Analysis of solders on tin and lead bases by X-ray floorescent spectroscopy

Alekseev A.V., Orlov G.V., Petrov P.S., Slavin A.V.
UDC
543.51; 669.1
DOI
10.18577/2307-6046-2021-0-4-124-131
Article PDF (Russian) (701 KB)
How to cite
Alekseev A.V., Orlov G.V., Petrov P.S., Slavin A.V. Analysis of solders on tin and lead bases by X-ray floorescent spectroscopy // Proceedings of VIAM. 2021. No. 4. DOI: 10.18577/2307-6046-2021-0-4-124-131. URL: https://test.viam.ru/en/journal/2021/4/10
Keywords
x-ray fluorescence spectroscopy, x-ray fluorescence analysis, nickel alloys, solders, tin analysis, lead analysis.
Abstract

The determination of the elements Cu, Ni, Sb, Bi, Pb, Zn and Fe in the tin-based solder VPr35, as well as the elements Sn, Ni, Sb, Bi and In in the lead-based VPr40 solder by the method of х-ray fluorescence spectroscopy has been carried out. The calibration dependences are corrected taking into account the superposition of signals from interfering elements on the analytical signal and changes in intensity caused by inter-element influences in the matrix. The analysis was carried out by the method of fundamental parameters without using standard samples. The correctness of the results obtained was confirmed by their comparative analysis by atomic emission spectroscopy and high-resolution mass spectrometry with a glow discharge.

Reference list
  1. REFERENCES LIST
  2. Kablov E.N. Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030». Aviacionnye materialy i tehnologii, 2015, no. 1 (34), pp. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
  3. Kablov E.N., Ospennikova O.G., Svetlov I.L. Highly efficient cooling of GTE hot section blades. Aviacionnye materialy i tehnologii, 2017, no. 2 (47), pp. 3–14. DOI: 10.18577/2071-9140-2017-0-2-3-14.
  4. Kablov E.N., Bondarenko Yu.A., Echin A.B. Development of technology of cast superalloys directional solidification with variable controlled temperature gradient. Aviacionnye materialy i tehnologii, 2017, no. S, pp. 24–38. DOI: 10.18577/2071-9140-2017-0-S-24-38.
  5. Bazyleva O.A., Ospennikova O.G., Arginbaeva E.G., Letnikova E.Yu., Shestakov A.V. Development trends of nickel-based intermetallic alloys. Aviacionnye materialy i tehnologii, 2017, no. S, pp. 104–115. DOI: 10.18577/2071-9140-2017-0-S-104-115.
  6. Rylnikov V.S., Lukin V.I. Solders used for soldering materials aviation applications. Trudy VIAM, 2013, no. 8, paper no. 02. Available at: http://viam-works.ru (accessed: November 25, 2020).
  7. Kablov E.N., Chabina E.B., Morozov G.A., Muravskaya N.P. Conformity assessment of new materials using high-level CRM and MI. Kompetentnost, 2017, no. 2, pp. 40–46.
  8. State Standard 15483.4–78. Tin. Methods for the determination of copper. Moscow: Publishing house of standards, 1978, pp. 3–7.
  9. State Standard 20580.4–80. Lead. Methods for the determination of bismuth. Moscow: Publishing house of standards, 1985, pp. 2–5.
  10. State Standard 15483.1–78. Tin. Methods for the determination of antimony. Moscow: Publishing house of standards, 1978, pp. 9–15.
  11. State Standard 26880.1–86. Lead. Atomic absorption method of analysis. Moscow: Publishing house of standards, 1986, pp. 2–14.
  12. State Standard 15483.6–78. Tin. Methods for the determination of iron. Moscow: Publishing house of standards, 1978, pp. 11–13.
  13. State Standard 15483.10-2004. Tin. Atomic emission spectral analysis methods. Moscow: Publishing house of standards, 2004, pp. 21–32.
  14. State Standard 8857–77. Lead. Spectral analysis method. Moscow: Publishing house of standards, 1977, pp. 4–17.
  15. Handbook of x-ray spectrometry. Ed. R.E. Van Grieken, A.A. Marcowicz. 2nd ed., rev. and exp. New-York: Marcel Dekker, Inc., 2001, pp. 14–56.
  16. Criss J.W., Birks L.S. Calculation methods for fluorescent X-ray spectrometry. Empirical coefficients vs. fundamental parameters. Analytical Chemistry, 1968, vol. 40, pp. 1080–1086.
  17. Mashin N.I., Lebedeva R.V., Tumanova A.N. X-ray fluorescence analysis of systems Ni–Fe–Mn–Cr. Analitika i kontrol, 2004, no. 2, vol. 8, pp. 160–164.