CLIMATE AGING OF PAINT COATING SYSTEMS

Part 3. Comparison of results of natural and accelerated climatic tests taking into account the effect of seasonality
Startsev V.O.
UDC
667.6:535.6
DOI
10.18577/2307-6046-2025-0-7-105-118
Article PDF (Russian) (1.24 MB)
How to cite
Startsev V.O. CLIMATE AGING OF PAINT COATING SYSTEMS. Part 3. Comparison of results of natural and accelerated climatic tests taking into account the effect of seasonality // Proceedings of VIAM. 2025. No. 7. DOI: 10.18577/2307-6046-2025-0-7-105-118. URL: https://test.viam.ru/en/journal/2025/7/8
Keywords
paint coating, color distance, solar radiation, mathematical modeling, forecasting
Abstract

The article examines the correlation dependences between the change in the color distance of aluminum alloy samples with epoxy and fluoropolyurethane enamels with red and gray pigments when exposed to natural conditions of three climatic zones and laboratory conditions. It is shown that the use of a model of color distance change, taking into account the dose of solar radiation, and the obtained correlation dependences allows to accurately calculate the duration of laboratory simulation tests.

Reference list
  1. Cornet A.J., Homborg A.M., Anusuyadevi P.R. et al. Unravelling corrosion degradation of aged aircraft components protected by chromate-based coatings. Engineering Failure Analysis, 2024, vol. 159, art. 108070.
  2. Zhang Ti., Zhang Te., He Y. et al. Corrosion and aging of organic aviation coatings: A review. Chinese Journal of Aeronautics, 2023, vol. 36, no. 4, pp. 1–35.
  3. Huang H., Guo H., Feng Y. Study on UV-aging performance of fluorinated polymer coating and application on painted muds. Materials Research Express, 2021, vol. 8, no. 1, art. 015301.
  4. Cai G., Wang H., Jiang D., Dong Z. Degradation of fluorinated polyurethane coating under UVA and salt spray. Part I: Corrosion resistance and morphology. Progress in Organic Coatings, 2018, vol. 123, pp. 337–349.
  5. Cai G., Zhang D., Jiang D., Dong Z. Degradation of fluorinated polyurethane coating under UVA and salt spray. Part II: Molecular structures and depth profile. Progress in Organic Coatings, 2018, vol. 124, pp. 25–32.
  6. Lebedev M.P., Startsev O.V., Koval T.V., Veligodskii I.M. Multiplet relaxation α-transitions in a fluororethane coating after climatic aging. Doklady Rossiyskoy akademii nauk. Khimiya, nauki o materialakh, 2024, vol. 516, no. 1, pp. 45–51.
  7. Isupov V.V., Startsev O.V. Numerical methods in dynamic mechanical spectroscopy of polymers. Mathematical models and numerical methods of continuum mechanics: reports Int. conf. dedicated to the 75th anniversary of the outstanding mathematician and mechanic, organizer of science academician N.N. Yanenko. Ed. Yu.I. Shokin. Novosibirsk: Publ. SB RAS, 1996, pp. 293–294.
  8. Startsev O.V., Perepechko I.I. Molecular mobility and relaxation processes in the epoxy matrix of a composite. 1. Influence of the type of reinforcing filler. Mekhanika kompozitnykh materialov, 1984, no. 3, pp. 387–391.
  9. Startsev V.O., Nizina T.A., Startsev O.V. A colour criterion of the climatic ageing of an epoxy polymer. International Polymer Science and Technology, 2016, vol. 43, no. 8, pp. 45–48.
  10. Kablov E.N., Startsev O.V., Krotov A.S., Kirillov V.N. Climatic aging of composite aviation materials: 3. Significant aging factors. Russian Metallurgy (Metally), 2012, no. 4, pp. 323–329.
  11. Dexter H.B. Long-term environmental effects and flight service evaluation of composite materials: technical report TM-89067. NASA, 1987, 188 р.
  12. Kablov E.N., Lebedev M.P., Startsev O.V., Golikov N.I. Climatic tests of materials, structural elements, machinery and equipment in conditions of extremely low temperatures. Proceedings of the VI Eurasian Symposium on the Problems of Strength of Materials and Machines for Cold Climate Regions EURASTRENCOLD–2013, Yakutsk, 2013, pp. 5–7.
  13. Startsev O.V., Lebedev M.P., Kychkin A.K. Aging of polymer composite materials in conditions of extremely cold climate. Izvestiya Altayskogo gosudarstvennogo universiteta, 2020, no. 1 (111), pp. 41–51.
  14. Malshe V.C., Waghoo G. Weathering study of epoxy paints. Progress in Organic Coatings, 2004, vol. 51, no. 4, pp. 267–272.
  15. Cocuzzi D.A., Pilcher G.R. Ten-year exterior durability test results compared to various accelerated weathering devices: Joint study between ASTM International and National Coil Coatings Association. Progress in Organic Coatings, 2013, vol. 76, pp. 979–984.
  16. Pavlov A.V., Andreeva N.P., Pavlov M.R., Merkulova Yu.I. Climatic tests of paint coating based on fluoroplastic and features of its destruction. Trudy VIAM, 2019, no. 5, paper no. 12. Available at: http://www.viam-works.ru (accessed: March 10, 2025). DOI: 10.18577/2307-6046-2019-0-5-103-110.
  17. Kablov E.N., Startsev O.V., Medvedev I.M., Panin S.V. Corrosive aggressiveness of the coastal atmosphere. Part 1. Influencing factors (review). Korroziya: materialy, zashchita, 2013, no. 12, pp. 6–18.
  18. Kablov E.N., Startsev O.V., Medvedev I.M. Corrosive aggressiveness of the coastal atmosphere. Part 2. New approaches to assessing the corrosivity of coastal atmospheres. Korroziya: materialy, zashchita, 2016, no. 1, pp. 1–15.
  19. Startsev O.V., Yarmolinets L.V., Rudnev V.P., Tsintsadze G.B. Forecasting the light transmission of organic glass during climatic aging. Aviatsionnaya promyshlennost, 1990, no. 2, pp. 64–65.
  20. Startsev O.V., Tsintsadze G.B., Vapirov Yu.M., Kiryushkin S.G. Climatic aging of transparent thermoplastic films. 1. Polyethylene. Polimernye opticheskie materialy. Ed. B.R. Smirnov. Chernogolovka: Publ. house of the Institute of Chemical Physics of the USSR Academy of Sciences, 1989, pp. 152–177.
  21. Startsev O.V. Climatic aging of transparent thermoplastic films. 2. Polycarbonate. Polimernye opticheskie materialy. Ed. B.R. Smirnov. Chernogolovka: Institute of Chemical Physics of the USSR Academy of Sciences, 1989, pp. 178–197.
  22. Momber A.W., Buchbach S., Plagemann P., Marquardt T. Edge coverage of organic coatings and corrosion protection over edges under simulated ballast water tank conditions. Progress in Organic Coatings, 2017, vol. 108, pp. 90–92.
  23. Pélissier K., Le Bozec N., Thierry D., Larché N. Evaluation of the Long-Term Performance of Marine and Offshore Coatings System Exposed on a Traditional Stationary Site and an Operating Ship and Its Correlation to Accelerated Test. Coatings, 2022, vol. 12, no. 11, р. 1758.
  24. Bierwagen G.P., He L., Li J. et al. Studies of a new accelerated evaluation method for coating corrosion resistance – thermal cycling testing. Progress in Organic Coatings, 2000, vol. 39, no. 1, pp. 67–78.
  25. Knudsen O.Ø., Skilbred A.W.B., Løken A. et al. Correlations between standard accelerated tests for protective organic coatings and field performance. Materials Today Communications, 2022, vol. 31, art. 103729.
  26. Revin P.O., Makarenko A.V., Harisov R.A., Farhetdinov I.R. Research of underwater applied coatings for corrosion protection of port facilities. Science and Technologies: Oil and Oil Products Pipeline Transportation, 2022, vol. 12, no. 4, pp. 385–393.
  27. LeBozec N., Thierry D., Le Calvé P. et al. Performance of marine and offshore paint systems: Correlation of accelerated corrosion tests and field exposure on operating ships. Materials and Corrosion, 2015, vol. 66, no. 3, pp. 215–225.
  28. Li S., Bi H., Weinell C.E., Dam-Johansen K. A quantitative real-time evaluation of rust creep propagation in coating systems exposed to field testing and cyclic ageing test. Progress in Organic Coatings, 2023, vol. 184, art. 107866.
  29. Saha J.K., Mitra P.K., Paul S., Singh D.D.N. Performance of different organic coatings on steel substrate by accelerated and in atmospheric exposure tests. Indian Journal of Chemical Technology, 2010, vol. 17, no. 2, pp. 102–110.
  30. Chu M.T., Do D.T., Sereda V.N., Karpov V.A. Correlation between climate testing methods and service life prediction for paint systems. International Journal of Corrosion and Scale Inhibition, 2023, vol. 12, no. 3, pp. 1363–1373.
  31. Gao J., Hu W., Wang R., Li X. Study on a multifactor coupling accelerated test method for anticorrosive coatings in marine atmospheric environments. Polymer Testing, 2021, vol. 100, art. 107259.
  32. Kuznetsova V.A., Shapovalov G.G., Marchenko S.A., Kovrizhkina N.A., Silaeva A.A. Paint coatings on the basis of epoxy and acrylic diphasic polymeric system for coloring of elements of cabin of pilots and dashboards. Trudy VIAM, 2020, no. 12 (94), paper no. 09. Available at: http://www.viam-works.ru (accessed: March 10, 2025). DOI: 10.18577/2307-6046-2020-0-12-87-95.
  33. Kuznetsova V.A., Marchenko S.A., Emelyanov V.V., Zheleznyak V.G. Study of the influence of molecular mass of epoxy oligomers and hardeners on the operational properties of paint coatings. Aviation materials and technology, 2021, no. 1 (62), paper no. 07. Available at: http://www.journal.viam.ru (accessed: March 10, 2025). DOI: 10.18577/2713-0193-2021-0-1-71-79.
  34. Kozlova A.A., Kuznetsova V.A., Kozlov I.A., Naprienko S.A., Silaeva A.A. The effect of prolonged heating on the properties of protective coatings for aluminum alloy system Al–Si–Mg. Aviacionnye materialy i tehnologii, 2019, no. 2 (55), pp. 74–80. DOI: 10.18577/2071-9140-2019-0-2-74-80.
  35. Startsev V.O., Valevin E.O., Gulyaev A.I. The influence of polymer composite materials’ surface weathering on its mechanical properties. Trudy VIAM, 2020, no. 8 (90), paper no. 07. Available at: http://www.viam-works.ru (accessed: March 10, 2025). DOI: 10.18577/2307-6046-2020-0-8-64-76.
  36. Startsev V.O. Climate aging of paint coating systems. Part 2. Influence of different climatic zones. Trudy VIAM, 2025, no. 6 (148), paper no. 07. Available at: http://www.viam-works.ru (accessed: June 06, 2025). DOI: 10.18577/2307-6046-2025-0-6-86-97.
  37. Startsev V.O., Kogan A.M., Zeleneva T.O. Climate aging of paint coating systems. Part 1. Effect of long-term exposure on color characteristics. Trudy VIAM, 2025, no. 5 (147), paper no. 08. Available at: http://www.viam-works.ru (accessed: May 19, 2025). DOI: 10.18577/2307-6046-2025-0-5-99-111.
  38. Startsev V.O., Nizina T.A. The modeling of epoxy polymers weathering by the color characteristics measurements. Trudy VIAM, 2015, no. 12, paper no. 10. Available at: http://www.viam-works.ru (accessed: March 10, 2025). DOI: 10.18577/2307-6046-2015-0-12-10-10.