Determination of platinum group elements in nickel alloys by inductively coupled plasma mass spectrometry method

Beznosyuk A.N., Alekseev A.V.
UDC
543.51:669.1
DOI
10.18577/2307-6046-2024-0-8-101-110
Article PDF (Russian) (653.61 KB)
How to cite
Beznosyuk A.N., Alekseev A.V. Determination of platinum group elements in nickel alloys by inductively coupled plasma mass spectrometry method // Proceedings of VIAM. 2024. No. 8. DOI: 10.18577/2307-6046-2024-0-8-101-110. URL: https://test.viam.ru/en/journal/2024/8/9
Keywords
inductively coupled plasma mass spectrometry, platinum group metals, determination of harmful impurities, microwave sample preparation
Abstract

The work determined the impurities of platinum group metals (Ru, Rh, Pd, Os, Ir, Pt) and gold in complex-alloyed nickel alloys using inductively coupled plasma mass spectrometry. The method for dissolving a sample and preparing it for analysis is presented. Spectral interferences are eliminated using a reaction-collision cell and a mathematical correction method. The accuracy of the results was confirmed by comparative analysis with data obtained using high-resolution mass spectrometry with a glow discharge.

Reference list
  1. Min P.G., Vadeev V.E., Kramer V.V. The development of the new VZhM200 superalloy and the technology of its production for casting of the advanced engines’ blades by the directional crystallization. Aviation materials and technologies, 2021, no. 3 (64), paper no. 02. Available at: http://www.journal.viam.ru (accessed: June 04, 2024). DOI: 10.18577/2713-0193-2021-0-3-11-18.
  2. Kablov E.N. Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030». Aviacionnye materialy i tehnologii, 2015, no. 1 (34), pp. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
  3. Min P.G., Vadeev V.E. The development and introduction into serial production of the new superalloy VZhL125 for the advanced aviation engines vanes. Aviation materials and technologies, 2023, no. 1 (70), paper no. 01. Available at: http://www.journal.viam.ru (accessed: June 04, 2024). DOI: 10.18577/2713-0193-2023-0-1-3-16.
  4. Kablov E.N., Petrushin N.V., Svetlov I.L., Demonis I.M. Casting heat-resistant nickel alloys for advanced aviation gas turbine engines. Tekhnologiya legkikh splavov, 2007, no. 2, pp. 6–16.
  5. Svetlov I.L., Petrushin N.V., Epishin A.I., Karashaew M.M., Elyutin E.S. Single crystals of nickel-based superalloys alloyed with rhenium and ruthenium (review). Part 1. Aviation materials and technologies, 2023, no. 1 (70), paper no. 03. Available at: http://www.journal.viam.ru (accessed: June 04, 2024). DOI: 10.18577/2713-0193-2023-0-1-30-50.
  6. Svetlov I.L., Petrushin N.V., Epishin A.I., Karashaew M.M., Elyutin E.S. Single crystals of nickel-based superalloys alloyed with rhenium and ruthenium (review). Part 2. Aviation materials and technologies, 2023, no. 2 (71), paper no. 01. Available at: http://www.journal.viam.ru (accessed: June 04, 2024). DOI: 10.18577/2713-0193-2023-0-2-3-22.
  7. Kablov E.N., Chabina E.B., Morozov G.A., Muravskaya N.P. Conformity assessment of new materials using high-level RMs and MI. Kompetentnost, 2017, no. 2, pp. 40–46.
  8. State Standard 12228.1–78. Ruthenium. Spectral analysis method. Moscow: Publ. House of Standards, 1977, pp. 1–3.
  9. Van Meel K., Smekens A., Behets M., Kazandjian P., Van Grieken R. Determination of platinum, palladium, and rhodium in automative catalysts using high-energy secendory target X-ray fluorescence spectrometry. Analytical Chemistry, 2007, vol. 79, no. 16, pp. 6383–6389.
  10. Tsogas G.Z., Giokas D.L., Vliessidies A.G., Evmiridis N.P. On the re-assessment of the optimum conditions for the determination of platinum, palladium and rhodium in environmental samples by electrothermal atomic absorbtion spectrometry and microwave digestion. Talanta, 2008, vol. 76, pp. 635–641.
  11. Tyutyunnik O.A., Nabiullina S.N., Anosova M.O., Kubrakova I.V. Determination of trace contents of platinum group elements and gold in ultramafic rocks using AG-X8 and LN-RESIN sorbents by inductively coupled plasma mass spectrometry. Zhurnal analiticheskoy khimii, 2020, vol. 75, no. 6, pp. 527–536.
  12. Leikin A.Yu., Karandashev V.K., Lisovsky S.V., Volkov I.A. Use of a reaction-collision cell for the determination of impurity elements in rare earth metals by ICP-MS. Zavodskaya laboratoriya. Diagnostika materialov, 2014, vol. 80, no. 5, pp. 6–9.
  13. Grebneva-Balyuk O.N., Kubrakova I.V. Determination of platinum group elements in geological objects by inductively coupled plasma mass spectrometry: possibilities and limitations. Zhurnal analiticheskoy khimii, 2020, vol. 75, no. 3, pp. 195–208.
  14. Menshikov V.I., Vlasova V.N., Lozhkin V.I., Sokolnikova Yu.V. Determination of platinum group elements in rocks by ICP-MS with external calibration after separation of matrix elements on the KU-2-8 cation exchanger. Analytics and Control. 2016, vol. 20, no. 3, pp. 190–201.
  15. Pupyshev A.A., Epova E.N. Spectral interference of polyatomic ions in the method of mass spectrometry with inductively coupled plasma. Analitika i kontrol, 2001, vol. 5, no. 4, pp. 335–369.