Determination of sulfur mass fraction in heat resistant nickel alloys and steels within the concentration range from 0.0001 to 0.0009% wt.

Mekhanik E.A., Min P.G., Goundobin N.V., Rastegayeva G.Yu.
UDC
543.272.51
DOI
10.18577/2307-6046-2014-0-9-12-12
Article PDF (Russian) (428.92 KB)
How to cite
Mekhanik E.A., Min P.G., Goundobin N.V., Rastegayeva G.Yu. Determination of sulfur mass fraction in heat resistant nickel alloys and steels within the concentration range from 0.0001 to 0.0009% wt. // Proceedings of VIAM. 2014. No. 9. DOI: 10.18577/2307-6046-2014-0-9-12-12. URL: https://test.viam.ru/en/journal/2014/9/12
Abstract

Sulfur mass fraction in heat-resistant nickel alloys and steels was determined by using infrared absorption of sulfur dioxide SO2 formed during combustion of samples with flux (catalyst) by oxygen flow in the induction furnace of gas analyzer LECO CS-444. A new composition of catalyst for full sulfur extraction from the analyzed alloys was chosen in this work. The catalyst consists of 1 g of flux LECOSEL II HP and 0.5 g of tin. The minimum time of the analysis required for full sulfur extraction was chosen. The possibility of sulfur content determination in heat-resistant nickel alloys and steels with in concentrations range from 0.0001 to 0.0009% wt. is shown.

Reference list
  1. Kablov E.N. Strategicheskie napravlenija razvitija materialov i tehnologij ih perera-botki na period do 2030 goda [Strategic directions of development of materials and technologies to process them for the period up to 2030] //Aviacionnye materialy i tehnologii. 2012. №S. S. 7–17.
  2. Kablov E.N., Ospennikova O.G., Vershkov A.V. Redkie metally i redkozemel'nye jelementy – materialy sovremennyh i budushhih vysokih tehnologij [Rare metals and rare earth elements – materials of current and future high-tech] //Trudy VIAM. 2013. №2. St. 01 (viam-works.ru).
  3. Kablov E.N., Bondarenko Ju.A., Echin A.B., Surova V.A. Razvitie processa napravlennoj kristallizacii lopatok GTD iz zharoprochnyh splavov s monokristallicheskoj i kompozicionnoj strukturoj [The development process of directional solidification of GTE blades with single crystal superalloys and composite structure] //Aviacionnye materialy i tehnologii. 2012. №1. S. 3–8.
  4. Kablov E.N., Petrushin N.V., Svetlov I.L., Demonis I.M. Nikelevye litejnye zharoprochnye splavy novogo pokolenija [Casting nickel superalloys new generation] //Aviacionnye materialy i tehnologii. 2012. №S. S. 36–52.
  5. Kablov E.N., Petrushin N.V., Bronfin M.B., Alekseev A.A. Osobennosti monokristallicheskih zharoprochnyh nikelevyh splavov, legirovannyh reniem [Features single-crystal high-temperature nickel alloys alloyed with rhenium] //Metally. 2006. №5. S. 47–57.
  6. Kablov E.N., Ospennikova O.G., Bazyleva O.A. Materialy dlja vysokoteplonagruzhennyh detalej gazoturbinnyh dvigatelej [Materials for high-thermal components of gas turbine engines] //Vestnik MGTU im. N.Je. Baumana. Ser. «Mashinostroenie». 2011. №SP2.
  7. S. 13–19.
  8. Bondarenko Ju.A., Kablov E.N. Napravlennaja kristallizacija zharoprochnyh splavov s povyshennym temperaturnym gradientom [Directional solidification of superalloys with a high temperature gradient] //MiTOM. 2002. №7. S. 20–23.
  9. Kablov E.N., Svetlov I.L., Petrushin N.V. Nikelevye zharoprochnye splavy dlja lit'ja lopatok s napravlennoj i monokristallicheskoj strukturoj. [Nickel superalloys for blades casting with directional and single-crystal structure] Ch. I //Materialovedenie. 1997. №4.
  10. S. 32–39.
  11. Kablov E.N., Svetlov I.L., Petrushin N.V. Nikelevye zharoprochnye splavy dlja lit'ja lopatok s napravlennoj i monokristallicheskoj strukturoj. [Nickel superalloys for blades casting with directional and single-crystal structure] Ch. II //Materialovedenie. 1997. № 5. S. 14–16.
  12. Sidorov V.V., Min P.G. Rafinirovanie slozhnolegirovannogo nikelevogo rasplava ot primesi sery pri plavke v vakuumnoj indukcionnoj pechi (chast' 1) [Refining complex-nickel impurities from molten sulfur melting in a vacuum induction furnace] //Jelektrometallurgija. 2014. №3. S. 18–23.
  13. Sidorov V.V., Min P.G. Rafinirovanie slozhnolegirovannogo nikelevogo rasplava ot primesi sery pri plavke v vakuumnoj indukcionnoj pechi (chast' 2) [Refining complex-nickel impurities from molten sulfur melting in a vacuum induction furnace] //Jelektrometallurgija. 2014. №4. (v pechati).
  14. Mc Vay R.V., William P., Meier G.H., Pettit F.S. Oxidation of Low Sulfur Single Crystal Nickel-base Superalloys //Superalloys. 1992. P. 807–816.
  15. Sarioglu C., Stinner C., Blanchere J.R., Birks N., Pettit F.S., Meier G.H. The control of sulfur content in nickel-base, single crystal superalloys and its effect on cyclic oxidation resistance /In: Superalloys. 1996. P. 71–80.
  16. Simpson T.M., Price A.R. Oxidation improvements of low sulfur processed superalloys
  17. /In: Superalloys. 2000. P. 387–392.
  18. Ultra low sulfur supperalloy casting and method of making: pat. 5922148 US; pabl. 13.07.1999.
  19. Improved low sulfur nickel-base single crystal supperalloy with ppm additions of lanthanum and yttrium: pat. 2415888 EU; pabl. 14.10.2010.
  20. Sidorov V.V., Rigin V.E., Kablov D.E. Organizacija proizvodstva lityh prutkovyh za-gotovok iz sovremennyh litejnyh vysokozharoprochnyh nikelevyh splavov [Organization of production of cast bar stock of modern casting nickel-base superalloys] //Litejnoe proizvodstvo. 2011. №10. S. 2–5.
  21. Kablov E.N., Sidorov V.V., Kablov D.E., Rigin V.E., Gorjunov A.V. Sovremennye tehnologii poluchenija prutkovyh zagotovok iz litejnyh zharoprochnyh splavov novogo pokolenija [Modern technologies for bar stock of casting superalloys new generation] //Aviacionnye materialy i tehnologii. 2012. №S. S. 97–105.
  22. Min P.G., Sidorov V.V. Opyt pererabotki litejnyh othodov splava ZhS32-VI na nauchno-proizvodstvennom komplekse VIAM po izgotovleniju lityh prutkovyh (shihtovyh) zagotovok [Experience processing waste foundry alloy ZHS32-VI at the scientific-industrial complex for the production of cast VIAM of bar (of charge) blanks] //Aviacionnye materialy i tehnologii. 2013. №4. S. 20–25.
  23. Sidorov V.V., Rigin V.E., Zajcev D.E., Gorjunov A.V. Formirovanie nanostrukturirovannogo sostojanija v litejnom zharoprochnom splave pri mikrolegirovanii ego lantanom [Formation of nanostructured state in casting superalloy with microalloying its lanthanum] //Trudy VIAM. 2013. №1. St. 01 (viam-works.ru).
  24. Sidorov V.V., Rigin V.E., Gorjunov A.V., Kablov D.E. Vysokojeffektivnye tehnologii i sov-remennoe oborudovanie dlja proizvodstva shihtovyh zagotovok iz litejnyh zharoprochnyh splavov [Enabling technologies and modern equipment for production of charge billets casting superalloys] //Metallurg. 2012. №5. S. 26–30.
  25. Sidorov V.V., Rigin V.E., Gorjunov A.V., Min P.G., Kablov D.E. Poluchenie Re–Ru soderzhashhego splava s ispol'zovaniem nekondicionnyh othodov [Preparation of Re–Ru-containing alloy using rejects] //Metallurgija mashinostroenija. 2012. №3. S. 15–17.
  26. Lawrenz D. Ultra-low sulfur determination in high purity base metals and high temperature nickel base alloys //Psys. stat. sol. 1998. V. 167. P. 373–381.
  27. Liu Y., Shao X., Qu L. Study on analytical method for carbon and sulfur in high nickel corrosion resistant alloy tubing //ICPTT. 2011. P. 1099–1103.
  28. GOST 24018.8–91. Splavy zharoprochnye na nikelevoj osnove. Metody opredelenija sery[High-temperature nickel-based. Methods for determination of sulfur].
  29. ASTM E1019–11. Standard test methods for determination of carbon, sulfur, nitrogen, and ox-ygen in steel, iron, nickel, and cobalt alloys by various combustion and fusion techniques.
  30. Kablov E.N., Buntushkin V.P., Povarova K.B., Bazyleva O.A., Morozova G.I., Kazanskaja N.K. Malolegirovannye legkie zharoprochnye vysokotemperaturnye materialy na osnove intermetallida Ni3Al [Low-alloy high-temperature heat-resistant lightweight materials based on the intermetallic Ni3Al] //Metally. 1999. №1. S. 58–65.
  31. Kablov E.N., Bondarenko Ju.A., Kablov D.E. Osobennosti struktury i zharoprochnyh svojstv monokristallov 001> vysokorenievogo nikelevogo zharoprochnogo splava, poluchennogo v uslovijah vysokogradientnoj napravlennoj kristallizacii [Features of the structure and properties of single crystals of high-temperature 001> vysokorenievogo nickel superalloy, obtained with high-gradient directional solidification] //Aviacionnye materialy i tehnologii. 2011. №4. S. 25–31.