The development of a solution for promotion of corrosion attack on aluminium alloys in a galvanostatic mode
Kutyrev A.E., Chesnokov D.V., Antipov V.V., Vdovin A.I. The development of a solution for promotion of corrosion attack on aluminium alloys in a galvanostatic mode // Proceedings of VIAM. 2018. No. 9. DOI: 10.18577/2307-6046-2018-0-9-105-118. URL: https://test.viam.ru/en/journal/2018/9/11
Keywords
aluminum alloys, pitting corrosion, anodic dissolution, natural exposure, intergranular corrosion, corrosion prediction
Abstract
Anodic dissolution of aluminum alloys in different solutions was studied as a promising approach to imitate corrosion of these alloys in natural environment. The solution, containing sodium nitrate, sodium sulfite and sodium chloride with «Ekomet» additive, which allows formation of pitting corrosion damage, comparable to observed in natural environment, during the anodic polarization, was developed. To promote not only the pitting corrosion, but also intergranular and exfoliation corrosion, additional chlorides were added to the solution. Alternative approach is to perform anodic dissolution in solution, containing nitrates, sulfites and
chlorides, first and then in sulfite-chloride solution.
Reference list
- Illarionov E.I., Kolobnev N.I., Gorbunov P.Z., Kablov E.N. Alyuminievye splavy v aviakosmicheskoj tekhnike [Aluminum alloys in aerospace engineering]. M.: Nauka, 2001. 192 s.
- Findlay S.J, Harrison N.D. Why aircraft fail // Materials Today. 2002. Vol. 5. No. 11. P. 18–25
- Fejgenbaum Yu.M., Dubinskij S.V. Vliyanie sluchajnykh ekspluatatsionnykh povrezhdenij na prochnost' i resurs konstruktsii vozdushnykh sudov [Influence of accidental operational damage on the strength and lifetime of aircraft construction] // Nauchnyj vestnik Moskovskogo gosudarstvennogo tekhnicheskogo universiteta grazhdanskoj aviatsii. 2013. №187. S. 83–91.
- Sadkov V.V., Mirkin I.I. Obespechenie korrozionnoj stojkosti alyuminievykh konstruktsij v samoletakh «Tu» [Providing corrosion resistance of aluminum structures in Tu airplanes] // Tsvetnye metally. 2006. №11. S. 73–76.
- Katsura A.V. Issledovanie vliyaniya korrozionnykh povrezhdenij na dolgovechnost elementov konstruktsij letatel'nykh apparatov: avtoref. dis. … kand. tekh. Nauk [Investigation of the effect of corrosion damage on the durability of structural elements of aircrafts: thesis, Cand. Sc. (Tech.)]. Krasnoyarsk, 2001. 15 s.
- Semin A.V. Metod utochneniya kharakteristik zhivuchesti silovykh elementov planera dlitelno ekspluatiruemykh vozdushnykh sudov: avtoref. dis. … kand. tekh. Nauk [Method of refinement of survivability characteristics of power elements of the airframe of long-term operated aircraft: thesis, Cand. Sc. (Tech.)]. M., 2011. 23 s.
- Sinyavskij V.S., Valkov V.D., Budov G.M., Korroziya i zashchita alyuminievykh splavov [Corrosion and protection of aluminum alloys]. M.: Metallurgiya, 1979. 224 s.
- Kurs M.G., Laptev A.B., Kutyrev A.E., Morozova L.V. Issledovanie korrozionnogo razrusheniya deformiruemykh alyuminievykh splavov pri naturno-uskorennykh ispytaniyakh. Chast 1 [Investigation of the corrosive destruction of deformable aluminum alloys in field-accelerated tests. Part 1] // Voprosy materialovedeniya. 2016. №1 (85). S. 116–126.
- Fomina M.A., Kutyrev A.E., Klochkova Yu.Yu., Sbitneva S.V. Issledovanie korrozionnyh harakteristik vysokoprochnogo splava sistemy Al–Cu–Li v zavisimosti ot razlichnyh rezhimov termicheskoj obrabotki [Research of corrosion characteristics of high-strength alloy of Al–Cu–Li system depending on various modes of heat treatment] // Aviacionnye materialy i tehnologii. 2016. №S2. S. 39–48. DOI: 10.18577/2071-9140-2016-0-S2-39-48.
- Fomina M.A., Karimova S.A. Analiz korrozionnogo sostoyaniya materialov planera samoletov tipa «Su» posle dlitelnykh srokov ekspluatatsii [Analysis of the corrosive state of airframe materials of Su-type airplanes after long service life] // Korroziya: materialy, zashchita. 2014. №9. S. 20–24.
- Fomina M.A., Karimova S.A. Issledovanie korrozionnyh svojstv listov splava V-1461-T1 primenitelno k vseklimaticheskim usloviyam ekspluatacii aviacionnoj tehniki [Study of corrosion properties of V-1461-T1 aluminum alloy sheets in all-climatic conditions of aerotechnics operation ] // Aviacionnye materialy i tehnologii. 2014. №4. S. 18–22. . DOI: 10.18577/2071-9140-2014-0-4-18-22.
- Agarwala V.S. Aircraft corrosion and aging: problems and controls // Proceedings of 15th ICC. Granada, Spain. 2002. P. 3–12.
- Kurs M.G., Kutyrev A.E., Fomina M.A. Issledovanie korrozionnogo razrusheniya deformiruemyh alyuminievyh splavov pri laboratornyh i naturnyh ispytaniyah [Research of corrosion damage of wrought aluminium alloys at laboratory and full-scale tests] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2016. №8 (44). St. 10. Available at: http://www.viam-works.ru (accessed: September 14, 2018). DOI: 10.18577/2307-6046-2016-0-8-10-10.
- Kurs M.G., Antipov V.V., Lutsenko A.N., Kutyrev A.E. Integralnyj koeffitsient korrozionnogo razrusheniya deformiruemykh alyuminievykh splavov [Integral figure of corrosion damage of deformed aluminum alloys] // Aviacionnye materialy i tehnologii. 2016. №3 (42). S. 24–32. DOI: 10.18577/2071-9140-2016-0-3-24-32.
- Szklarska-Smialowska Z. Mechanism of pit nucleation by electrical breakdown of the passive film // Corrosion Science. 2002. Vol. 44. P. 1143–1149.
- McCafferty E. Sequence of steps in the pitting of aluminum by chloride ions // Corrosion Science. 2003. Vol. 45. P. 1421–1438.
- Knörnschild G. Mechanism of Pit Growth in Homogeneous Aluminum Alloys // Pitting Corrosion, 2012. InTech, Rijeka, Croatia. 178 p.
- Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] // Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
- Grigoreva I.O., Dresvyannikov A.F., Khasan A.D.M. Lokalnaya korroziya alyuminiya v usloviyakh anodnoj polyarizatsii [Local corrosion of aluminum under conditions of anodic polarization] // Vestnik Kazanskogo tekhnologicheskogo universiteta. 2014. №7. S. 279–283.
- Zhuk N.P. Kurs teorii korrozii i zashchity metallov [Course in the theory of corrosion and protection of metals]. M.: Metallurgiya, 1976. 472 s.
- Kuznetsov Yu.I., Kazanskij A.P. Fiziko-khimicheskie aspekty zashchity metallov ingibitorami korrozii klassa azolov [Physicochemical aspects of metal protection by corrosion inhibitors of the azole class] // Uspekhi khimii. 2008. T. 77. №3. S. 227–241.
- Karimova S.A., Kutyrev A.E., Pavlovskaya T.G., Zaharov K.E. Nizkotemperaturnoe uplotnenie anodno-oksidnyh pokrytij na detalyah iz alyuminievyh splavov [Low temperature sealing of anodic oxide coatings on parts of aluminum alloys] // Aviacionnye materialy i tehnologii. 2014. №4. S. 9–17. DOI: 10.18577/2071-9140-2014-0-4-9-17.
- Sprowls D.O. Evaluation of pitting corrosion // ASM Handbook. New York: John Wiley & Sons, 1987. Vol. 13: Corrosion. P. 516–521.
- Sowinski G., Sprowls D.O. Weathering of Aluminum Alloys // Atmospheric Corrosion. Jonh Wiley & Sons, 1982. P. 297–328.
- Kurs M.G. Metod rascheta integralnogo koeffitsienta korrozionnogo razrusheniya listov iz deformiruemykh alyuminievykh splavov pri naturno-uskorennykh ispytaniyakh: dis. … kand. tekhn. nauk [The method of calculating the integral coefficient of corrosive destruction of sheets from deformable aluminum alloys in field-accelerated tests: thesis, Cand. Sc. (Tech.)]. M., 2016. 147 s.
- Klochkov G.G., Grushko O.E., Klochkova Ju.Ju., Romanenko V.A. Promyshlennoe osvoenie vysokoprochnogo splava V-1469 sistemy Al–Cu–Li–Mg [Industrial development of strength alloy V-1469 of Al–Cu–Li–Mg] // Trudy VIAM : elektron. nauch.-tehnich. zhurn. 2014. №7. St. 01. Available at: http://viam-works.ru (accessed: September 17, 2018). DOI: 10.18577/2307-6046-2014-0-7-1-1.
- Kablov E.N., Morozova L.V., Grigorenko V.B., Zhegina I.P., Fomina M.A. Issledovanie vliyaniya korrozionnoj sredy na protsess nakopleniya povrezhdenij i kharakter razrusheniya konstruktsionnykh alyuminievykh splavov 1441 i V-1469 pri ispytaniyakh na rastyazhenie i malotsiklovuyu ustalost [Investigation of the influence of the corrosive environment on the process of accumulation of damages and the nature of destruction of structural aluminum alloys 1441 and B-1469 in tensile tests and low cycle fatigue] // Materialovedenie. 2017. №1. S. 41–48.
