Thermographic analysis of waste carbon- and organic plastics as way of evaluation of rational conditions of their destruction

Nistratov A.V., Vu Kim Long, Klushin V.N., Mishkin S.I., Doriomedov M.S., Daskovskiy M.I.
UDC
678.8:620.1
DOI
10.18577/2307-6046-2017-0-11-10-10
Article PDF (Russian) (713.76 KB)
How to cite
Nistratov A.V., Vu Kim Long, Klushin V.N., Mishkin S.I., Doriomedov M.S., Daskovskiy M.I. Thermographic analysis of waste carbon- and organic plastics as way of evaluation of rational conditions of their destruction // Proceedings of VIAM. 2017. No. 11. DOI: 10.18577/2307-6046-2017-0-11-10-10. URL: https://test.viam.ru/en/journal/2017/11/10
Keywords
wastes, polymer composites, pyrolysis, thermal oxidation, thermal analysis.
Abstract

The thermal decomposition of samples of several carbon- and organic plastics in atmosphere of nitrogen and air was studied using thermographic method. Characteristics of mass loss and thermal transitions of the materials were revealed when heated. It is established, that binding of carbon plastics is destroyed by heating at ~300–410°C, and their pyrolysis in contrast to incineration retains exteriorly individual carbon fibers. Adhesive of organic plastics decomposes at ~390°C, and their fibers become carbonized or fade/oxidize. The rational parameters of thermal treatment of studied samples composits were grounded, providing the ability to extract from they secondary fibers or to produce carbonized materials, requiring study of their properties as adsorbents.

Reference list
  1. Kablov E.N. Kompozity: segodnya i zavtra [Composites: today and tomorrow] // Metally Evrazii. 2015. №1. S. 36–39.
  2. Kablov E.N. Materialy – osnova lyubogo dela [Materials – basis of any business] // Delovaya slava Rossii. 2013. №2 (40). S. 4–9.
  3. Petrov A.V., Doriomedov M.S., Skripachev S.Yu. Tehnologii utilizacii polimernyh kompozicionnyh materialov (obzor) [Recycling technologies of polymer composite materials (review)] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2015. №8. St. 09. Available at: http://viam-works.ru (accessed: September 17, 2017). DOI: 10.18577/2307-6046-2015-0-8-9-9.
  4. Hrulkov A.V., Gusev Yu.A., Mishkin S.I., Doriomedov M.S. Effektivnost utilizacii kompozicionnyh materialov [Efficiency of utilization of composite materials] // Novosti materialovedeniya. Nauka i tehnika: elektron. nauch.-tehnich. zhurn. 2016. №6 (24). St. 09. Available at: http://www. materialsnews.ru (accessed: September 17, 2017).
  5. Kablov E.N., Starcev O.V., Krotov A.S., Kirillov V.N. Klimaticheskoe starenie kompozicionnyh materialov aviacionnogo naznacheniya. I. Mehanizmy stareniya [Climatic aging of composite materials of aviation assignment. I. Aging mechanisms] // Deformaciya i razrushenie materialov. 2010. №11. S. 19–27.
  6. Nikolajkin N.I. Analiz modeli vozdejstviya rezultatov proizvodstvennyh processov grazhdanskoj aviacii na okruzhayushhuyu sredu [The analysis of model of influence of results of productions of civil aviation on environment] // Nauchnyj vestnik Moskovskogo gosudarstvennogo tehnicheskogo universiteta grazhdanskoj aviacii. 2006. №100. S. 48–54.
  7. Oliveux G., Dandy L.O., Leeke G.A. Current status of recycling of fibre reinforced polymers: Review of technologies, reuse and resulting properties // Progress in Materials Science. 2015. Vol. 72. P. 61–99.
  8. Howarth J., Mareddy S.S.R., Mativenga P.T. Energy intensity and environmental analysis of mechanical recycling of carbon fibre composite // Journal of Cleaner Production. 2014. Vol. 81. P. 46–50.
  9. Pinero-Hernanza R., Garcia-Serna J., Dodds C. et al. Chemical recycling of carbon fiber composites using alcohols under subcritical and supercritical conditions // The Journal of Supercritical Fluids. 2008. Vol. 46. Issue 1. P. 83–92.
  10. Pickering S.J. Recycling technologies for thermoset composite materials–current status // Composites Part A: Applied Science and Manufacturing. 2006. Vol. 37. Issue 8. P. 1206–1215.
  11. Pimenta S., Pinho S.T. Recycling carbon fibre reinforced polymers for structural applications: Technology review and market outlook // Waste Management. 2011. Vol. 31. Issue 2. P. 378–392.
  12. Nikolajkin N.I., Nikolajkina N.E., Melehova O.P. Ekologiya: uchebnik dlya vuzov [Ecology: the textbook for higher education institutions]. M.: Drofa, 2004. 624 s.
  13. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] // Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
  14. Feng N., Wang X., Wu D. Surface modification of recycled carbon fiber and its reinforcement effect on nylon-6 composites: Mechanical properties, morphology and crystallization behaviors // Current Applied Physics. 2013. Vol. 13. Issue 9. P. 2038–2050.
  15. Shibryaeva L.S., Gorbunova I.Yu., Kerber M.L. Termookislitel'naya destrukciya kompozicii na osnove epoksidnogo oligomera [Thermooxidizing destruktsiya of composition on the basis of epoxy oligomer] // Himicheskaya fizika. 2014. T. 33. №9. S. 65–77.
  16. Kodolov V.I. Goryuchest i ognestojkost polimernyh materialov [Combustibility and fire resistance of polymeric materials]. M.: Himiya, 1976. 126 s.
  17. Zaharov A.K. K voprosu o kinetike processa termicheskogo razlozheniya ugleplastikov. Himiya i tehnologiya uglerodistyh materialov [To question of kinetics of process of thermal decomposition carbon plastics. Chemistry and technology of carbonaceous materials] // Trudy MHTI im. D.I. Mendeleeva. 1979. Vyp. 105. S. 101–102.
  18. Kudryavcev G.I., Zhmaeva I.V. Organicheskie volokna – armiruyushhie materialy [Organic fibers – reinforcing materials] // Zhurnal VHO. 1978. №3. S. 253–258.
  19. Process for preparating acitve carbon fibers: pat 3464268 USA. B01 4 21/18; publ: 13.07.76.
  20. Plankovskij S.I., Garin V.O., Cegelnik E.V. Sovremennye metody utilizacii polimernyh kompozicionnyh materialov [Modern methods of utilization of polymeric composite materials] // Otkrytye informacionnye i kompyuternye integrirovannye tehnologii. 2011. №51. S. 186–193.
  21. Shimkin A.A. Termicheskij analiz v kontrole kachestva polimernyh materialov [The thermal analysis in quality control of polymeric materials] // Sb. tez. dokl. XX Mendeleevskogo sezda po obshhej i prikladnoj himii v 5 t. Ekaterinburg: UrO RAN, 2016. T. 1. S. 130.
  22. Doriomedov M.S., Petrov A.V., Daskovskiy M.I., Skripachev S.Yu. Pererabotka armiruyushchikh napolniteley pri utilizatsii izdeliy iz PKM [Processing of reinforcing fillers at utilization of products from PCM] // Trudy VIAM: elektron. nauch.-tekhnich. zhurn. 2016. №8. St. 12. Available at: http://www.viam-works.ru (accessed: September 17, 2017). DOI: 10.18577/2307-6046-2016-0-8-12-12.
  23. Petrov A.V., Doriomedov M.S., Skripachev S.Yu. Zarubezhnyj opyt razvitiya proizvodstva izdelij s ispolzovaniem vtorichno pererabotannyh polimernyh kompozicionnyh materialov (obzor) [Foreign experience of manufacturing products using recycled polymer composites (review)] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2015. №12. St. 12. Available at: http://www.viam-works.ru (accessed: September 17, 2017). DOI: 10.18577/2307-6046-2015-0-12-12-12.