Comparison of the properties of carbon fiber reinforced plastics and glass fiber reinforced plastics based on the VSE-1212 binder after exposure to different climatic zones

Startsev O.V., Skirta A.A., Startsev V.O., Valevin E.O., Dvirnaya E.V.
Startsev O.V., Skirta A.A., Startsev V.O., Valevin E.O., Dvirnaya E.V. Comparison of the properties of carbon fiber reinforced plastics and glass fiber reinforced plastics based on the VSE-1212 binder after exposure to different climatic zones // Proceedings of VIAM. 2024. No. 7. DOI: 10.18577/2307-6046-2024-0-7-77-92. URL: https://test.viam.ru/en/journal/2024/7/9
Keywords
fiberglass, carbon fiber, aging, strength, plasticization, thermal expansion, glass transition temperature, destruction
Abstract

Comparative tests of fiberglass VPS-48/7781 and carbon fiber plastic VKU-39 for aging were carried out in the moderately warm climate of Gelendzhik and the humid tropics of Vanning. A decrease in the strength of fiberglass during bending and shear was discovered. The decrease in mechanical properties measured at 120 °C was greater than at room temperature. The compressive strength of VKU-39 carbon fiber plastic is stable after 3 years of exposure in both climatic zones. For fiberglass VPS-48/7781, the decrease in compressive strength was 11% after 3 years of aging in Gelendzhik and 26% after 3 years in Vanning.

Reference list
  1. Ageing of composites. Ed. R. Martin. Cambridje: Woodhead Publishing Limited, 2008, 544 p.
  2. Kablov E.N., Kirillov V.N., Startsev O.V., Krotov A.S. Climatic aging of composite aviation materials: 3. Significant aging factors. Russian Metallurgy (Metally), 2012, no. 4, pp. 323–329.
  3. Irving P., Soutis C. Polymer Composites in the Aerospace Industry. 2nd ed. Cambridje: Woodhead Publishing Limited, 2019, 688 p.
  4. Postnov V.I., Veshkin E.A., Makrushin K.V., Sudin Yu.I. Technological features of manufacturing polymer composite materials of main rotor blades for a light helicopter. Aviation materials and technologies, 2023, no. 1 (70), paper no. 06. Available at: http://www.journal.viam.ru (accessed: May 30, 2024). DOI: 10.18577/2713-0193-2023-0-1-30-50.
  5. Kychkin A.K., Gavrilieva A.A., Kychkin A.A., Lukachevskaya I.G., Lebedev M.P. The initial stage of climatic aging of basalt-reinforced and glass-reinforced plastics in extremely cold climates: regularities. Polymers, 2024, vol. 16, art. 866.
  6. Odegard G.M., Bandyopadhyay A. Physical aging of epoxy polymers and their composites. Journal of Polymer Science, Part B: Polymer Physics, 2011, vol. 49, no. 24, pp. 1695–1716.
  7. Wu J., Zhang C. Modified Constitutive Models and Mechanical Properties of GFRP after High-Temperature Cooling. Buildings, 2024, vol. 14, no. 2, art. 439.
  8. Starkov A.I., Isaev A.Yu., Kutsevich K.E. Comprehensive assessment of the impact of operational and climatic tests on the change of strength properties of polymer composite materials based on adhesive prepregs. Рart 1. Сarbon fiber-reinforced plastic VKU-59. Trudy VIAM, 2024, no. 3 (133), paper no. 08. Available at: http://www.viam-works.ru (accessed: May 30, 2024). DOI: 10.18577/2307-6046-2024-0-3-91-100.
  9. Pickett J.E., Sargent J.R. Sample temperatures during outdoor and laboratory weathering exposures. Polymer Degradation and Stability, 2009, vol. 94, pp. 189–195.
  10. Burch D., Martin J., VanLandingham M. Computer analysis of a polymer coating exposed to field weather conditions. Journal of Coatings, 2002, vol. 74, no. 1, pp. 75–86.
  11. Сальников В.Г. Исследование влагопоглощения авиационных углепластиков в условиях теплого влажного климата. Monitoring Systems of Environment, 2021, no. 2, pp. 46–53.
  12. Heinrick M., Crawford B., Milani A.S. Degradation of Fibreglass Composites under Natural Weathering Conditions. MOJ Polymer Science, 2017, vol. 1, no. 1, pp. 18–24.
  13. Behera A., Vishwakarma A., Thawre M.M., Ballal A. Effect of hygrothermal aging on static behavior of quasi-isotropic CFRP composite laminate. Composites Communications, 2020, vol. 17, pp. 51–55.
  14. Liu X., Su Q., Zhu J., Song X. The Aging Behavior and Life Prediction of CFRP Rods under a Hygrothermal Environment. Polymers, 2023, vol. 15, no. 11, art. 2490.
  15. Cheng W., Cao Y. Strength degradation of GFRP cross-ply laminates in hydrothermal conditions. APL Materials, 2024, vol. 12, no. 3, art. 031113.
  16. Attukur Nandagopal R., Gin Boay C., Narasimalu S. An empirical model to predict the strength degradation of the hygrothermal aged CFRP material. Composite Structures, 2020, vol. 236, аrt. 111876.
  17. Uthaman A., Xian G., Thomas S. et al. Durability of an epoxy resin and its carbon fiber-reinforced polymer composite upon immersion in water, acidic, and alkaline solutions. Polymers, 2020, vol. 12, no. 3, art. 614.
  18. Bone J.E., Sims G.D., Maxwell A.S. et al. On the relationship between moisture uptake and mechanical property changes in a carbon fibre/epoxy composite. Journal of Composite Materials, 2022, vol. 56, no. 14, pp. 2189–2199.
  19. Tao L., Min W., Qi L. et al. The hygrothermal aging process and mechanism of CFRP papered by prepreg that may be stored at room temperature. Polymer Degradation and Stability, 2020, vol. 182, art. 109395.
  20. Zhu R., Li X., Wu C. et al. Effect of Hydrothermal Environment on Mechanical Properties and Electrical Response Behavior of Continuous Carbon Fiber/Epoxy Composite Plates. Polymers, 2022, vol. 14, no. 19, art. 4072.
  21. Aviation materials: a reference book in 13 vols. Ed. E.N. Kablov. Moscow: VIAM, 2015, vol. 13: Climate and microbiological resistance of non-metallic materials, 270 p.
  22. Kirillov V.N., Efimov V.A., Barbotko S.L., Nikolaev E.V. Methodological features of conducting and processing the results of climatic tests of polymer composite materials. Plasticheskie massy, 2013, no. 1, pp. 37–41.
  23. Evdokimov A.A. Polymer compositional material made using vacuum infusion technology with molding at temperatures up to 40 ° C: thesis, Cand. Sc. (Tech.). Moscow: VIAM, 2022, 116 p.
  24. Startsev V.O., Antipov V.V., Slavin A.V., Gorbovets M.A. Modern domestic polymer composite materials for aviation industry (review). Aviation materials and technologies, 2023, no. 2 (71), paper no. 10. Available at: http://www.journal.viam.ru (accessed: May 30, 2024). DOI: 10.18577/2713-0193-2023-0-2-122-144.
  25. Mukhametov R.R., Petrova A.P. Thermoreactive binders for polymer composite materials: textbook. Moscow: VIAM, 2021, 528 p.
  26. Gunyaeva A.G., Sidorina A.I., Kurnosov A.O., Klimenko O.N. Polymeric composite materials of new generation on the basis of binder VSE-1212 and the filling agents alternative to ones of Porcher Ind. and Toho Tenax. Aviacionnye materialy i tehnologii, 2018, no. 3 (52), pp. 18–26. DOI: 10.18577/2071-9140-2018-0-3-18-26.
  27. Nikolaev E.V., Barbotko S.L., Andreeva N.P., Pavlov M.R., Grashchenkov D.V. Comprehensive research of the influence of climatic and operational factors on new generation epoxy binding and polymeric composite materials on its basis. Part 3. Calculation of activation energy and thermal resource of polymeric composite materials on the basis of epoxy matrix. Trudy VIAM, 2016, no. 5 (41), paper no. 11. Available at: http://www.viam-works.ru (accessed: May 30, 2024). DOI: 10.18577/2307-6046-2016-0-5-11-11.
  28. Mishurov K.S., Mishkin S.I. Environmental effect on properties of CFRP (Carbon Fiber Reinforced Plastic) VKU-39. Trudy VIAM, 2016, no. 12 (48), paper no. 08. Available at: http://www.viam-works.ru (accessed: May 30, 2024). DOI: 10.18577/2307-6046-2016-0-12-8-8.
  29. Nikolaev E.V. The preservation of the official characteristics of polymer composite materials for the motorized motor motion engines under the influence of climatic and operational factors: thesis, Cand. Sc. (Tech.). Moscow: VIAM, 2016, 123 p.
  30. Startsev V.O., Slavin A.V. Carbon and glass reinforced polymer based on solventfree binders resistance to the impact of a moderate cold and moderate warm climate. Trudy VIAM, 2021, no. 5 (99), paper no. 12. Available at: http://www.viam-works.ru (accessed: May 30, 2024). DOI: 10.18577/2307-6046-2021-0-5-114-126.
  31. Veligodskiy I.M., Koval T.V., Gulyaev I.N. Influence of climatic conditions on CFRP VKU-39 after three year outdoor exposition in eight climatic zones. Trudy VIAM, 2023, no. 8 (126), paper no. 10. Available at: http://www.viam-works.ru (accessed: May 30, 2024). DOI: 10.18577/2307-6046-2023-0-8-113-128.
  32. Veligodskiy I.M., Koval T.V., Kurnosov A.O., Marakhovskiy P.S. Study of resistance of glass fiber reinforced plastic to natural weathering in different climatic conditions. Trudy VIAM, 2022, no. 11 (117), paper no. 12. Available at: http://www.viam-works.ru (accessed: May 30, 2024). DOI: 10.18577/2307-6046-2022-0-11-134-148.
  33. Startsev V.O., Valevin E.O., Gulyaev A.I. The influence of polymer composite materials’ surface weathering on its mechanical properties. Trudy VIAM, 2020, no. 8 (90), paper no. 07. Available at: http://www.viam-works.ru (accessed: May 23, 2024). DOI: 10.18577/2307-6046-2020-0-8-64-76.
  34. Startsev V.O., Valevin E.O., Pavlov M.R., Skirt A.A. The study of the climatic resistance of thiocol and sulovsan sealants. Klei. Germetiki. Tekhnologii, 2024, no. 1, pp. 24–31.
  35. Sidorina A.I. The mechanical properties of polymer composite materials based on Russian high -strength carbon fillers and new generation polymer matrices. Khimicheskie volokna, 2018, no. 2, pp. 16–19.
  36. Kurs M.G., Vetrova E.Yu. The corrosion aggressiveness of the atmosphere and the climatic resistance of metal materials in various regions of the Russian Federation. III All-Rus. Sci-techn. Conf. «Climate–2018. Issues of predicting corrosion, aging and biopersion of materials». Moscow: VIAM, 2018, pp. 128–143.
  37. Zhang X., Liu M., Lu F. et al. Atmospheric Corrosion of 7B04 Aluminum Alloy in Marine Environments. Corrosion Science and Technology, 2018, vol. 17, no. 1, pp. 6–11.
  38. Zhang T., Zhang T., He Y. et al. Long-term atmospheric aging and corrosion of epoxy primer-coated aluminum alloy in coastal environments. Coatings, 2021, vol. 11, no. 2, art. 237.
  39. State Standard R ISO 4287–2014. Geometric characteristics of products (GPS). Surface structure. Profile method. Terms, definitions and parameters of surface structure. Moscow: Standinform, 2019, 20 p.
  40. Kaplonek W., Nadolny K. Review of the advanced microscopy techniques used for diagnostics of grinding wheels with ceramic bond. Journal of Machine Engineering, 2012, vol. 12, pp. 81–98.
  41. Startsev O.V., Lebedev M.P., Vapirov Y.M., Kychkin A.K. Comparison of Glass-Transition Temperatures for Epoxy Polymers Obtained by Methods of Thermal Analysis. Mechanics of Composite Materials, 2020, vol. 56, no. 2, pp. 227–240.
  42. Malysheva G.V., Marakhovskiy P.S., Barinov D.Ya., Nikolaev E.V. Optimization of the curing modes of fiber-glass based on epoxy binder. Aviation materials and technologies, 2023, no. 2 (71), paper no. 08. Available at: http://www.journal.viam.ru (accessed: May 30, 2024). DOI: 10.18577/2713-0193-2023-0-2-94-103.
  43. Kablov E.N., Startsev V.O. Systematical analysis of the climatics influence on mechanical properties of the polymer composite materials based on domestic and foreign sources (review). Aviacionnye materialy i tehnologii, 2018, no. 2 (51), pp. 47–58. DOI: 10.18577/2071-9140-2018-0-2-47-58.