Investigation of the influence of the chemical composition of fenotam N210, fenotam N210M, KMF-S, SFZH-3024 resins on their physico-chemical properties

Salimov I.E., Bespalov A.S., Babashov V.G., Maximov V.G.
Salimov I.E., Bespalov A.S., Babashov V.G., Maximov V.G. Investigation of the influence of the chemical composition of fenotam N210, fenotam N210M, KMF-S, SFZH-3024 resins on their physico-chemical properties // Proceedings of VIAM. 2024. No. 2. DOI: 10.18577/2307-6046-2024-0-2-84-91. URL: https://test.viam.ru/en/journal/2024/2/9
Keywords
phenol-formaldehyde resin, urea-modified phenol-formaldehyde resin, urea-melamine-formaldehyde resin, optical microscopy, X-ray diffraction, contact angle, humidity, sorption moisture
Abstract

In this paper, the physicochemical properties of resins of the Fenotam N210, Fenotam N210M, KMF-S, SFZh-3024 brands were studied. The samples of cured resins were tested for humidity and sorption moisture (moisture absorption) in accordance with the methods from GOST 17177–94. Optical microscopy in polarized light and X-ray diffraction have been used to determine the features of the structure of these resins. The dependences of the contact angle of the glass surface on duration of the study for liquid resins of the Fenotam N210M and KMF-S grades were obtained by the sessile drop method.

Reference list
  1. Kablov E.N. Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030». Aviacionnye materialy i tehnologii, 2015, no. 1 (34), pp. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
  2. Kablov E.N. Materials for «Buran» spaceship – innovative solutions of formation of the sixth technological mode. Aviacionnye materialy i tehnologii, 2013, no. S1, pp. 3–9.
  3. Kablov E.N. Russia needs new generation materials. Redkie zemli, 2014, no. 3, pp. 8–13.
  4. Istomin A.V., Bespalov A.S., Babashov V.G. Adding increased resistance to heat and sound insulation of material based on mixture of inorganic and plant fibers. Aviacionnye materialy i tehnologii, 2018, no. 4 (53), pp. 74–78. DOI: 10.18577/2071-9140-2018-0-4-74-78.
  5. Mukhametov R.R., Petrova A.P. Thermosetting binders for polymer composites (review). Aviacionnye materialy i tehnologii, 2019, no. 3 (56), pp. 48–58. DOI: 10.18577/2071-9140-2019-0-3-48-58.
  6. Kablov E.N., Shuldeshov E.M., Petrova A.P., Lapteva M.A., Sorokin A.E. Dependence of complex of sound-proof VZMK type material properties on concentration of hydrophobizing composition on the basis of organosilicon sealant. Aviacionnye materialy i tehnologii, 2020, no. 2 (59), pp. 41–49. DOI: 10.18577/2071-9140-2020-0-2-41-49.
  7. Kan A.Ch., Zhelezina G.F., Kulagina G.S., Ayupov T.R. Fire safety of structural organic plastics reinforced with aramid fabrics. Aviation materials and technologies, 2022, no. 4 (69), paper no. 05. Available at: http://www.journal.viam.ru (accessed: February 17, 2023). DOI: 10.18577/2713-0193-2022-0-4-51-60.
  8. Zastrogina O.B., Shvets N.I., Serkova E.A., Veshkin E.A. Fireproof materials based on phenol-formaldehyde binders. Klei. Germetiki. Tekhnologii, 2017, no. 7, pp. 22–27.
  9. Knopf A., Sheib W. Chemistry and applications of phenolic resins. New York: Springer-Verlag, 1979, 32 р.
  10. Pizzi A., Ibeh C.C. Handbook of Thermoset Plastics. Elsevier, 2014, 13 р. DOI: 10.1016/B978-1-4557-3107-7.00002-6.
  11. Liu H., Zhai D.D., Wang M. et al. Design of urea-modified phenol-formaldehyde as well as the derived N-carbon nanosheets for supercapacitors with elevated rate capability and cycling stability. ChemElectroChem, 2019, p. 12. DOI: 10.1002/celc.201801855.
  12. Solomon M.M., Umoren S.A., Udosoro I.I., Udoh A.P. Inhibitive and adsorption behaviour of carboxymethyl cellulose on mild steel corrosion in sulphuric acid solution. Corrosion Science, 2010, vol. 52, pp. 1317–1325.
  13. Shukla S.K., Quraishi M.A. Effect of some substituted anilines-formaldehyde polymers on mild steel corrosion in hydrochloric acid medium. Journal Applied Polymer Science, 2012, vol. 12, pp. 45130–45137.
  14. Chugh B., Thakur S., Pani B. et al. Investigation of phenol-formaldehyde resins as corrosion impeding agent in acid solution. Journal of Molecular Liquids, 2021, vol. 330, art. 115649.
  15. Si Y., Li J., Cui B. et al. Janus phenol-formaldehyde resin and periodic mesoporous organic silica nanoadsorbent for the removal of heavy metal ions and organic dyes from polluted water. Advanced Composites and Hybrid Materials, 2022, vol. 5, pp. 1180–1195.
  16. Wibowo E.S., Park B.-D., Causin V. Hydrogen-Bond-Induced Crystallization in Low-Molar-Ratio Urea–Formaldehyde Resins during Synthesis. Industrial & Engineering Chemistry Research, 2020, vol. 59, pp. 13095–13104.