://www.viam-works.ru (accessed: December 12, 2023). DOI: 10.18577/2307-6046-2023-0-4-81-89.
  6. Petrova G.N., Perfilova D.N., Starostina I.V., Sapego Yu.A. Research of ways of combination polyurethane thermoplastics with fluoropolymers. Trudy VIAM, 2019, no. 7 (79), paper no. 02. Available at: http://www.viam-works.ru (accessed: December 12, 2023). DOI: 10.18577/2307-6046-2019-0-7-12-25.
  7. Kuznetsova V.А. Influence of the elastomeric modifier on mechanical and viscoelastic properties of epoxy and rubber compositions for erosion resistant coatings. Aviacionnye materialy i tehnologii, 2020, no. 2 (59), pp. 56–62. DOI: 10.18577/2071-9140-2020-0-2-56-62.
  8. Ivanov M.S., Veshkin E.A., Satdinov R.A., Donskikh I.N. New domestic coated textile material for flexible air conditioning ducts of flight vehicles. Trudy VIAM, 2019, no. 4 (76), paper no. 07. Available at: http://www.viam-works.ru (accessed: December 12, 2023). DOI: 10.18577/2307-6046-2019-0-4-57-66.
  9. Arzhakov M.S. Relaxation phenomena in polymers. Montreal: Accent Graphics Communication, 2018, 136 p.
  10. Kozlov G.V., Zaikov G.E. Structure of the Polymer Amorphous State. Leiden: Brill Academic Publishers, 2004, 465 р.
  11. Bartenev G.M., Zelenev Yu.V. Physics and mechanics of polymers. Moscow: Vysshaya shkola, 1983, 391 p.
  12. Volynsky A.L., Bakeev N.F. Structural self-organization of amorphous polymers. Moscow: FIZMATLIT, 2005, 232 p.
  13. Malkin A.Ya., Semakov A.V., Kulichikhin V.G. Structure formation during the flow of polymer and colloidal systems (review). Vysokomolekulyarnye soyedineniya, Ser.: A, 2010, vol. 52, pp. 1879–1902.
  14. Sokolova L.V. Features of high-temperature transitions in polymers. Plasticheskiye massy, 2006, no. 5, pp. 13–25.
  15. Sokolova L.V. Flexibility of macromolecules and structure formation in amorphous polymers. Vysokomolekulyarnye soyedineniya, Ser.: A, 2017, vol. 59, no. 4, pp. 318–330. DOI: 10.7868/S2308112017040113.
  16. Sokolova L.V. Study of the structure of natural and synthetic cis-1,4-polyisoprenes using IR spectroscopy. Vysokomolekulyarnye soyedineniya, Ser.: B, 1994, vol. 36, no. 10, pp. 1737–1748.
  17. Sokolova L.V., Losev A.V., Pronin D.S., Politova E.D. The influence of nanosized modifications of titanium dioxide on the nanoorganization of elastomers. Kristallografiya, 2022, vol. 67, no. 2, pp. 479–487.
  18. Kuzmicheva G.M. Nanosized systems with titanium (IV) oxides. Receipt. Characterization. Properties. Tonkie khimicheskiye tekhnologii, 2015, vol. 10, no. 6, pp. 5–36.
  19. Kuzmicheva G.M., Yulovskaya V.D., Domoroshchina E.N. et al. Influence of nanosized modifications of titanium dioxide with anatase and η-TiO2 structures on the structural characteristics and properties of nanocomposites based on 1,2-polybutadiene. Kauchuk i rezina, 2013, no. 5, pp. 6–11.
  20. Matyushenko D.V. Study of structural transformations stimulated by heating and shock compression in titanium dioxide nanopowders: thesis abstract, Cand. Sc. (Phys.&Math.). Chernogolovka: IPCP RAS, 2011, 23 p.
  21. Umansky Ya., Skakov Yu., Ivanov A. Crystallography, radiography and electron microscopy. Moscow: Metallurgiya, 1982, 632 p.
  22. Manalastas-Cantos К., Konarev P.V., Hajizadeh N.R., KikhneyA.G., Petoukhov M.V. ATSAS 3.0: expanded functionality and new tools for small-angle scattering data analysis. Journal of Applied Crystallography, 2021, vol. 54, no. 2, p. 343. DOI: 10.1107/S1600576720013412.
  23. Svergun D.I., Konarev P.V., Volkov V.V., Koch M.H.J., Sager W.F.C., Smeets J., Blokhuis E.M. A small angle x-ray scattering study of the droplet-cylinder transition in oil-rich sodium
  24. bis(2-ethylhexyl) sulfosuccinate microemulsions. The Journal of Chemical Physics, 2000, vol. 113, no. 11, pp. 1651–1665. DOI: 10.1063/1.481954.
  25. Dennis J.E., Gay D.M., Welsh R.E. An adaptive nonlinear least-squares algorithm. ACM Transactions on Mathematical Software, 1981, vol. 7, no. 3, p. 369. DOI: 10.1145/355958.355966.
  26. Wasserman A.M., Kovarsky A.L. Spin labels and probes in the physical chemistry of polymers. Moscow: Nauka, 1986, 244 p.
  27. Budil D.E., Lee S., Saxena S., Freed J.H. Nonlinear-least-squares analysis of slow-motion EPR spectra in one and two dimensions using a modified Levenberg–Marquardt algorithm. Journal of Magnetic Resonance, Ser.: A, 1996, vol. 120, p. 155. DOI: /10.1006/jmra.1996.0113.
  28. Timofeev V.P., Misharin A.Yu., Tkachev Ya.V. Modeling of ESR spectra of the TEMPO radical in water-lipid systems in different frequency ranges. Biofizika, 2011, vol. 56, vol. 3, p. 420.
  29. Nudelman Z.N. Fluororubbers: basics, processing, application. Moscow: PIF RIAS, 2007, 384 p.
  30. Novitskaya S.P., Nudelman Z.N., Dontsov A.A. Fluoroelastomers. Moscow: Chemistry, 1988, 240 p.
  31. Moore A.L. Fluoroelastomers Handbook: The definitive user’s guide and databook. Norwich, NY: William Andrew, 2005, 366 p.
  32. Kargin V.A., Slonimsky G.L. Brief essays on the physical chemistry of polymers. Moscow: Khimiya, 1967, 231 p.
  33. Sokolova L.V., Evreinov Yu.V. The influence of high-temperature transitions on the deformability of a number of flexible-chain polymers. Vysokomolekulyarnyye soyedineniya, Ser.: A, 1993, vol. 35, no. 5, p. 244.
  34. Galil-Ogly F.A., Novikov A.S., Nudelman Z.N. Fluorine rubbers and rubbers based on them. Moscow: Khimiya, 1966, 235 p.
  35. Krakht L.N., Igumenova T.I., Chichvarin A.V. On the mechanism of interaction of a mixture of fullerenes with macromolecules of polymers of various structures. Sovremennye problemy nauki i obrazovaniya, 2012, no. 6, pp. 179–185.
  36. Boyer R.F. Order in the Amorphous State of Polymers. Plenum Press, NY, 1987, p. 477.
  37. Olkhov Yu.A., Allayarov S.R., Nikolsky V.G. Study of gamma-irradiated copolymer of vinylidene fluoride and chlorotrifluoroethylene using radiothermoluminescence and thermomechanical spectroscopy methods. Khimiya vysokikh energiy, 2016, vol. 50, no. 3, pp. 177–183.
  38. Kochervinsky V.V. The influence of radiation on the ferroelectric characteristics of polyvinylidene fluoride. Vysokomolekulyarnye soyedineniya, Ser.: A, 1993, vol. 35, no. 12, p. 1978.
  39. Hussein A.D., Sabry R.S., Dakhil O.A.A. Fabrication of stretchable PVDF piezoelectric NanoGenerator. Journal of College of Education, 2019, vol. 1, no. 1, p. 17.
  40. A critical analysis of the α, β and γ phases in poly(vinylidene fluoride) using FTIR. RSC Advances, 2017, vol. 7, no. 25, p. 15382. DOI: 10.1039/c7ra01267e.
  41. Polymer nanocomposites. Eds. Yu-Wing Mai, Zhon-Zhen Yu. Moscow: Technosphere, 2011, 687 p.
  42. Gamlitsky Yu.A. Nanomechanics of the phenomenon of strengthening of filled elastomers. Kauchuk i rezina, 2017, vol. 76, no. 5, pp. 308–317.